Search results for "MINERALOGY"
showing 10 items of 1516 documents
Isotactic polypropylene solidification under pressure and high cooling rates. A master curve approach
2000
Solidification in industrial processes very often involves flow fields, high thermal gradients and high pressures: the development of a model able to describe the polymer behavior becomes complex. Recently a new equipment has been developed and improved to study the crystallization of polymers when quenched under pressure. An experimental apparatus based on a modified, special injection moulding machine has been employed. Polymer samples can be cooled at a known cooling rate up to 100 °C/s and under a constant pressure up to 40 MPa. Density, Micro Hardness (MH), Wide angle X-ray diffraction (WAXD), and annealing measurements were then used to characterize the obtained sample morphology. Res…
Structural, microstructural and impedance spectroscopy study of functional ferroelectric ceramic materials based on barium titanate
2013
The differences between the physical properties of barium titanate BaTiO3 and newly obtained BaHfxTi1-xO3 were identified. These ceramics were prepared by solid-phase reaction from simple oxides and carbonates using the conventional method. The structure and morphology of investigated samples were characterised by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The application of impedance spectroscopy made possible to characterize of these materials in the terms of electrical properties.
In situ analysis of garnet inclusion in diamond using single-crystal X-ray diffraction and X-ray micro-tomography
2012
A single crystal of garnet enclosed in a diamond from the Jericho kimberlite (Slave Craton, Canada) has been investigated using X-ray diffraction and X-ray micro-tomography. The novel experimental approach allowed us to determine the crystal structure of the garnet. The unit-cell edge a and fractional atomic coordinates of oxygen were used to determine the composition via an updated Margules model for garnets. The composition is Pyr(0.41(5))Alm(0.36(7))Gro(0.22(1))Uva(0.01(1)), which is indistinguishable from the eclogitic garnets found in other Jericho diamonds. We also demonstrated that residual pressures on the inclusion of up to 1 GPa do not affect significantly the determination of the…
STACKING-FAULTS IN VERY FINE PALLADIUM PARTICLES SUPPORTED ON PUMICE
1990
By means of an X-ray diffraction study, carried out with best-fitting procedures, of the asymmetry and peak maximum shifts of some reflections, stacking-faults in the FCC lattice of very fine palladium particles supported on pumice were detected using the Warren-Wagner-Cohen theoretical approach.
Inorganic gels as precursors of TiO2 photocatalysts prepared by low temperature microwave or thermal treatment
2008
Abstract A simple procedure for preparing active TiO2 photocatalysts is presented. The starting materials were unusual TiO2 gels formed from TiCl4. The use of microwaves for a very short time enhanced the TiO2 crystallinity preventing an increase of particle size and minimizing the decrease of specific surface area. This result makes this preparation very attractive. The formation of the gels was monitored through measurements of viscosity. All the samples were characterized by means of X-ray diffraction, diffuse reflectance spectroscopy and BET specific surface area measurements. The photoactivity of the samples was evaluated using the photodegradation of 4-nitrophenol in liquid–solid regi…
RADIUS - rapid particle analysis of digital images by ultra-high-resolution scanning of thin sections
2005
RADIUS is a newly developed particle-size measurement technique, based on evaluation of digital images of thin sections. Analyses are performed with sub-millimetre sample resolution and are thus designed to work on a single lamina of laminated sediments. The method covers grain sizes from medium silt to coarse sand. The application contains pattern-recognition modules that allow the detection of typical particle distributions of loess, organic detritus, turbidites and tephra layers. Cutting and hiding effects of particles on thin sections are corrected by empirical correction matrices. The calculated analysis results are compared with manually counted and measured samples to calibrate the a…
The formation of peak rings in large impact craters.
2016
The Chicxulub impact crater, known for its link to the demise of the dinosaurs, also provides an opportunity to study rocks from a large impact structure. Large impact craters have “peak rings” that define a complex crater morphology. Morgan et al. looked at rocks from a drilling expedition through the peak rings of the Chicxulub impact crater (see the Perspective by Barton). The drill cores have features consistent with a model that postulates that a single over-heightened central peak collapsed into the multiple-peak-ring structure. The validity of this model has implications for far-ranging subjects, from how giant impacts alter the climate on Earth to the morphology of crater-dominated …
Textures and c-axis orientations of deformed quartz crystals from porphyric dikes of the Alpine »Root Zone« (Western Alps)
1986
Deformation textures and c-axis preferred orientations of quartz phenocrysts from porphyric dikes of the Alpine »Root Zone« have been formed under conditions of greenschist to low amphibolite facies. It is shown that the deformation textures as shear planes and kink bands, boudins, grain boundary sutures, subgrains, coarse and fine recrystallized grains, deformation lamellae and fractures are developed in a chronological sequence during first increasing and later decreasing temperatures. The c-axis orientations are chiefly influenced by kinking during the early stage of metamorphism and later by recrystallization but not by the initial orientations of the c-axes. The shape of crossed-girdle…
Dependence of the Lattice Parameter of Magnesium Oxide on Crystallite Size
1966
Lattice parameters were measured on MgO specimens prepared in air between 450° and 1200°C. The lattice parameter, a, decreases with increase in preparation temperature, Tp, and with increase in crystallite size. A hydroxide layer is present on the MgO particles. If MgO is prepared in vacuum, a increases as Tp increases and as crystallite size, D, increases. It is concluded that a dilatant volume stress is imposed by the hydroxide layer. It is also shown that the oxide surface reactivity toward water is linked to the deviation from perfect order ensuing from low preparation temperatures.
Deformation of melt-bearing systems—insight from in situ grain-scale analogue experiments
2005
Abstract The deformation behaviour of partially molten rocks was investigated using in situ analogue experiments with norcamphor+ethanol, as well as partially molten KNO 3 +LiNO 3 . Three general deformation regimes could be distinguished during bulk pure shear deformation. In regime I, above ca. 8–10 vol.% liquid (melt) fraction ( ϕ bulk ), deformation is by compaction, distributed granular flow, and grain boundary sliding (GBS). At ϕ bulk ϕ bulk (regime III), grains form a coherent framework that deforms by grain boundary migration accommodated dislocation creep, associated with efficient segregation of remaining liquid. The transition liquid fraction between regimes I and II ( ϕ LT ) dep…