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First discovery of orichalcum ingots from the remains of a 6th century BC shipwreck near Gela (Sicily) seabed
2017
Ingots recently recovered from the seabed near Gela, a major harbour of Sicily, reveal an unexpected side of ancient metallurgy. The ingots were found near remains of a ship and earthenware dated around the end of the VI century BC and probably coming from the eastern Mediterranean and the Aegean sea. The ingots were analysed by means of X-Ray Fluorescence spectroscopy via a portable spectrometer. Results indicate that they are mostly consist of copper and zinc although many of them have a significant amount of lead. This alloy is nowday called brass, but in ancient time it was know as orichalcum, one of the rarest and most precious alloy along with gold and silver. Only small items of oric…
Copper supply during the Final Neolithic at the Saint-Blaise/Bains des Dames site (Neuchâtel, Switzerland)
2009
The Saint-Blaise/Bains des Dames stratified site in Neuchâtel, Switzerland, contains several occupations that span the Late through Final Neolithic, including the Horgen, Lüscherz, and Auvernier-Cordé periods. As part of a study on prehistoric metallurgy in western Switzerland, we compare the lead isotope ratios (multicollector inductively coupled plasma mass spectrometer) and elemental compositions (instrumental neutron activation analysis) of the site's numerous copper finds to a database of corresponding measurements for copper ores throughout Europe. The results show a considerable variation in copper compositions present at the site, suggesting complex economic relationships and multip…
Captación y selección de materias primas en la primera metalurgia del Sureste de la península ibérica
2020
The authors are grateful for the technical and human support provided by SGIker of UPV/EHU and European funding (ERDF and ESF). We are also in debt with Eduardo Galán, Ruth Maicas and Carmen Cacho, curators of the Museo Arqueológico Nacional (Madrid) for facilitating the sampling and study of metal objects as well as with Ignacio Soriano Llopis for his help on the selection and sampling of the Palmela points, with Massimo Chiaradia who performed the analyses of the Palmela points at the Department of Earth Sciences (University of Geneva, Switzerland) and with Óscar García Vuelta for his pictures of some assemblages. We also appreciate and the careful work of editing and style of the TP edit…
Lead in the Bones of Cows from a Medieval Pb-Ag Metallurgical Settlement: Bone Mineralization by Metalliferous Minerals
2021
Pb contents (13-53 mg kg−1) and pathological changes in almost complete cow skeletonsdiscovered in graves adjacent to Pb and Ag smelting furnaces active in the Silesian-Cracovian region, in the mid-12th century are reported in the article. In addition to Pb,elements such as Zn, Cd, Fe, Mn, Cd, and Ba characteristic of Zn-Pb-Ag ores in the regionwere identified. Bone fragments and the soil in which they had lain for almost 800 yearswere examined by SEM, EDS. XRD was used to identify minerals present in soils. Theenrichment of the bones with Zn, Pb, Fe, Mn, and Cd is associated with the remobilisationof elements from soil contaminated with primary and synthetic phase-rich metals. In bioticmat…
The SISAL database: a global resource to document oxygen and carbon isotope records from speleothems
2018
Stable isotope records from speleothems provide information on past climate changes, most particularly information that can be used to reconstruct past changes in precipitation and atmospheric circulation. These records are increasingly being used to provide “out-of-sample” evaluations of isotope-enabled climate models. SISAL (Speleothem Isotope Synthesis and Analysis) is an international working group of the Past Global Changes (PAGES) project. The working group aims to provide a comprehensive compilation of speleothem isotope records for climate reconstruction and model evaluation. The SISAL database contains data for individual speleothems, grouped by cave system. Stable isotopes of oxyg…
A compositional analysis by energy dispersive X-ray fluorescence of Iberian copper-alloy votive figurines from southern Spain (fourth-third centuries…
2018
The metamorphic rocks of the Nunatak Viedma in the Southern Patagonian Andes: Provenance sources and implications for the early Mesozoic Patagonia-An…
2019
The Nunatak Viedma within the Southern Patagonian Icefield has been considered as a volcanic center based on its geomorphologic features, despite the fact that field explorations by Eric Shipton determined its metamorphic nature 70 years ago. We carried out fieldwork to characterize this isolated outcrop and performed the first U-Pb dating in detrital zircons from the basement rocks located inside the Southern Patagonian Icefield. We recognized very-low grade metamorphic rocks, corresponding principally to metapelites and metapsammites, and scarce metabasites. Detrital zircons in three metapsammitic samples (composite group of 240 grains) yielded prominent age population peaks at ∼1090, ∼96…
Soil physicochemical and microbial drivers of temperature sensitivity of soil organic matter decomposition under boreal forests
2020
Abstract Soil organic matter (SOM) in boreal forests is an important carbon sink. The aim of this study was to assess and to detect factors controlling the temperature sensitivity of SOM decomposition. Soils were collected from Scots pine, Norway spruce, silver birch, and mixed forests (O horizon) in northern Finland, and their basal respiration rates at five different temperatures (from 4 to 28 °C) were measured. The Q10 values, showing the respiration rate changes with a 10 °C increase, were calculated using a Gaussian function and were based on temperature-dependent changes. Several soil physicochemical parameters were measured, and the functional diversity of the soil microbial communit…
Local temperatures inferred from plant communities suggest strong spatial buffering of climate warming across Northern Europe
2013
Recent studies from mountainous areas of small spatial extent (2500 km(2) ) suggest that fine-grained thermal variability over tens or hundreds of metres exceeds much of the climate warming expected for the coming decades. Such variability in temperature provides buffering to mitigate climate-change impacts. Is this local spatial buffering restricted to topographically complex terrains? To answer this, we here study fine-grained thermal variability across a 2500-km wide latitudinal gradient in Northern Europe encompassing a large array of topographic complexities. We first combined plant community data, Ellenberg temperature indicator values, locally measured temperatures (LmT) and globally…
Change in dominance determines herbivore effects on plant biodiversity
2018
Herbivores alter plant biodiversity (species richness) in many of the world’s ecosystems, but the magnitude and the direction of herbivore effects on biodiversity vary widely within and among ecosystems. One current theory predicts that herbivores enhance plant biodiversity at high productivity but have the opposite effect at low productivity. Yet, empirical support for the importance of site productivity as a mediator of these herbivore impacts is equivocal. Here, we synthesize data from 252 large-herbivore exclusion studies, spanning a 20-fold range in site productivity, to test an alternative hypothesis—that herbivore-induced changes in the competitive environment determine the response …