Search results for "Measurements"
showing 10 items of 720 documents
Erroneous p-type assignment by Hall effect measurements in annealed ZnO films grown on InP substrate
2013
We report on incorrect carrier type identification achieved by Hall effect measurements performed on ZnO films grown by pulsed laser deposition on InP substrates and subsequently annealed for 1 h at 600 C in air. While Hall measurements, after post-growth annealing, reveal a change in the electrical properties of the films, from n-type to p-type, both photocurrent-based and standard C V measurements performed on the same samples show no change in the native n-type doping of the ZnO films. A possible interpretation of the two results is reported. In particular, p-type conductivity observed by Hall effect may be ascribed to a highly conductive thin layer formed during the annealing process at…
Luminescence properties of nonbridging oxygen hole centers at the silica surface
2009
Abstract Two variants of the surface-nonbridging oxygen hole center, ( Si–O)3Si–O• and ( Si–O)2(H–O)Si–O•, stabilized in porous films of silica nano-particles were investigated by time resolved luminescence excited in the visible and UV spectral range by a tunable laser system. Both defects emit a photoluminescence around 2.0 eV with an excitation spectrum evidencing two maxima at 2.0 and 4.8 eV, this emission decreases by a factor ∼2 on increasing the temperature from 8 up to 290 K. However, the different local structure influences the emission lineshape, the quantum yield and the decay lifetime. Such peculiarities are discussed on the basis of the symmetry properties of these defects.
Photoluminescent hybrid nanomaterials from modified halloysite nanotubes
2018
The synthesis of photoluminescent nanomaterials based on halloysite nanotubes is described. The obtained hybrid was characterized by means of TGA, FT-IR, DLS and XPS measurements; in addition its morphology was imaged by TEM and HR-TEM. The HNT hybrid also exhibited photoluminescent properties, both in solution and in the solid state, and white-light emission (0.24, 0.36; CIE coordinates) was observed. This work could be pioneering as a new strategy for manufacturing both LEDs and fluorescent tags based on HNT nanomaterials. © 2018 The Royal Society of Chemistry.
Isoelectronic series of oxygen deficient centers in silica: experimental estimation of homogeneous and inhomogeneous spectral widths
2008
We report nanosecond time-resolved photoluminescence measurements on the isoelectronic series of oxygen deficient centers in amorphous silica related to silicon, germanium and tin atoms, which are responsible of fluorescence activities at approximately 4 eV under excitation at approximately 5 eV. The dependence of the first moment of their emission band on time and that of the radiative decay lifetime on emission energy are analyzed within a theoretical model able to describe the effects introduced by disorder on the optical properties of the defects. We obtain separate estimates of the homogeneous and inhomogeneous contributions to the measured emission line width, and we derive homogeneou…
Green phosphorescence and electroluminescence of sulfur pentafluoride-functionalized cationic iridium(III) complexes
2015
EZ-C acknowledges the University of St Andrews for financial support. We report four cationic iridium(III) complexes [Ir(C^N)2(dtBubpy)](PF6) that have sulfurpentafluoride-modified 1-phenylpyrazole and 2-phenylpyridine cyclometalating (C^N) ligands (dtBubpy = 4,4'-di-tert-butyl-2,2'-bipyridyl). Three of the complexes were characterized by single-crystal X-ray structure analysis. In cyclic voltammetry, the complexes undergo reversible oxidation of iridium(III) and irreversible reduction of the SF5 group. They emit bright green phosphorescence in acetonitrile solution and in thin films at room temperature, with emission maxima between 482–519 nm and photoluminescence quantum yields of up to 7…
Operation and first results of the NEXT-DEMO prototype using a silicon photomultiplier tracking array
2013
NEXT-DEMO is a high-pressure xenon gas TPC which acts as a technological test-bed and demonstrator for the NEXT-100 neutrinoless double beta decay experiment. In its current configuration the apparatus fully implements the NEXT-100 design concept. This is an asymmetric TPC, with an energy plane made of photomultipliers and a tracking plane made of silicon photomultipliers (SiPM) coated with TPB. The detector in this new configuration has been used to reconstruct the characteristic signature of electrons in dense gas, demonstrating the ability to identify the MIP and "blob" regions. Moreover, the SiPM tracking plane allows for the definition of a large fiducial region in which an excellent e…
Optical pulling and pushing forces in bilayer PT-symmetric structures
2018
Photons are massless, yet can exert force on small particles. This $r\phantom{\rule{0}{0ex}}a\phantom{\rule{0}{0ex}}d\phantom{\rule{0}{0ex}}i\phantom{\rule{0}{0ex}}a\phantom{\rule{0}{0ex}}t\phantom{\rule{0}{0ex}}i\phantom{\rule{0}{0ex}}o\phantom{\rule{0}{0ex}}n$ $p\phantom{\rule{0}{0ex}}r\phantom{\rule{0}{0ex}}e\phantom{\rule{0}{0ex}}s\phantom{\rule{0}{0ex}}s\phantom{\rule{0}{0ex}}u\phantom{\rule{0}{0ex}}r\phantom{\rule{0}{0ex}}e$, though discussed by Kepler, still needs investigation for modern systems. This study reveals that the optical force exerted on a parity-time-symmetric bilayer with balanced gain and loss can be $a\phantom{\rule{0}{0ex}}s\phantom{\rule{0}{0ex}}y\phantom{\rule{0}{0…
Revealing Hidden Quantum Correlations in an Electromechanical Measurement.
2018
Under a strong quantum measurement, the motion of an oscillator is disturbed by the measurement back-action, as required by the Heisenberg uncertainty principle. When a mechanical oscillator is continuously monitored via an electromagnetic cavity, as in a cavity optomechanical measurement, the back-action is manifest by the shot noise of incoming photons that becomes imprinted onto the motion of the oscillator. Following the photons leaving the cavity, the correlations appear as squeezing of quantum noise in the emitted field. Here we observe such "ponderomotive" squeezing in the microwave domain using an electromechanical device made out of a superconducting resonator and a drumhead mechan…
Limiting neutrino magnetic moments with Borexino Phase-II solar neutrino data
2017
A search for the solar neutrino effective magnetic moment has been performed using data from 1291.5 days exposure during the second phase of the Borexino experiment. No significant deviations from the expected shape of the electron recoil spectrum from solar neutrinos have been found, and a new upper limit on the effective neutrino magnetic moment of $\mu_{\nu}^{eff}$ $<$ 2.8$\cdot$10$^{-11}$ $\mu_{B}$ at 90\% c.l. has been set using constraints on the sum of the solar neutrino fluxes implied by the radiochemical gallium experiments.Using the limit for the effective neutrino moment, new limits for the magnetic moments of the neutrino flavor states, and for the elements of the neutrino magne…
Contrail Formation: Analysis of Sublimation Mechanisms
2018
We study losses of ice crystals in a persistent, soot-rich contra i l in the wake behind a medium-sized aircraft at cru i se. Constrain i n g a model covering ice nucleation, growth, and subl i m a t i o n phases with a n aircraft data set, we track the subl i m a t i o n history over two minutes of cont r a i l age and rela t e ice crystal numbers to the number of soot particles emitted by th e aircraft engines.