Search results for "Magnetism"
showing 10 items of 1934 documents
Monitoring the Early Steps of Unfolding of Dicalcium and Mono-Ce3+-Substituted Forms of P43M Calbindin D9k
2003
Early steps of unfolding of P43M Calbindin D9k have been evaluated by NMR spectroscopy on the native dicalcium and on the paramagnetic monocerium-substituted derivative. Although at 2 M GdmHCl the ...
Mössbauer Spectral Study of Two Layered Honeycomb Molecular Magnets: PPh4FeIIFeIII(ox)3 and NBu4FeIIFeIII(ox)3
2002
The Mossbauer spectra of the layer ferrimagnets PPh4FeIIFeIII(ox)3 and NBu4FeIIFeIII(ox)3 have been measured between 1.9 and 315 K. The paramagnetic spectra exhibit both high-spin iron(II) and iron(III) doublets. The iron(II) quadrupole splittings are negative and decrease substantially upon cooling as a result of a low-symmetry crystal field splitting. In contrast, the iron(III) splittings are small, positive, and virtually independent of temperature. The respective magnetic ordering temperatures of 30 and 42.5 K agree well with the phase observed by bulk magnetometry and the magnetic sextets yield hyperfine fields of ca. 60 kOe for iron(II) and 540 kOe for iron(III). The unusually low iro…
Giant magnetoresistance in semiconducting DyNiBi
2008
Abstract The semiconducting half-Heulser compound DyNiBi shows a negative giant magnetoresistance (GMR) below 200 K. Except for a weak deviation, this magnetoresistance scales roughly with the square of the magnetization in the paramagnetic state, and is related to the metal–insulator transition. At low temperature, a positive magnetoresistance is found, which can be suppressed by high fields. The magnitude of the positive magnetoresistance changes slightly with the amount of impurity phase.
Magnetic and structural investigations of ultra-thin Co–Fe alloy films on W(1 1 0)
2004
Abstract We investigated ultra-thin CoxFe1−x films on a flat and vicinal BCC W(1 1 0) surface with thicknesses between 1.8 and 7 monolayers (ML) using longitudinal Kerr magnetometry. We found a transition from magnetic bulk behavior between 3 and 4 ML to the monolayer. The maximum of the remnant Kerr signal that appears for thicker films at x=0.5 turns into a minimum for a sample thickness below 4 ML , while the specific Kerr-rotation per monolayer shows the well known bulk behavior. A similar magnetic behavior on the flat as well as on the stepped part of the substrate indicates that this is an intrinsic property. For x=0.5 the pseudomorphic monolayer is paramagnetic even when it is covere…
Correlation of quenched structural disorder and magnetism inTiFe2Laves-phase thin films
2002
In recent bandstructure calculations for the $C14$ Laves-phase intermetallic compound ${\mathrm{TiFe}}_{2}$ two energetically nearly degenerate magnetic ground states (antiferromagnetic and ferromagnetic) were predicted. As a consequence of this near-degeneracy in the $C14$ stability range of ${\mathrm{Ti}}_{x}{\mathrm{Fe}}_{1\ensuremath{-}x}$ $(x\ensuremath{\approx}1/3)$ the magnetic properties are strongly correlated with the sublattices' occupation by Ti and Fe. We analyzed the magnetic properties of a series of thin epitaxial films with varying composition in the $C14$ stability range. The temperature- and field-dependent magnetic properties of these samples were determined by dc superc…
Antiferromagnetic order competing with topological state in CexBi2−xTe3
2015
The topological surface states in three-dimensional topological insulators are easily tuned by chemical doping, especially by magnetic impurities. We prepared single crystals of CexBi2−xTe3 with various x (=0.04, 0.06, 0.08, 0.10, and 0.12). The obtained crystals were characterized by X-ray diffraction and scanning electron microscopy. The magnetic susceptibility data revealed that the Ce atoms are well substituted for Bi into Bi2Te3. From the Curie-Weiss fits, we observed that the effective magnetic moments μeff are close to 2.54 μB for free Ce ion, and the paramagnetic Curie-Weiss temperatures θp are negatively increased from 2.87 K to −59.3 K with increasing x. The magnetization data cle…
ESR observations of paramagnetic centers in intrinsic hydrogenated microcrystalline silicon
2002
Paramagnetic centers in hydrogenated microcrystalline silicon, mc-Si:H have been studied using dark and light-induced electron-spin resonance ~ESR!. In dark ESR measurements only one center is observed. The g values obtained empirically from powder-pattern line-shape simulations are gi52.0096 and g’52.0031. We suggest that this center may be due to defects in the crystalline phase. During illumination at low temperatures, an additional ESR signal appears. This signal is best described by two powder patterns indicating the presence of two centers. One center is asymmetric (gi51.999, g’51.996), while the other is characterized by large, unresolved broadening such that unique g values cannot b…
Hysteresis in the spin transition regime of [Fe(NH2trz)3](NO3)2 as probed by ZF-μSR
2006
The thermal spin transition which occurs in the polymeric chain compound [Fe(NH(2)trz)(3)](NO3)(2) above room temperature has been investigated by zero-field muon spin relaxation (mu SR) (similar to 8-402 K). The depolarization curves are best described by a Lorentzian and a Gaussian line that represent fast and slow components respectively. The spin transition is associated with a hysteresis loop of width Delta T = 34 K (T-1/2(up arrow) = 346 K and T-1/2(down arrow) = 312 K) that has been delineated by the temperature variation of the initial asymmetry parameter. Comparison of zero-field and transverse field (20 Oe) mu SR measurements shows that diamagnetic muon species occur over the enti…
The chain length of anisotropic paramagnetic particles in a rotating field
2020
In this article, the maximal length of a chain of paramagnetic particles with magnetic anisotropy in a rotating magnetic field is studied. The theory of paramagnetic particle chains usually assumes that the particles are magnetically isotropic and do not rotate in a rotating field. In experiments it is seen that spherical paramagnetic particles rotate, which can be explained by small magnetic anisotropy. In this article, the maximal chain length is calculated for paramagnetic particles with magnetic anisotropy in a rotating magnetic field. Results show that the maximal chain length as a function of field frequency has the same trend for isotropic magnetic particles and particles with magnet…
Spin Crossover and Paramagnetic Behaviour in Two-Dimensional Iron(II) Coordination Polymers with Stilbazole Push–Pull Ligands
2009
The suitability of the stilbazole push–pull ligands, 4′-dimethylaminostilbazole (DMAS) and 4′-diethylaminostilbazole (DEAS), for the construction of bimetallic FeII–AgI/AuI cyanide-based coordination polymers that exhibit spin crossover properties is investigated. The structural and physical characterization of four novel two-dimensional FeII polymers formulated as {Fe(DMAS)2[Ag(DMAS)(CN)2]2} (1) and {Fe(L)2[M(CN)2]2} (L = DMAS, M = Au (2); DEAS, Ag (3); DEAS, Au (4)) is reported. Polymers 1 and 4 are paramagnetic over the whole range of temperatures studied (5–300 K), whereas 2 and 3 exhibit spin crossover properties.