Search results for "MINERALOGY"
showing 10 items of 1516 documents
Reprocessing and restabilization of greenhouse films
2002
From the ecological and economical points of view, reprocessing of polyethylene greenhouse films is a promising solution to reduce discarded materials and to produce useful, or potentially useful, objects for service. Films exposed outdoors, however, show inferior mechanical properties and the melt processing worsens these properties. The addition of stabilizers and antioxidants to recycled plastic products prevents inherent thermal instabilities from occurring within the time frame of proper processing. In this study, we attempt to explore ways for improving product performance by the addition of four different additives when the recycled films undergo intensive shear processing. The proce…
Dielectric investigation of sodium potassium niobate ceramic doped 7% of antimony
2012
Abstract Electric properties of sodium potassium niobate ceramic doped antimony (Na0.5K0.5)(Nb0.93Sb0.07)O3 with sintering aid MnO2 (0.5 mol% MnO2) (KNNSbx + 0.5Mn) were investigated in a broad frequency (from 1 Hz to 54 GHz) and temperature (from 110 K to 800 K) ranges. The mean relaxation times calculated from the dielectric permittivity measurements fulfill Arrhenius relationship with dipole activation energy EA = 3409 K (EA/kB = 0.29 eV). The DC conductivity has been extracted from experimental results and the activation energy was calculated EA = 11733.78 K (EA/kB = 1.011 eV).
INFLUENCE OF MONOXIDES ADDITION ON SINTERING OF SODIUM-POTASSIUM NIOBATES SOLID SOLUTION
2008
ABSTRACT In this paper the preparation, structure and dielectric parameters of ceramics from different powders of pure potassium sodium niobate (KNN) and KNN doped with 1.0 wt% of Li2O, CdO, Bi2O3, MnO2, V2O5 and WO3 have been studied. The dopping of sintering aids did not affect the crystallographic structure of the ceramics significantly; all ceramic samples had a single-phase perovskite structure. Added elements Li2O, CdO, MnO2, V2O5 effectively decreased the sintering temperature of KNN (50°–80°C). All sintering aids influenced sinterability, microstructure and dielectric properties of ceramics. Dielectric constant for doped samples increased from 6000 up to 8000.
Mapping Ash CaCO3, pH, and Extractable Elements Using Principal Component Analysis
2017
Abstract Ash cover in fire-affected areas is an important factor in the reduction of soil erosion and increased availability of soil nutrients. Thus it is important to understand the spatial distribution of ash and its capacity for soil protection and to provide nutrients to the underlying soil. In this work, we aimed to map ash CaCO3, pH, and select extractable elements using a principal component analysis (PCA). Four days after a medium to severe wildfire, we established a grid in a 9 ×27 m area on a west facing slope and took ash samples every 3 m for a total of 40 sampling points. The PCA carried out retained five different factors. Factor 1 had high positive loadings for ash with elect…
Influence of Temperature on Calcium Hydroxyapatite Nanopowders
2012
The aim of this work is to investigate the effects of thermal treatment, in the range of temperature between 80°C - 900°C, on crystallinity, morphology and particles size of calcium hydroxylapatite nanopowders (HAp). A complete study was carried out applying 31P Magic Angle Spinning NMR, X-ray diffraction, nitrogen porosimetry and Transmis- sion Electron Microscopy techniques. HAp specimens were prepared by chemical precipitation in an aqueous solution of calcium nitrate and ammonium hydrogen phosphate. The thermal treatment performed, showed the formation of crystals whose appearance has three main morphologies and different particles size. HAp treated up to 500°C showed a set of needle-li…
Bond strength dependent superionic phase transformation in the solid solution series Cu2ZnGeSe4−xSx
2014
Recently, copper selenides have shown to be promising thermoelectric materials due to their possible superionic character resulting from mobile copper cations. Inspired by this recent development in the class of quaternary copper selenides we have focused on the structure-to-property relationships in the solid solution series Cu2ZnGeSe4−xSx. The material exhibits an insulator-to-metal transition at higher temperatures, with a transition temperature dependent on the sulfur content. However, the lattice parameters show linear thermal expansion at elevated temperatures only and therefore no indication of a structural phase transformation. 63Cu nuclear magnetic resonance shows clear indications…
The Suitability of Chemically and Thermally Activated Quaternary Clays of Latvia as Raw Material for Geopolymer Binders
2013
It is now accepted that new binders are needed to replace Portland cement (PC) for enhanced environmental and durability performance. The urge to reduce emissions of carbon and the fact that PC structures having built a few decades ago are already facing disintegration problems points out the handicaps of PC binders. Research works carried out in developing of alkali-activated binders show that this new type of binder could have a huge potential to become as alternative building material. Latvian Quaternary clays were studied from the point of view of the national economy, analysing the physical properties and chemical composition of those sediments in connection with the possibilities of …
Using the simplified falling head technique to detect temporal changes in field-saturated hydraulic conductivity at the surface of a sandy loam soil
2007
Abstract Determining temporal changes in field-saturated hydraulic conductivity ( K fs ) is important for understanding and modeling hydrological phenomena at the field scale. Little is known about temporal variability of K fs values measured at permanent sampling points. In this investigation, the simplified falling head (SFH) technique was used for an approximately 2-year period to determine temporal changes in K fs at 11 permanent sampling points established at the surface of a sandy loam soil. Additional K fs measurements were obtained by the single-ring pressure infiltrometer (PI) technique to also compare the SFH and PI techniques. The lowest mean values of K fs , M ( K fs ), were det…
Surface and interface analysis of worn TiN (PVD) coated cold forging tools
1992
Abstract Wear of cold forging tools, improved by TiN (PVD) hard coating and used in the production of alternator and starter components in the car industry, has been studied in detail. The most complicated case was the tool that produced a clutch housing of high precision. The 630 kN press process (50 pcs min −1 ) caused heavy adhesive and abrasive wear due to material flow, high surface pressure and also wear in the direction of tool movement. Results show that on the worn functional surfaces of the analysed tool, the lifetime of which was extended with TiN coating by a factor of 8–10, the following features were observed: non-uniform TiN coating thickness decrease; long grooves, damaged a…
Mechanism of Formation of TiO2-Doped Mullites from Heated Single-Phase Gels Investigated by Structural and Microstructural Parameters
2008
An analysis of the microstructure of TiO 2 -doped mullites prepared from monophasic gels thermally treated in the temperature range 900°-1600°C is reported. Two series of gels with nominal compositions 3(Al 2-x Ti x O 3 ) ·2(SiO 2 ) and 2(Al 2-x Ti x O 3 )·(SiO 2 ), in the range 0≤x≤0.15, were prepared. X-ray powder diffraction (XRD) and scanning electron microscopy (SEM) were used to follow the structural and textural evolution from gels to the final doped mullites. The crystallite sizes and microstrains were determined by linewidth refinements of XRD patterns using the integral breadth method of Langford and the Warren-Averbach analysis. XRD patterns showed the formation of Al 2 TiO 5 and…