Search results for "Metallic"
showing 10 items of 813 documents
Earth resistance measurements in urban contexts: Problems and possible solutions
2017
Both EN 50522 and IEEE Std. 81 propose the Fall of Potential Method (FPM) to carry out the measurement of the resistance to earth of an Earthing System (ES). However, in urban areas, the recommended distances between the ES and auxiliary electrodes are not easy to respect, due to the presence of buildings and tarmac. Moreover, unknown buried metallic parts, as well as the interconnection among the ESs made by the Distributor System Operator, could modify the earth potential profile of the area, affecting the measurement results. In this paper, the issues that could affect the measurement result if FPM is used in an urban context are presented. A parametric analysis, carried out with Comsol …
Liposomes modified by mono- and bis-phthalocyanines: A comprehensive EPR study.
2016
The impact of selected metallophthalocyanines, featuring diverse molecular structure, upon the fluidity of liposome membranes was studied using the spin label EPR technique. The “mono”-type MPc’s (M = Zn, Sn; Pc = C32H16N8 is the phthalocyanine ligand) and sandwich LnPc2 complexes (Ln = Nd, Sm, Gd) were explored. Liposomes were obtained in a sonication process, from egg yolk lecithin (EYL) in water. TEMPO and 16-DOXYL spin labels were used to monitor the peripheral and central part of the lipid double layer, respectively, which allowed to localize the phthalocyanine additive within the bilayer, as well as to perform independent measurements of changes in fluidity upon addition thereof. All …
Dix ans d'archéologie forestière dans le Châtillonnais (Côte-d'Or) : enclos, habitats, parcellaires
2010
National audience; Ces recherches sur les ensembles de structures de pierre sous forêt sont mises en œuvre depuis dix ans et sont inté- grées depuis 2003 dans le P.C.R. ‘Vix et son Environnement', dirigé par C. Mordant, S. Wirth et B. Chaume. Les vestiges étudiés sont implantés dans deux milieux géographiques distincts mais contigus : le plateau calcaire recouvert par la forêt domaniale de Châtillon, et les rebords de la Digeanne et du Brevon qui entaillent ce plateau à l'est et au sud. La prospection présente ici des caractères particuliers liés au couvert forestier. Les relevés G.P.S. sont intégrés dans un S.I.G. et constituent la base de cette étude, dans un va et vient…
Stellar populations of galaxies in the ALHAMBRA survey up toz ∼ 1
2018
Aims. We aim at constraining the stellar population properties of quiescent galaxies. These properties reveal how these galaxies evolved and assembled since z similar to 1 up to the present time. Methods. Combining the ALHAMBRA multi-filter photo-spectra with the fitting code for spectral energy distribution MUFFIT (MUlti-Filter FITting), we built a complete catalogue of quiescent galaxies via the dust-corrected stellar mass vs. colour diagram. This catalogue includes stellar population properties, such as age, metallicity, extinction, stellar mass, and photometric redshift, retrieved from the analysis of composited populations based on two independent sets of simple stellar population (SSP…
Mass-Metallicity Relation from Cosmological Hydrodynamical Simulations and X-ray Observations of Galaxy Groups and Clusters
2018
Recent X-ray observations of galaxy clusters show that the distribution of intra-cluster medium (ICM) metallicity is remarkably uniform in space and time. In this paper, we analyse a large sample of simulated objects, from poor groups to rich clusters, to study the dependence of the metallicity and related quantities on the mass of the systems. The simulations are performed with an improved version of the Smoothed-Particle-Hydrodynamics \texttt{GADGET-3} code and consider various astrophysical processes including radiative cooling, metal enrichment and feedback from stars and active galactic nuclei (AGN). The scaling between the metallicity and the temperature obtained in the simulations ag…
The origin of ICM enrichment in the outskirts of present-day galaxy clusters from cosmological hydrodynamical simulations
2018
The uniformity of the intra-cluster medium (ICM) enrichment level in the outskirts of nearby galaxy clusters suggests that chemical elements were deposited and widely spread into the intergalactic medium before the cluster formation. This observational evidence is supported by numerical findings from cosmological hydrodynamical simulations, as presented in Biffi et al. (2017), including the effect of thermal feedback from active galactic nuclei. Here, we further investigate this picture, by tracing back in time the spatial origin and metallicity evolution of the gas residing at z=0 in the outskirts of simulated galaxy clusters. In these regions, we find a large distribution of iron abundanc…
Multinuclear and Solid State NMR of Gels
2020
Over the past six decades, nuclear magnetic resonance spectroscopy has been an integral part of synthetic organic and organometallic chemistry, as well as biochemistry. Beyond solution state experiments, increasing developments have opened new avenues to study materials in their solid state. Between two extremes (i.e., solution and solid), there exist several other forms of materials, especially soft materials such as gels and liquid crystals. Traditionally gels have been studied using solution state NMR spectroscopic methods. However, the viscosity of complex viscoelastic fluids such as gels affects the molecular tumbling, which in turn affects the chemical shift anisotropy and dipolar and…
Reduction and catalytic behaviour of heterobimetallic copper–lanthanide oxides
2008
Abstract The reduction of the heterobimetallic copper–lanthanide oxides 2CuO·CeO2 and 3CuO·Ln2CuO4 (Ln = La, Pr, Nd) was studied by H2-TG/DTA and H2-TPR. All systems exhibit two main reduction steps accompanied by mass losses in the temperature range 20–1000 °C. The first step was attributed to CuO reduction, whereas the second step is due either to copper reduction in the Ln2CuO4 phase with the concomitant formation of Ln2O3 or to the surface reduction of CeO2. The products were characterized by XRD, SEM, EDX, and BET techniques and are better described as supported copper type materials. They were active for the mesityl oxide (4-methyl-2-penten-2-one) gas phase hydrogenation.
Active lighting applied to three dimensional reconstruction of specular metallic surfaces by polarization imaging
2005
This thesis deals with a new automated tridimensional inspection system for specular metallic surfaces, based on polarization analysis. We first present an extension of the ‘Shape from Polarization' method for dielectric to metallic surfaces. After being reflected, an unpolarized light wave becomes partially linearly polarized, depending on the surface normal and on the refractive index of the media it impinges on. Hence, by measuring the polarization parameters of the reflected light, the surface normals are computed. The ambiguity concerning the normals orientation is solved here with a new active lighting system. Then, we describe and compare numerical methods for reconstructing the trid…
Investigation of Activities for Pt-M Bimetallic Nanoparticles Catalysts on the Oxygen Reduction Reaction
2015
Bi-metallic Pt3Ni/C and Pt3Co/C electrocatalysts were successfully synthesized by a solvent free chemical vapour deposition method with a narrow particle size distribution. The results showed that the electrochemical surface area was increased by adding the additional Ni or Co to a pure Pt catalyst. Pt3Ni/C catalyst exhibited a significant enhancement of oxygen reduction reaction activity. The catalysts were characterized by EDS, XRD, HRTEM and electrochemical activity was determined using cyclic voltammetry.