Search results for "Meri"
showing 10 items of 7596 documents
Microheterogeneous electrocatalytic chiral recognition at monoclinic vanadium-doped zirconias: enantioselective detection of glucose.
2007
Synthetic tetragonal and monoclinic vanadium-doped zirconias (t- and m-VxZr1-xO2, 0.005x0.150) exert an effective catalytic effect toward the electrochemical oxidation of glucose in aqueous alkaline media. The catalytic effect of monoclinic specimens attached to carbon and fluorine-doped tin oxide electrodes exhibits a remarkable enantioselectivity, so that catalytic currents for the oxidation of L-glucose at +0.92 V vs AgCl/Ag are considerably larger than those obtained for the oxidation of D-glucose. This enantioselectivity can be associated with the existence of a noncentrosymmetric coordination of vanadium centers in the monoclinic crystalline form of zirconia. From the electrochemical …
New Self-Assembling Polyaspartamide-Based Brush Copolymers Obtained by Atom Transfer Radical Polymerization
2009
A simple and efficient method for the synthesis of polyaspartamide-based brush copolymers using Atom Transfer Radical Polymerization (ATRP) is here presented. The syntheses were performed by using two subsequent steps. In the first step the macroinitiator was obtained by the conjugation of a proper number of 2-bromoisobutyryl bromide (BIB) residues to the R, -poly(N-2-hydroxyethyl)-D,L-aspartamide (PHEA) side chains, obtaining the PHEA-BIB copolymer. PHEA-BIB copolymer was used as “multi-functional macroinitiator” for the polymerization via ATRP of hydrophilic methacrylic monomers, such as methacrylic acid (MA), obtaining PHEA-IB-poly(MA) copolymer, sodium methacrylate (MANa+), obtaining PH…
Novel water-swellable beads based on an acryloylated polyaspartamide
2001
Spherical polymeric microparticles have been prepared by a reverse-phase suspension polymerization technique. The starting polymer was α,β-poly (N-2-hydroxyethyl)-dl-aspartamide (PHEA) partially functionalised with glycidylmethacrylate (GMA) in order to introduce reactive vinyl groups in the side chain. The PHEA–GMA copolymer obtained (PHG) was cross-linked in a mixture of water/hexane–carbon tetrachloride in the presence of sorbitan trioleate (Span 85) as surfactant and ammonium persulfate/N,N,N′,N′-tetramethylethylenediamine as initiator system. The reaction was also carried out in the presence of N,N′-dimethylacrylamide as comonomer or N,N′-ethylenebisacrylamide as a cross-linking agent.…
Design, Synthesis and Evaluation of Enzyme-Responsive Fluorogenic Probes Based on Pyridine-Flanked Diketopyrrolopyrrole Dyes
2020
The ever-growing demand for fluorogenic dyes usable in the rapid construction of analyte-responsive fluorescent probes, has recently contributed to a revival of interest in the chemistry of diketopyrrolopyrrole (DPP) pigments. In this context, we have explored the potential of symmetrical and unsymmetrical DPP derivatives bearing two or one 4-pyridyl substituents acting as optically tunable group(s). The unique fluorogenic behavior of these molecules, closely linked to N-substitution/charge state of their pyridine unit (i.e., neutral pyridine or cationic pyridinium), has been used to design DPP-based fluorescent probes for detection of hypoxia-related redox enzymes and penicillin G acylase …
Novel pathways for the preparation of mesoporous MCM-41 materials: control of porosity and morphology
1999
Two novel synthesis routes for the preparation of mesoporous MCM-41 materials are introduced. Both methods use tetra-n-alkoxysilanes such as tetraethoxysilane (TEOS) or tetra-n-propoxysilane (TPS) as a silica source which are added to an aqueous solution of a cationic surfactant in the presence of ammonia as catalyst. In this study, n-alkyltrimethylammonium bromides and n-alkylpyridinium chlorides were employed as templates. The addition of an alcohol (e.g. ethanol or isopropanol) leads to a homogeneous system which allows the formation of spherical MCM-41 particles. The main advantages of these methods are short reaction times, excellent reproducibility and easy preparation of large batche…
Conformational investigations of bis(α-aminoalkyl)phosphinic acids and studies of the stability of their complexes with Cu(II)
2008
Abstract Conformational investigations of a group of bis(α-aminoalkyl)phosphinic acids were performed by use of NMR spectroscopy and theoretical calculations. In the case of one of the studied compounds, substituted with aminobenzyl and amino(p-chlorobenzyl) moieties, a pH-dependent equilibrium between conformers, stabilized by intermolecular hydrogen bonds was observed. Potentiometric studies proved that these molecules formed stable complexes with copper(II) ions, where stoichiometry was 1:1 and 1:2 depending on pH of their aqueous solution.
El nuevo escenario del orden público en el arbitraje : comentario a la STC de España, Sala Primera, núm. 17/2021, de 15 de febrero.
2021
The Constitutional Court delimits the concept and scope of public order, the requirement to state the grounds and the judicial review within the framework of the action for annulment of arbitral awards. The Constitutional Court rejects the jurisprudential line of the High Court of Justice of Madrid regarding the broadening of the concept of public policy and prevents the review of the merits of the case through the action for annulment.
The Windy clustered prize-collecting arc-routing problem
2011
This paper introduces the windy clustered prize-collecting arc-routing problem. It is an arc-routing problem where each demand edge is associated with a profit that is collected once if the edge is serviced, independent of the number of times the edge is traversed. It is further required that if a demand edge is serviced, then all the demand edges of its component are also serviced. A mathematical programming formulation is given and some polyhedral results including several facet-defining and valid inequalities are presented. The separation problem for the different families of inequalities is studied. Numerical results from computational experiments are analyzed. © 2011 INFORMS.
A 45-year sub-annual reconstruction of seawater temperature in the Bay of Brest, France, using the shell oxygen isotope composition of the bivalve Gl…
2020
A reconstruction of sea surface temperature (SST) spanning 45 years (1966–2011) was developed from δ18O obtained from the aragonitic shells of Glycymeris glycymeris, collected from the Bay of Brest, France. Bivalve sampling was undertaken monthly between 2014 and 2015 using a dredge. In total, 401 live specimens and 243 articulated paired valves from dead specimens were collected, of which 24 individuals were used to reconstruct SST. Temperatures determined using the palaeotemperature equation of Royer et al. compared well with observed SST during the growing season between 1998 and 2010 (Pearson’s correlation: p = 0.002, r = 0.760). Furthermore, a significant negative correlation was foun…
Terracotas en Terra Sigillata Hispánica. Reflexión a partir de un nuevo ejemplar en Augusta Emerita (Mérida, Badajoz)
2017
En este trabajo abordamos el estudio en clave iconográfca, funcional y cronológica de un ejemplar de terracota elaborado en Terra Sigillata Hispánica (TSH). Éste apareció en un contexto funerario en Augusta Emerita. Se trata de una fgura de bulto redondo mutilada y que presenta la peculiaridad de estar pintada, algo no muy frecuente en el repertorio de la TSH. Aprovechamos además la ocasión para plantear una nueva hipótesis interpretativa sobre este hallazgo como representación de una deidad oriental y analizamos otros ejemplares similares producidos en las otras fglinae peninsulares