Search results for "MINERALOGY"

Morphology of ZnO grown by MOCVD on sapphire substrates

2004

A quantitative roughness and microstructural analysis of ZnO grown on sapphire by atmospheric metalorganic chemical vapor deposition (MOCVD) is presented. In order to investigate the influence of the substrate on the morphology, different sapphire orientations have been employed. Scanning force microscopy data have been analyzed for a variety of thicknesses to elucidate, if possible, the growth mechanisms involved in the growth process. Our study reveals significant differences between morphologies depending on whether the substrate surface exhibits steps (misoriented a-, c- and r-planes) or not (m-plane); however, no major differences on the calculated roughness coefficients have been foun…

Development of crystal morphology during unitaxial growth in a progressively widening vein: II. Numerical simulations of the evolution of antitaxial …

2001

The development of fibrous morphology and capability of fibres for tracking the opening trajectory were investigated using numerical simulations of a natural antitaxial fibrous vein. Starting from a non-unique best case, variation of fracture opening velocity, grain size, wall roughness, growth anisotropy and crystal growth velocity shows that these parameters differ in importance for crystal morphology and tracking capability. Fibrous veins can be simulated using crack–seal opening of the fracture. Grain boundaries track the opening trajectory if the wall roughness is high, opening increments are small and crystals touch the wall before the next crack increment starts.

The influence of the raw material and production method on the morphology, microstructure, chemical and phase composition of tetrabasic lead sulfate …

1992

Abstract Tetrabasic lead sulfate (4BS) produced by two different methods (solution and paste) and from two different raw materials (tetragonal PbO and leady oxide) were charaterized by different analytical techniques. The techniques applied were wet-chemical methods, scanning electron microscopy, transmission electron microscopy and X-ray powder diffraction. The preparation method was observed to be the most decisive factor influencing the structure and the morphology of the 4BS pastes in this study.

The role of nano-perovskite in the negligible thorium release in seawater from Greek bauxite residue (red mud)

2016

AbstractWe present new data about the chemical and structural characteristics of bauxite residue (BR) from Greek Al industry, using a combination of microscopic, analytical, and spectroscopic techniques. SEM-EDS indicated a homogeneous dominant “Al-Fe-Ca-Ti-Si-Na-Cr matrix”, appearing at the microscale. The bulk chemical analyses showed considerable levels of Th (111 μg g−1), along with minor U (15 μg g−1), which are responsible for radioactivity (355 and 133 Bq kg−1 for 232Th and 238U, respectively) with a total dose rate of 295 nGy h−1. Leaching experiments, in conjunction with SF-ICP-MS, using Mediterranean seawater from Greece, indicated significant release of V, depending on S/L ratio,…

Synthesis and Structure Determination of the Hierarchical Meso-Microporous Zeolite ITQ-43

2011

[EN] The formation of mesopores in microporous zeolites is generally performed by postsynthesis acid, basic, and steam treatments. The hierarchical pore systems thus formed allow better adsorption, diffusion, and reactivity of these materials. By combining organic and inorganic structure-directing agents and high-throughput methodologies, we were able to synthesize a zeolite with a hierarchical system of micropores and mesopores, with channel openings delimited by 28 tetrahedral atoms. Its complex crystalline structure was solved with the use of automated diffraction tomography.

A multivariate approach to the study of orichalcum ingots from the underwater Gela's archaeological site

2017

Abstract In this work a careful ICP-OES and ICP-MS investigation of 38 ancient ingots has been performed to determine both major components and trace elements content to find a correlation between the observed different features and the composition. The ingots, recovered in an underwater archaeological site of various finds near Gela (CL, Italy), were previously investigated by X-Ray Fluorescence (XRF) spectroscopy to know the composition of the alloy and it was found that the major elements were copper and zinc, in a ratio compatible with the famous orichalcum similar to the contemporary brass that was considered a precious metal in ancient times. The discovery of huge amount this alloy is…

Partial least squares X-ray fluorescence determination of trace elements in sediments from the estuary of Nerbioi-Ibaizabal River.

2010

The feasibility of partial least squares (PLS) regression modeling of X-ray fluorescence (XRF) spectra of estuarine sediments has been evaluated as a tool for rapid trace element content monitoring. Multivariate PLS calibration models were developed to predict the concentration of Al, As, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sn, V and Zn in sediments collected from different locations across the estuary of the Nerbioi-Ibaizabal River (Metropolitan Bilbao, Bay of Biscay, Basque Country). The study was carried out on a set of 116 sediment samples, previously lyophilized and sieved with a particle size lower than 63 microm. Sample reference data were obtained by inductively coupled plasma mass …

Formation of refractory metal nuggets and their link to the history of CAIs

2015

Abstract Ca, Al-rich inclusions (CAIs) often contain numerous refractory metal nuggets (RMNs), consisting of elements like Os, Ir, Mo, Pt and Ru. The nuggets are usually thought to have formed by equilibrium condensation from a gas of solar composition, simultaneously with or prior to oxide and silicate minerals. However, the exact mechanisms responsible for their extremely variable compositions, small sizes and associations with CAI minerals remain puzzling. Expanding on previous work on chemically separated RMNs, we have studied a large number of RMNs within their host CAIs from three different meteorite types, i.e., the highly primitive chondrite Acfer 094 (C2-ungrouped), Allende (CV3 ox…

The scientific instruments of the historical Mineralogical Museum of Palermo: testimonies of almost two centuries of mineralogical and petrographic s…

The scientific collections of the historic Museum of Mineralogy of Palermo are located on the second floor of via Archirafi 36 and are preserved by the Dipartimento di Scienze della Terra e del Mare (DiSTeM) of the University of Palermo. The historical edifice was designed by the architect Antonio Zanca and completed in the years 1933-1934. From the beginning, it has hosted the Institute of Physics at the ground and first floors, today entitled in honour of the famous physicians Emilio Segrè, and the Institute of Mineralogy at the second floor, which has kept one of the richest and ancient collections of Sicilian minerals. Today, the collections are partially exposed and are the subject of …

Recovering ammonium by treated and untreated zeolitic mixtures: A comprehensive experimental and modelling study

2023

The recovery of ammonium (NH4+) from aqueous solutions by zeolite is attractive. In this study, the physicalchemistry of NH4+ adsorption process from aqueous solution by two zeolitic mixtures, either treated or not treated with NaCl, was assessed. Results suggested that the zeolitic mixture richer in mordenite and with high specific surface area adsorbed more NH4+ than the one richer in clinoptilolite and heulandite showing a lower specific surface area. NaCl treatment increased the amount of NH4+ adsorbed by the zeolitic mixtures. The higher amount of NH4+ adsorbed by the zeolitic mixtures treated with NaCl was explained by the low/high density water model accounting for cation exchange am…