Search results for "Mean squared error"
showing 10 items of 145 documents
A satellite stand-alone procedure for deriving net radiation by using SEVIRI and MODIS products
2018
Abstract In this study, a new stand-alone satellite approach for the estimation of net surface radiation (Rn) has been implemented and validated for the Italian territory. The method uses the MODIS and MSG-SEVIRI time series products and it is independent of the use of ancillary data (i.e. ground measurements). A database of daily measurements of Rn, provided by 9 stations of the FLUXNET network, was used to validate the method in different ecological scenarios in the period 2010-12. The Rn modelled by the proposed approach and the corresponding FLUXNET measurements were in good agreement, with RMSE and R2 of 19.8 Wm−2 and 0.87, respectively, at 8-days scale, and 23.3 Wm−2 and 0.92, respect…
Efficient Computation of Multiscale Entropy over Short Biomedical Time Series Based on Linear State-Space Models
2017
The most common approach to assess the dynamical complexity of a time series across multiple temporal scales makes use of the multiscale entropy (MSE) and refined MSE (RMSE) measures. In spite of their popularity, MSE and RMSE lack an analytical framework allowing their calculation for known dynamic processes and cannot be reliably computed over short time series. To overcome these limitations, we propose a method to assess RMSE for autoregressive (AR) stochastic processes. The method makes use of linear state-space (SS) models to provide the multiscale parametric representation of an AR process observed at different time scales and exploits the SS parameters to quantify analytically the co…
Multivariate regression analysis applied to the calibration of equipment used in pig meat classification in Romania.
2016
This paper highlights the statistical methodology used in a dissection experiment carried out in Romania to calibrate and standardize two classification devices, OptiGrade PRO (OGP) and Fat-o-Meat'er (FOM). One hundred forty-five carcasses were measured using the two probes and dissected according to the European reference method. To derive prediction formulas for each device, multiple linear regression analysis was performed on the relationship between the reference lean meat percentage and the back fat and muscle thicknesses, using the ordinary least squares technique. The root mean squared error of prediction calculated using the leave-one-out cross validation met European Commission (EC…
A green method for the determination of cocaine in illicit samples
2013
Abstract Direct determination of cocaine in untreated seized samples has been made based on diffuse reflectance measurements of the near infrared (NIR) radiation through samples contained inside standard glass vials. The method used a series of previously analyzed samples, by the reference gas chromatography method, to build a partial least squares calibration model which was validated using an independent set of samples. The use of a general model for samples containing from 11.38% till 86.44% (w/w) cocaine was based on the use of spectral ranges from 12500.7 to 10128.6, 9339.8 to 6967.7 and 5388.3 to 4597.6 cm−1 with previous first derivative and vector normalization data pre-processing a…
Forecasting container transshipment in Germany
2009
International audience; In this paper, we examine container transshipment at German ports using the seasonal ARIMA (SARIMA) model and the Holt-Winters exponential smoothing approach. Our models are designed especially to take account of the seasonal behavior of the quarterly data used. We consider the dynamic development in this sector for the whole container throughput and also the destinations Asia, Europe and North America, which are the world's three main economic regions. Our data runs from the first quarter of 1989 to the fourth quarter of 2006. We provide detailed quarterly forecasts for the year 2007 and 2008. According to forecasting error measures such as Mean Square Error and The…
Calibration of Cholesky Auxiliary Basis Sets for Multiconfigurational Perturbation Theory Calculations of Excitation Energies
2010
The accuracy of auxiliary basis sets derived from Cholesky decomposition of two-electron integrals is assessed for excitation energies calculated at the state-average complete active space self-consistent field (CASSCF) and multiconfigurational second order perturbation theory (CASPT2) levels of theory using segmented as well as generally contracted atomic orbital basis sets. Based on 196 valence excitations in 26 organic molecules and 72 Rydberg excitations in 3 organic molecules, the results show that Cholesky auxiliary basis sets can be used without compromising the accuracy of the multiconfigurational methods. Specifically, with a decomposition threshold of 10(-4) au, the mean error due…
Spatial analysis of the homogeneity of the land surface temperature in three Spanish test sites
2015
Calibration and validation cal/val are key activities to test the data quality acquired from satellite-based instruments, as well as to report the accuracy of derived products such as the land surface temperature LST. Calibration of thermal infrared TIR data and validation of LST products at low spatial resolution requires the identification of large and homogeneous areas, which is a difficult task. In this work, spatial and temporal homogeneity of LST was analysed over three Spanish regions: the agricultural area of Barrax, Donana National Park, and Cabo de Gata Natural Park. For this purpose, very high spatial resolution approximately 3 m imagery acquired with the Airborne Hyperspectral S…
A more cost-effective geomatic approach to modelling PM10 dispersion across Europe
2014
International audience; PM10 concentrations in most major European cities exceed the limits set by the European Directive and are expected to continue to do so in the coming years. Moreover, PM10s can be transported over long distances impacting air quality, public health and ecosystem functionality far from their sources of emission. Modelling remains one of the only options for tracking PM10 deposition in remote areas with no monitoring stations. Even so, air pollution models based on atmospheric physics usually imply substantial economic, logistical and computational investment. In this work, we present a new geomatic approach to modelling mean annual PM10 concentrations across Europe. O…
Relationship between UVB and broadband solar radiation in Spain
2014
The daily values of UVB irradiation (290–315 nm), IUVB, and the broadband total irradiation (300–2800 nm), IT, measured on a horizontal plane have been correlated for the period 2000–2008 at 16 measurement sites in Spain. The results have been compared with the daily experimental values registered at the same sites during the period 2009–2011. The coefficients of determination R2 obtained by applying a linear regression are higher than 0.88 for all sites and increase to 0.94 when using a quadratic regression. When all data are considered together, the values of R2 are 0.91 and 0.97 for the linear and quadratic regressions, respectively. Three different clearness indices, which are dimension…
Predicting the stream macroinvertebrate fauna across regional scales: influence of geographical extent on model performance
2008
AbstractPredictive modeling is used increasingly often in freshwater bioassessment. These models are routinely applied across broad geographical areas, yet the influence of spatial extent on model performance has not been assessed directly. We examined the influence of changing geographical extent on the performance of River InVertebrate Prediction and Classification System (RIVPACS)–type predictive models of benthic macroinvertebrates in boreal headwater streams representative of reference conditions. Separate models were constructed for 2 hierarchical extents: within ecoregions (middle boreal and north boreal) and across ecoregions. We assessed the accuracy and precision of the models usi…