Search results for "MINERALOGY"
showing 10 items of 1516 documents
An Overview of the Hypogene Caves of Sicily
2017
Karst in Sicily develops in both Messinian gypsum and Mesozoic or Tertiary limestone rocks. Caves are also found in the basalts of Mount Etna. Except for some rare cases, until recently most caves developed in limestone were considered to be of epigenetic origin. The discovery of gypsum in some of these caves, and especially detailed morphological studies, have allowed defining a hypogenic origin for a dozen of caves up to now. In some of these, the hypogenic evidences are very clear, while others remain in doubt because of the widespread presence of well-developed condensation-corrosion morphologies not necessarily related to hydrothermal fluids. This paper reports the present knowledge of…
Investigation of the He solubility in H2O-CO2 bearing silicate liquids at moderate pressure: a new experimental method
2000
We have designed the first available experimental method capable to investigate the solubility of inert gases in H2O–CO2 bearing silicate melts in a large range of pressures. The method overcomes the difficulties imposed by the physical state of volatiles at room conditions. Experiments were done by using an internally heated pressure vessel, where sealed capsules containing the sample are introduced. The peculiarity of the method consists in the capability of loading, in accurately known proportions (even lower than ppm), volatiles in a gaseous state at room conditions. Gas is loaded as a weighed amount of a gas-bearing glass, which was previously prepared by using the same gas as a pressu…
Acid-Base Properties of 2:1 Clays. I. Modeling the Role of Electrostatics
2010
We present a theoretical investigation of the titratable charge of clays with various structural charge (sigma(b)): pyrophyllite (sigma(b) = 0 e x nm(-2)), montmorillonite (sigma(b) = -0.7 e x nm(-2)) and illite (sigma(b) = -1.2 e x nm(-2)). The calculations were carried out using a Monte Carlo method in the Grand Canonical ensemble and in the framework of the primitive model. The clay particle was modeled as a perfect hexagonal platelet, with an "ideal" crystal structure. The only fitting parameters used are the intrinsic equilibrium constants (pK(0)) for the protonation/deprotonation reactions of the broken-bond sites on the lateral faces of the clay particles, silanol, =SiO(-) + H(+) --=…
Fracture stratigraphy and oil first migration in Triassic shales, Favignana Island, western Sicily, Italy
2021
This study aims at evaluating the control exerted by fracture stratigraphy and diagenetic processes on oil first migration through an outcropping, mixed carbonate-siliciclastic succession. The present work included results of sedimentological, paleontological, mineralogical, petrographic, structural, and microstructural analyses carried out on organic-rich shales exposed at the Favignana Island of Sicily, Italy. The analyses focus on Upper Triassic yellowish siltstones and greyish laminated dolomitic limestones, which form a 10's of m-thick succession exposed along the westernmost portion of the Sicilian fold-and-thrust belt. The studied succession deposited in a coastal lagoon associated t…
Fabric control on strain and rupture of heterogeneous shale samples by using a non-conventional mechanical test
2004
Abstract This work was a part of the preliminary stage of the ANDRA project on a deep-seated research laboratory for the feasibility study of long-term radioactive waste storage in the Callovo–Oxfordian argillites of the Eastern part of the Paris Basin. These rocks are bedded, their density is about 2.4, and they contain an average of 30% carbonates and 25% quartz. Thick (5 mm) sections from cores were put through a non-conventional device called CGI testcell (CGI: Centre de Geologie de l'Ingenieur, i.e. Engineering Geology Centre). The aim of this versatile device is to achieve plane deformation tests under compressive uniaxial loading together with controlled temperature and humidity cond…
Mineralogical variability of Callovo-Oxfordian clays from the Paris Basin and the Subalpine Basin.
2006
High-resolution clay mineralogical data at the Middle/Upper Jurassic boundary from the French Subalpine Basin, the Jura Mountains and the Paris Basin (ANDRA boreholes) from Callovo-Oxfordian clayey deposits allow spatial and temporal terrigenous flux evolution to be considered over a period of 6 to 7 Myr. Recorded diachronisms of major mineralogical changes and complex clays distribution at the Paris Basin scale result to combined palaeogeographic/eustatic variations and climate input. In the French Subalpine Basin, mineralogical homogeneity confirms the burial diagenesis influence, but other terrigenous supplies must be involved in contrast to the Paris Basin domains. Volcanogenic clays (b…
Towards the development of a fossil bone geochemical standard: An inter-laboratory study
2007
Ten international laboratories participated in an inter-laboratory comparison of a fossil bone composite with the objective of producing a matrix and structure-matched reference material for studies of the bio-mineralization of ancient fossil bone. We report the major and trace element compositions of the fossil bone composite, using in-situ method as well as various wet chemical digestion techniques. For major element concentrations, the intra-laboratory analytical precision (%RSDr) ranges from 7 to 18%, with higher percentages for Ti and K. The %RSDr are smaller than the inter-laboratory analytical precision (%RSDR; 100% was found for the high field strength elements (Hf, Th, Zr, Nb). The…
Plant Pigments: Properties, Analysis, Degradation
2005
Publisher Summary This chapter discusses the molecular structures, the general physicochemical properties of plant pigments, and the mechanisms involved in pigment degradation. The invasive and noninvasive methods used for pigment analysis, including the mechanisms involved in pigment degradation, are reviewed. The chapter presents different analytical methods that can be used to identify pigments. All the methods are invasive techniques that are time consuming and often expensive. To reduce sampling and analytical costs, and to speed up the analyses, noninvasive analytical procedures have been developed with the aim to characterize the pigment content of samples, and in the case of food pr…
Possible functions of biomineralization of some Textulariid (Foraminifera) species of the Nw Iberian Margin
2016
The main goal of this work is to analyze the elemental composition of the test’s wall of some species/specimens of Textulariids (sub-class Subclass Textulariia), collected in surface sediments of the NW Iberian Margin. The elemental analyses was based on the Energy Dispersive Spectroscopy (EDS) on the Scanning Electron Microscope (SEM; Hitachi, S4100) of Textularia deltoidea, Textularia agglutinans, Sahulia conica, Karrerotextularia flintii, Siphotextularia heterostoma, Karreriella bradyi, Spiroplectammina sagittula and Arenoparrella mexicana . The elelemetal cocnentrations of the species wall were compared with the mineralogical composition (X-Ray diffraction) of the sediments of the stati…
Compartmentalization of gypsum and halite associated with cyanobacteria in saline soil crusts
2016
The interface between biological and geochemical components in surface crust of a saline soil was investigated using X-Ray Diffraction (XRD), and variable pressure scanning electron microscopy (SEM) in combination with Energy Dispersive X-ray Spectrometry (EDS). Mineral compounds such as halite and gypsum were identified crystallized around filaments of cyanobacteria. A total of 92 genera were identified from the bacterial community based on 16S gene pyrosequencing analysis. The occurrence of the gypsum crystals, their shapes and compartmentalization suggested that they separated NaCl from the immediate microenvironment of the cyanobacteria, and that some cyanobacteria and communities of su…