Search results for "Material chemistry"
showing 10 items of 413 documents
Corrosion in amine solvents used for the removal of acid gases
2008
International audience; Processes using amine solvents for the removal of CO 2 have long been used for the treatment of natural gas. More recently, developments in the field of post-combustion CO 2 capture have gained considerable interest for greenhouse gas mitigation. Even though the nature of the amine is different for both applications, the process flow diagrams are very similar. The raw gas is contacted with the amine solvent in an absorber column, and the CO 2 is absorbed by the solvent. The rich solvent containing the CO 2 then circulates to a regenerator, where the temperature is increased to strip the CO 2. The lean solvent then returns to the absorber for a new cycle. For these pr…
Incorporation d'azote et d'oxygène dans les nanoparticules formées par traitement de surface laser de cibles métalliques dans l'air
2016
International audience; Lors de l'irradiation de matériaux métalliques tels que l'aluminium, le fer ou le titane par un faisceau laser de courte durée d'impulsion (de l'ordre de la nanoseconde), il se forme une vapeur très énergétique et fortement ionisée appelée plume-plasma. A la fin de l'interaction, ce plasma se refroidit et se détend à des vitesses supersoniques. Des nanoparticules résultent de la condensation de cette vapeur métallique dans l'air, donc de la réactivité chimique avec les gaz réactifs de l'air tels que l'azote et l'oxygène. L'objectif de cette étude est de quantifier la quantité d'éléments légers afin de comprendre les mécanismes physiques mis en jeu dans le plasma, cré…
Continuous hydrothermal synthesis of doped barium zirconate powder for PCFC (Protonic Ceramic Fuel Cell) application
2019
International audience; BaZr 1-x M x O 3-d (M=Ce and/or Y) perovskite materials are good potential candidates for Protonic Ceramic Fuel Cell (PCFC) electrolyte due to their remarkable property of protonic conduction at intermediate temperature (400-600°C). Fabbri et al. have reported a protonic conductivity of 2.10-2 S.cm-1 at 600°C for BaCe 0.7 Zr 0.1 Y 0.2 O 3-d [1]. However, the synthesis of these materials requires high temperature (1500°C) by solid state reaction. The hydrothermal synthesis in supercritical water appears then as a way to synthetize perovskite materials at a temperature as low as 400°C. Furthermore, this process allows the formation of nanometric powder. Finally the con…
Corrosion and pH prediction in the annulus of flexible pipes under high pressure of CO2
2016
International audience; Annulus of flexible pipelines represents a specific corrosive environment for the high strength carbon steel wires, mainly due to the low V/S ratio between the volume of electrolyte and the exposed steel surface. This environment induces high super-saturation levels of dissolved iron, together with the establishment of pH values far above thermodynamic equilibrium. Nevertheless, it also induces difficulties to predict actual levels of pH in the annulus, since thermodynamic models do not apply. In order to overcome these difficulties, and to obtain trustful pH values for the design of flexible pipelines, lots of efforts were put both in the experimental and modelling …
Corrosion in alcanolamines for natural gas treatment - High temperature experiments in lean and rich conditions
2011
International audience; In the oil and gas industry, acid gas removal is required for the treatment of natural gas. New applications were also recently pushed forward for CO 2 capture from the flue gas of power plants. For both applications, the most widespread industrial processes use absorption-desorption by an alcanolamine solvent. In such amine units for acid gas removal, corrosion represents an important operational concern. Influent parameters governing corrosion are temperature and acid gas loading, amine nature, and the presence of degradation by-products. Some of these parameters were studied with corrosion experiments in autoclave. Test temperature was between 110°C and 120°C, i.e…
Les céramiques pour l’électronique et l’électrotechnique
2013
International audience; Ce chapitre est consacré au très vaste domaine des céramiques pour l’électronique et l’électrotechnique : céramiques résistives, conductrices, supraconductrices, diélectriques, magnétiques, linéaires ou non linéaires, piézoélectriques, multifonctionnelles. En perpétuelle évolution: de plus en plus petites, de moins en moins chères, de plus en plus intégrées…
Nanotubes de carbone alignés synthétisés par CCVD : optimisation de rendement de synthèse et extension sur grandes surfaces pour matériaux multifonct…
2014
International audience
Nano-SiC/CNT composites sintered by SPS: CNT amount effect on mechanical, thermal and electrical properties
2014
International audience
Propriétés mécaniques, thermiques et électriques de composites à matrice SiC nanostructurée renforcée de nanotubes de carbone
2015
International audience
Bone regeneration into 3D architectured and osteoinductive titanium implants
2017
National audience