Search results for "MINERALOGY"
showing 10 items of 1516 documents
3D ERT for the study of an ancient wall covered by precious mosaics
2009
The DC electrical tomography (ERT) is still a method scarcely diffused for the study of masonry of recent and ancient buildings, in spite of the very high resolution power of this methodology. The major limitation on ERT applicability on precious surfaces (like masonries or floors with fresco or mosaic covering) depends on the method of current injection: usually it is necessary to drive electrodes (small nails) into small perforations on the surfaces, to obtain sufficiently high current values (to produce good signal to noise ratio). An interesting application of the MYG array (that reduces significantly, compared to other classical arrays, the number of electrodes utilized for current inj…
Thermal-Infrared Spectral and Angular Characterization of Crude Oil and Seawater Emissivities for Oil Slick Identification
2014
Previous work has shown that the emissivity of crude oil is lower than that of the seawater in the thermal-infrared (TIR) spectrum. Thus, oil slicks cause an emissivity decrease relative to the seawater in that region. The aim of this paper was to carry out experimental measurements to characterize the spectral and angular variations of crude oil and seawater emissivities. The results showed that the crude oil emissivity is lower than the seawater emissivity and that it is essentially flat in the atmospheric window of 8-13 μm. The crude oil emissivity has a marked emissivity decrease with the angle (from 0.956 ± 0.005 at 15 ° to 0.873 ± 0.007 at 65 °), which is even higher than that of the …
A new FESEM procedure for assessment of XRD microstructural data of kaolinites
2007
Abstract A sample preparation method for FESEM microstructural analysis of sheet silicates using oriented aggregates on metallic strips parallel to the electronic beam is described. The method allows the easy measurement of thickness of kaolinite crystallites. The results have been compared to the apparent crystallite size measured by XRD The performed measurements for a set of selected kaolinites are in the range 15–60 nm and show a good correlation with XRD crystallite thickness (in the range 11–48 nm) obtained by the Voigt function method.
Generation of CO2-rich melts during basalt magma ascent and degassing
2013
International audience; To test mechanisms of basaltic ma gma degassing, continuous decompressions of volatile-bearing (2.7-3.8 wt% H2O, 600-1300 ppm CO2) Stromboli melts were performed from 250-200 to 50-25 MPa at 1180-1140°C. Ascent rates were varied from 0.25 to ~ 1.5 m/s. Glasses after decompression show a wide range of textures, from totally bubble-free to bubble-rich, the latter with bubble number densities from 104 to 106/cm3, similar to Stromboli pumices. Vesicularities range from 0 to ~ 20 vol%. Final melt H2O concentrations are homogeneous and always close to solubilities. In contrast, the rate of vesiculation controls the final melt CO2 concentration. High vesicularity charges ha…
Gas emissions and crustal deformation from the Krýsuvík high temperature geothermal system, Iceland
2020
Abstract The Krýsuvik volcanic system is located on the oblique spreading Reykjanes Peninsula, SW Iceland. Since early 2009 the region has been undergoing episodes of localized ground uplift and subsidence. From April–November 2013, we operated near-real time monitoring of gas emissions in Krýsuvik, using a Multi-component Gas Analyzer System (Multi-GAS), collecting data on gas composition from a fumarole (H2O, CO2, SO2, H2S). The dataset in this study, comprises a near-continuous gas composition time series, the quantification of diffuse CO2 gas flux, analytical results for direct samples of dry gas, seismic records, and GPS data. Gas emissions from the Krýsuvik geothermal system were exam…
On-line database of voltammetric data of immobilized particles for identifying pigments and minerals in archaeometry, conservation and restoration (E…
2016
[EN] A web-based database of voltammograms is presented for characterizing artists' pigments and corrosion products of ceramic, stone and metal objects by means of the voltammetry of immobilized particles methodology. Description of the website and the database is provided. Voltammograms are, in most cases, accompanied by scanning electron microphotographs, X-ray spectra, infrared spectra acquired in attenuated total reflectance Fourier transform infrared spectroscopy mode (ATR-FTIR) and diffuse reflectance spectra in the UV-Vis-region. For illustrating the usefulness of the database two case studies involving identification of pigments and a case study describing deterioration of an archae…
Metallic nanoparticle enrichment at low temperature, shallow CO2 seeps in Southern Italy
2012
We report on metal enrichment along a natural pH gradient owing to increased CO2 degassing at cold, shallow seeps of Vulcano Island in the Mediterranean Sea, off Sicily. We assessed composition of unfiltered and filtered seawater (<100 nm) along acidic zones ranging between ambient and pH 5, and showed that most seep derived elements are present as nanoclusters which then aggregate into larger colloids while mixing with ambient seawater along a pH gradient. Size and elemental composition of such naturally occurring nanoparticles assessed by modern characterisation methods were in good agreement with the results from conventional analytical methods. We provide analytical evidence for the pre…
Green strategies for decontamination of analytical wastes
2010
Within the paradigm of green analytical chemistry, we discuss the different options for cleaning analytical wastes in the literature, paying special attention to on-line recycling of solvents, degradation of toxic compounds and trace-element passivation. The objective of this review is to present and to evaluate critically suitable methodologies that can be incorporated into analytical methods in order to reduce or to avoid the generation of toxic wastes, which could cumulate in the laboratory and have to be managed outside, so increasing the risks and the cost of analysis.
Natural and artificial radioactivity levels in Livingston Island (Antarctic regions).
1994
Radioactive contamination of the sea and land is due, on the one hand, to fallout from atmospheric atomic explosions since 1945, and, on the other, to emissions produced by nuclear and radioactive facilities. Given its geographic position far distant from the aforementioned main sources of radioactive contamination, Antarctica should have the lowest levels that can be measured on the Earth of artificial radionuclides in the various receptor media which are characteristic of the trophic chain. In the case of Antarctica, these are melt-water, sea-water, mosses, algae, and lichens. With the aim of contributing basic information on the radiation levels present in the Antarctic ecosystem, we hav…
Groundwater radon measurements in the Mt. Etna area.
2003
Radon levels were measured in 119 groundwater samples collected throughout the active volcanic area of Mt. Etna by means of a portable Lucas-type scintillation chamber. The measured activity values range from 1.8 to 52.7 Bq l(-1). About 40% of the samples exceed the maximum contaminant level of 11 Bq l(-1) proposed by the USEPA in 1991. The highest radon levels are measured in the eastern sector of the volcano, which is the seismically most active zone of the volcano. On the contrary the south-western sector, which is both seismically active and a site of intense magmatic degassing, display lower radon levels. This is probably due to the formation of a free gas phase (oversaturation of CO(2…