Search results for "MTO"
showing 10 items of 538 documents
Minimizing geminate recombination losses in small-molecule-based organic solar cells
2019
Small-molecule-based organic solar cells (OSCs) are a recurrent alternative to polymer-based OSCs. Due to the higher purity and definition of small molecules compared to polymers, the morphological requirements can be more relaxed. Here, we present a series of novel rhodanine-based small-molecule electron donors and blend them with the standard acceptor PC70BM. By performing a target analysis on femtosecond spectroscopy data, we quantify the rates of geminate charge recombination. We are able to reproduce these rates by applying the Marcus–Levich–Jortner equation, using results from quantum chemical calculations. This shows that in a series of differently substituted compounds, one can corr…
Ultrafast energy transfer in dansylated POPAM–eosin complexes
2006
Abstract Excitation energy transfer (EET) in dendritic host–guest complexes has been studied. Three generations G2, G3 and G4 of dansyl substituted poly(propyleneamine) dendrimers (POPAM) were complexed with a fluorescent dye eosin in chloroform solution. Arrival of excitation from dansyls to eosin was monitored by femtosecond transient absorption spectroscopy. EET rates from the dansyls to eosin(s) are characterised by two time constants 1 ps and 6 ps independent of dendrimer generation. Relaxation processes in eosin were clearly faster when complexed with dendrimer than in solution. As several eosins are bound to G3 and G4 dendrimers, besides host–guest interaction, also eosin–eosin inter…
The primary structural photoresponse of phytochrome proteins captured by a femtosecond X-ray laser
2020
Please check the README file for more information about the dataset.
Canonical correlation in multivariate time series analysis
1997
We analyze a class o f state space identification algorithms for time series, based on canonical correlation analysis in the ligth of recent results on stochastic systems theory calle d « subspace methods » .These can be describe as covariance estimation followed b y stochastic realization .The methods offer the major advantage o f converting the nonlinear parameter estimation phase in traditional V A R M A models identification in to the solution o f Riccati equation but introduce at the same time some no n trivial mathematical problem s related to positivity. The states o f the forward -backward innovations representation have an interpretation : Instrumental Variables estimators .
Mesure de l'effet Kerr d'ordre élevé des constituants de l'air
2009
Talk given by V. Loriot
De novo CCND2 mutations leading to stabilization of cyclin D2 cause megalencephaly-polymicrogyria-polydactyly-hydrocephalus syndrome
2014
Activating mutations in genes encoding phosphatidylinositol 3-kinase (PI3K)-AKT pathway components cause megalencephaly-polymicrogyria-polydactyly-hydrocephalus syndrome (MPPH, OMIM 603387)(1-3). Here we report that individuals with MPPH lacking upstream PI3K-AKT pathway mutations carry de novo mutations in CCND2 (encoding cyclin D2) that are clustered around a residue that can be phosphorylated by glycogen synthase kinase 313 (GSK-3 beta)(4). Mutant CCND2 was resistant to proteasomal degradation in vitro compared to wild-type CCND2. The PI3K-AKT pathway modulates GSK-3 beta activity(4), and cells from individuals with PIK3CA, PIK3R2 or AKT3 mutations showed similar CCND2 accumulation. CCND…
Hormonikorvaushoito ja luurankolihaksisto : estrogeenisten ja progestogeenisten komponenttien vaikutukset lihassoluviljelmässä
2010
Yksi merkittävimmistä ikääntymiseen liittyvistä tapahtumista on luurankolihasten heikentyminen. Sarkopenia eli lihaskato heikentää ennen kaikkea ikääntyvän ihmisen terveyttä ja sitä kautta elämänlaatua, mutta sen kustannukset myös sosiaali- ja terveydenhuollolle ovat suuret. Naisilla lihasten suorituskyky heikkenee merkittävästi vaihdevuosien aikana, jolloin myös estrogeenin ja progesteronin tasot laskevat. Etenkin 17β-estradiolin (E2) tuotanto munasarjoissa loppuu vaihdevuosien aikana. Estrogeenin tiedetään vaikuttavan primaaristen sukupuoliominaisuuksien lisäksi myös moniin muihin kudoksiin, kuten luuhun ja lihaksiin. Vaihdevuosien mukanaan tuomia oireita hoidetaan usein estradiolia ja pr…
Effects of combined hormone replacement therapy or its effective agents on the IGF-1 pathway in skeletal muscle.
2010
Objectives To investigate the effects of combined hormone replacement therapy (HRT) and its effective agents on the IGF-1 signaling pathway. Design and methods To examine the effects of HRT on skeletal muscle in vivo, we utilized pre- and post-intervention samples from a randomized double blinded trial with 50–57-year-old women. The intervention included the year-long use of either HRT preparation (2 mg 17β-estradiol, E2; 1 mg norethisterone acetate, NETA, n = 10) or placebo (CO, n = 9). Microarray technology and quantitative PCR (qPCR) were used to study the expression of insulin-like growth factor I (IGF-1) and its splice variants as well as IGF-1 receptor, Akt1, mTOR, FOXO1, FOXO3, atrog…
Non-linear interactions of femtosecond laser pulses with graphene : photo-oxidation, imaging and photodynamics
2017
This thesis presents a study focused on interactions of femtosecond laser pulses with graphene, a one atom thick carbon membrane. Graphene, which exhibits exceptional electronic and optoelectronic properties, could provide considerable advantage over current silicon-based electronics. Graphene alone, being semi-metal, is not sufficient for electronic applications, but requires modification. For this, a set of methods for modifying and measuring the properties of graphene was developed. With the perspective of making graphene a suitable component for electronics, optoelectronics or photonics, ultrashort laser pulses were used for drawing patterns on graphene. The procedure modifies graphene …
Electrical measurements of femtosecond laser treated graphene
2017
Tutkielman pääasiallinen tavoite oli valmistaa sähköisiin mittauksiin sopivia grafeenilaitteita ja tutkia femtosekuntilaserkäsittelyn vaikutusta grafeenin sähköisiin ominaisuuksiin. Tutkielmassa käsitellään grafeenin valmistamista kemiallisella kaasufaasipinnoituksella, laitegeometrian määrittelyä ja käsittelemättömän, sekä femtosekuntilaserilla käsitellyn grafeenin sähköisiä mittauksia. Grafeenin synteesin alustana käytettiin kupariohutkalvoja ja pääasiallisena lähtöaineena oli etanoli tai metaani. Metaanin käyttö grafeenin synteesissä johti paremmin toistettaviin tuloksiin. Lisäksi havaittiin, että synteesissä käytetyn uunin latausjärjestelmän teräksinen osa lisäsi kupariohutkalvon reikii…