Search results for "Metallurgy"
showing 10 items of 1419 documents
FIB-FESEM and EMPA results on Antoninianus silver coins for manufacturing and corrosion processes
2018
[EN] A set of ancient Antoninianus silver coins, dating back between 249 and 274¿A.D. and minted in Rome, Galliae, Orient and Ticinum, have been characterized. We use, for the first time, a combination of nano-invasive (focused ion beam-field emission scanning electron microscopy-X-ray microanalysis (FIB-FESEM-EDX), voltammetry of microparticles (VIMP)) and destructive techniques (scanning electron microscopy (SEM-EDX) and electron microprobe analysis (EMPA)) along with non-invasive, i.e., micro-Raman spectroscopy. The results revealed that, contrary to the extended belief, a complex Ag-Cu-Pb-Sn alloy was used. The use of alloys was common in the flourishing years of the Roman Empire. In th…
Nitrogen Adsorption on Graphene Sponges Synthesized by Annealing a Mixture of Nickel and Carbon Powders
2017
The present research has been supported by the National Research Programme for 2014–2017 “Multifunctional Materials and Composites, Photonics and Nanotechnologies”.
Modeling of the effect of EDTA on copper(II) biosorption onto Posidonia oceanica waste in batch and fixed-bed systems
2014
Abstract The performance of Posidonia oceanica for copper(II) biosorption in the presence of EDTA was investigated in batch and column experiments. In batch mode, copper(II) uptake in the presence of EDTA was lower than in its absence for the pH range 1.5–6.0. The decrease in the copper(II) uptake, attributed to the change in the chemical speciation of copper(II) with EDTA in solution, was from 71.7 to 58.8 mg/g in the absence and presence of EDTA respectively at pH 6. Column experiments were carried out at 5 and 20 mg Cu(II)/dm 3 and different doses of EDTA. Constant copper(II) leaks were detected in the effluent of the columns. Leak concentrations matched the copper(II)-EDTA complexes’ co…
Effect of welding and heat treatment on the properties of UHSS used in automotive industry
2021
This paper deals with the undesired effects of the heat treatments on the mechanical properties of (UHSS) Ultra High Strength Steel used nowadays in automotive industry to improve crashworthiness performance of vehicles. The UHSS specimens were extracted from certain parts of the car body and subjected to different heat treatments. Four types of specimens were tested: untreated, welded with metal inert gas welding, heat treated at 800 °C, and heat treated at 1250 °C. All heat-treated specimens showed dramatically reduced values of strength. The results suggest that it is important to follow the official repair manuals avoiding unnecessary welding and improper heat treatments of UHSS. The ex…
Using a neural network for qualitative and quantitative predictions of weld integrity in solid bonding dominated processes
2014
Solid-state bonding occurs in several manufacturing processes, as Friction Stir Welding, Porthole Die Extrusion and Roll Bonding. Proper conditions of pressure, temperature, strain and strain rate are needed in order to get effective bonding in the final component. In the paper, a neural network is set up, trained and used to predict the bonding occurrence starting from the results of specific numerical models developed for each process. The Plata-Piwnik criterion was used in order to define a quantitative parameter taking into account the effectiveness of the bonding. Excellent predictive capability of the network is obtained for each process.
Dual phase titanium alloy hot forging process design: experiments and numerical modeling
2015
Titanium alloys are considered desirable materials when both good mechanical properties and weight reduction are required at the same time. This class of materials is widely used in those fields (aeronautics, aerospace) in which common steels and light-weight materials, e.g., aluminum alloys, are not able to satisfy all operative service conditions. During the last decade, forging of titanium alloys has attracted greater attention from both industrial and scientific/academic researchers because of their potential in providing a near net shaped part with minimal need for machining. In this paper, a numerical model of the forging sequences for a Ti-6Al-4V titanium alloy aerospace component is…
Analytical bonding criteria for joint integrity prediction in friction stir welding of aluminum alloys
2014
Abstract In this study, two bonding criteria, previously used for porthole die extrusion, are applied to FSW starting from the local value of the main field variables calculated through a specifically developed 3D numerical model of the process. Their applicability and effectiveness have been assessed through an experimental and numerical campaign carried out with the main process parameters varying in a wide range. The pressure–time–flow criterion was demonstrated to be better suited for FSW processes when large welding speed is used.
Influence of M23C6 carbides on the heterogeneous strain development in annealed 420 stainless steel
2020
Understanding the local strain enhancement and lattice distortion resulting from different microstructure features in metal alloys is crucial in many engineering processes. The development of heterogeneous strain not only plays an important role in the work hardening of the material but also in other processes such as recrystallization and damage inheritance and fracture. Isolating the contribution of precipitates to the development of heterogeneous strain can be challenging due to the presence of grain boundaries or other microstructure features that might cause ambiguous interpretation. In this work a statistical analysis of local strains measured by electron back scatter diffraction and …
Cu-B alloy - analysis of use possibility as fuel cell cathode catalyst
2016
In recent years there has been a development of non-conventional and renewable sources of energy. One such sources of energy are fuel cells. Fuel cells are ecological and high efficiency sources of electric energy. However, the use of fuel cells on a large scale is limited, mainly by the high cost of catalysts. Platinum is most commonly used as the catalyst. But due to the high price of platinum there’s a need for finding other catalysts. Replacement of platinum will contribute to the fast development of green energy sources. This paper presents a study of possibility of using Cu-B alloy as catalyst for oxygen electrode in fuel cells. Researches were done in glass vessel, on a copper electr…
Microstructure and rheological response of laboratory-aged SBS-modified bitumens
2019
Polymer additives are widely used to improve the performance of road bitumens including their resistance to hardening during oxidation, although their oxidative inhibitor effect has not been well documented. This study aims to investigate the effect of laboratory-simulated ageing on the microstructure, and rheological properties of Polymer Modified Bitumens (PMBs) prepared with a Styrene-Butadiene-Styrene (SBS) copolymer and sulphur as a cross-linker. The laboratory ageing was conducted through the Rolling Thin Film Oven (RTFO) and the Pressure Aging Vessel (PAV) procedures. The unaged and aged binders were characterised using the Multiple Stress Creep and Recovery (MSCR) test, Gel Permeati…