Search results for "Magnetism"
showing 10 items of 1934 documents
Evolution of an isolated monopole in a spin-1 Bose-Einstein condensate
2016
We simulate the decay dynamics of an isolated monopole defect in the nematic vector of a spin-1 Bose-Einstein condensate during the polar-to-ferromagnetic phase transition of the system. Importantly, the decay of the monopole occurs in the absence of external magnetic fields and is driven principally by the dynamical instability due to the ferromagnetic spin-exchange interactions. An initial isolated monopole is observed to relax into a polar-core spin vortex, thus demonstrating the spontaneous transformation of a point defect of the polar order parameter manifold to a line defect of the ferromagnetic manifold. We also investigate the dynamics of an isolated monopole pierced by a quantum vo…
Quantum critical point in ferromagnet
2008
Abstract The heavy-fermion metal CePd 1 - x Rh x can be tuned from ferromagnetism at x = 0 to non-magnetic state at the critical concentration x c . The non-Fermi liquid behavior at x ≃ x c is recognized by power law dependence of the specific heat C ( T ) given by the electronic contribution, susceptibility χ ( T ) and volume expansion coefficient α ( T ) at low temperatures: C / T ∝ χ ( T ) ∝ α ( T ) / T ∝ 1 / T . We show that this alloy exhibits a universal thermodynamic non-Fermi liquid behavior independent of magnetic ground state. This can be well understood utilizing the quasiparticle picture and the concept of fermion condensation quantum phase transition at the density ρ = p F 3 / …
Dynamical mean-field theory versus second-order perturbation theory for the trapped two-dimensional Hubbard antiferromagnet
2011
In recent literature on trapped ultracold atomic gases, calculations for two-dimensional (2D) systems are often done within the dynamical mean-field theory (DMFT) approximation. In this paper, we compare DMFT to a fully 2D, self-consistent second-order perturbation theory for weak interactions in a repulsive Fermi-Hubbard model. We investigate the role of quantum and of spatial fluctuations when the system is in the antiferromagnetic phase, and find that, while quantum fluctuations decrease drastically the order parameter and critical temperatures, spatial fluctuations only play a noticeable role when the system undergoes a phase transition, or at phase boundaries in the trap. We conclude f…
One-dimensional iron(III) and two-dimensional iron(III)nickel(II) cyanide-bridged ferromagnetic arrays from hexacyanoferrate(III) and [Ni(cyclam)]2+ …
1999
Abstract The X-ray structures and magnetic properties of a iron(III) linear chain and a honeycomb-like layered iron(III)-nickel(II) cyanide-bridged compound are reported. The former contains alternating iron sites and unexpected ferromagnetic behaviour, justified on the basis of the axial distortion from regular octahedral geometry of one of the iron ions. The latter is metamagnetic with ferromagnetic intralayers and antiferromagnetic interlayers interactions with a Neel temperature, TN= 7.7 K. The field-induced transition from an antiferro- to a ferromagnetic state takes place at Hc= 5000 G. The antiferromagnetic ordered phase exhibits spin-canting and long range ferromagnetic ordering at …
New BEDT-TTF/[Fe(C5O5)3]3- Hybrid System: Synthesis, Crystal Structure, and Physical Properties of a Chirality-Induced α Phase and a Novel Magnetic …
2007
The paramagnetic and chiral anion [Fe(C5O5)3]3- (C5O52-=croconate) has been combined with the organic donor BEDT-TTF (=ET=bis(ethylenedithio)tetrathiafulvalene) to synthesize a novel paramagnetic semiconductor with the first chirality-induced alpha phase, alpha-(BEDT-TTF)5[Fe(C5O5)3].5H2O (1), and one of the few known paramagnetic molecular metals, beta-(BEDT-TTF)5[Fe(C5O5)3].C6H5CN (2). Both compounds present layers of BEDT-TTF molecules, with the alpha or beta packing modes, alternating with layers containing the high-spin S=5/2 Fe(III) anions and solvent molecules. In the alpha phase, the alternation of the chiral [Fe(C5O5)3]3- anions along the direction perpendicular to the BEDT-TTF cha…
Current density maps, magnetizability, and nuclear magnetic shielding tensors of bis-heteropentalenes. III. Thieno-thiophene isomers
2005
Near Hartree–Fock values of the magnetic susceptibility and nuclear magnetic shielding of bis-heteropentalenes consisting of two thiophene units ([2,3-b], [3,2-b], [3,4-b], and [3,4-c] isomers) have been estimated via computational schemes relying on continuous transformation of the origin of the current density within the coupled Hartree–Fock approximation and extended gaugeless Gaussian basis sets. The results are compared with those obtained via London gauge-including orbitals. Maps of streamlines and the modulus of the ring current density induced by a magnetic field normal to the molecular plane are reported for the three isomers of higher symmetry, showing that the intense diamagnetic…
Rational design of a new class of heterobimetallic molecule-based magnets: Synthesis, crystal structures, and magnetic properties of oxamato-bridged …
2008
Abstract Two new series of oxamato-bridged heterobimetallic coordination networks of general formula Li5[Li3M2(mpba)3(H2O)6] · 31H2O [M = NiII (1a) and CoII (1b)] and Li2[Mn3M2(mpba)3(H2O)6] · 22H2O [M = NiII (2a) and CoII (2b)] have been prepared from the metal-mediated self-assembly of the hexakis(bidentate), triple-stranded dinickel(II) and dicobalt(II) complexes [M2(mpba)3]8− [mpba = meta-phenylenebis(oxamato)] with either monovalent lithium(I) or divalent manganese(II) ions respectively, in water. X-ray structural analyses of 1a and 1b show an anionic three-dimensional network formed by an infinite parallel array of oxamato-bridged Li 3 I M 2 II (M = Ni and Co) hexagonal layers, which …
A stable oxoverdazyl free radical: Structural and magnetic characterization
2006
Abstract The structure and magnetic properties (susceptibility and ESR) of the stable oxoverdazyl free radical 6-(4-acetamidophenyl)-1,4,5,6-tetrahydro-2,4-dimethyl-1,2,4,5-tetrazin-3(2H)-one are presented. The crystal structure consists of chains of parallel planar molecules running along the b-axis. These chains are formed by dimers with a ring-over-bond overlap and a significant offset between dimers, although with similar inter- and intradimer distances. The susceptibility measurements show that this compound is an S = 1/2 paramagnet with weak antiferromagnetic interactions. The magnetic susceptibility can be very well reproduced with an antiferromagnetic regular chain model with g = 2.…
Colloidal layers in magnetic fields and under shear flow
2005
The behaviour of colloidal mono- and bilayers in external magnetic fields and under shear is discussed and recent progress is summarized. Superparamagnetic colloidal particles form monolayers when they are confined to a air–water interface in a hanging water droplet. An external magnetic field allows us to tune the strength of the mutual dipole–dipole interaction between the colloids and the anisotropy of the interaction can be controlled by the tilt angle of the magnetic field relative to the surface normal of the air–water interface. For sufficiently large magnetic field strength crystalline monolayers are found. The role of fluctuations in these two-dimensional crystals is discussed. Fur…
Valence band photoemission from thin iron films - A comparison of experimental and theoretical results
1998
Abstract In this contribution, we report on photoemission data from thin iron films on W(110) that have been carried out by means of spin-resolved photoelectron spectroscopy as well as Magnetic Circular Dichroism in valence band photoemission at the storage ring BESSY. These techniques give complementary information on the electronic and magnetic properties, such as exchange and spin–orbit splitting. We compare our experimental data to new photoemission calculations, which have been obtained in the framework of a fully relativistic one-step theory for ferromagnetic materials.