Search results for "Metallurgy"

Microstructure-oxidation resistance relationship in Ti3AlC2 MAX phase

2020

International audience; Spark Plasma Sintering and Hot Isostatic Pressing were used to synthesize coarse-grained and fine-grained Ti3AlC2 specimens. Moreover, Spark Plasma Sintering processing parameters were modified in order to vary the TiC, Al2O3 and TixAly impurity and the porosity contents in the fine-grained samples. The influence of the Ti3AlC2 microstructure on the oxidation resistance was assesed. It is demonstrated that the grain size can drastically modify the oxidation resistance. The higher density of grain boundaries, in fine-grained specimens, increases the number of Al diffusion paths and leads to the formation of a protective alumina scale. In coarse-grained sample, Al diff…

Effects of Laboratory Aging on Properties of Biorejuvenated Asphalt Binders

2017

This paper presents the results from a laboratory investigation on the effects of aging on the properties of two binders recovered from two different sources of Reclaimed Asphalt (RA) and additivated with a biorejuvenator derived from pine trees. It has been already proven that the rejuvenators are able to restore some of the properties of the aged binder present in the RA, but nowadays their effects into the long-term period are not well known. In this regard, the rejuvenated asphalt binders and a virgin binder, defined as a target, have been aged artificially to simulate short-and long-term aging. All binders have been studied conducting physical, chemical, rheological, and performance-re…

Formation of anodic films on sputtering-deposited Al–Hf alloys

2009

Abstract The growth of barrier-type anodic films at high efficiency on a range of sputtering-deposited Al–Hf alloys, containing from 1 to 95 at.% Hf, has been investigated in ammonium pentaborate electrolyte. The alloys encompassed nanocrystalline and amorphous structures, the latter being produced for alloys containing from 26 to 61 at.% Hf. Except at the highest hafnium content, the films were amorphous and contained units of HfO 2 and Al 2 O 3 distributed relatively uniformly through the film thickness. Boron species were confined to outer regions of the films. The boron distributions suggest that the cation transport number decreases progressively with increasing hafnium concentration i…

Identification of overglaze and underglaze cobalt decoration of ceramics from Valencia(Spain) by portable EDXRF spectrometry

2004

The purpose of this work is the application of non-destructive analysis to differentiate underglaze and overglaze techniques used in the decoration of glazed ceramics from Valencia (Spain). This study was carried out by portable EDXRF spectrometry using an X-ray tube and a thermoelectrically cooled semiconductor detector. From the EDXRF spectra we have identified the main elements present in the tin-opacified lead glaze and in the cobalt pigments. The identification of the underglaze and overglaze decoration is based on the different ratios between the fluorescence line of the main component of the glaze (Pb-La line) and the fluorescence lines of the main components of the pigment (Co-Ka, M…

Modeling Corrosion of Archaeological Silver-Copper Coins Using the Voltammetry of Immobilized Particles

2012

Two complementary models to describe the long-term corrosion of silver-copper coins, based on potential rate laws for smooth corrosion and those combined with diffusive law, for gross corrosion, are proposed. Theoretical kinetics can be tested using signatures of copper and silver corrosion products using the voltammetry of immobilized particles technique. The method is applied to silver coins minted during the 13th–14th centuries from the Libertad street hoard in Valencia (Spain) using non-invasive one-touch graphite pencil sampling. Voltammetric features yield functional dependences in agreement with the proposed model potentially useful for distinguishing between different mints.

Real-Time Monitoring of Intergranular Corrosion Damage on AA2024

2017

The total porosity induced by the intergranular corrosion was selected as a monitoring parameter to follow in real-time the defect propagation of AA2024. The pertinence of eddy current (EC) probing has been tested on very thin foils of AA2024 (30 μm in thickness) in immersion conditions under potentiostatic control and in atmospheric conditions simulated by controlled salt spray experiments. Combining this nondestructive evaluation technique with a direct optical interrogation of the backside of the test specimen (derived from the foil penetration technique) allows one to discuss the contribution of both the dissolution in the depth and along the grain boundaries to the total porosity. In i…

Experimental Research of the Formability of Lightweight Metallic Materials Used in Automotive Industry

2015

This paper aims to study the plastic deformation behaviour of lightweight metallic materials in order to reduce the total weight of the vehicles without affecting their performances. For the theoretical and experimental researches presented here, among these materials the AZ31B magnesium alloy has been chosen, a representative alloy for the magnesium-zinc-aluminium alloy system. The results of the theoretical researches, made on finite elements models, were validated by means of experimental researches consisting of tensile tests, forming limit curves determination tests and AZ31B magnesium alloy drawing, respectively.

Tailoring of highly porous SnO2 and SnO2-Pd thin films

2019

Abstract Tin oxide is a material that attracts attention due to variety of technological applications. The main parameters that influence its properties are morphology, crystalline structure and stoichiometry. Researchers try to develop nanostructured thin films with tunable parameters that would conform its technological applications. Herein, we report on the preparation and characterization of highly porous SnO2 and Pd-doped SnO2 thin films. These films were deposited in the form of nanorods with controllable geometry. Such morphology was achieved by utilizing glancing angle deposition (GLAD) with assisted magnetron sputtering. This arrangement allowed preparation of slanted pillars, zig-…

Influence of electric field on thermo-chemical conversion of mixtures of straw pellets with coal

2018

Experimental Characterization of FSW T-Joints of Light Alloys

2007

Welding is playing a growing role in transport industry due to relevant advantages it allows. Friction Stir Welding is considered one of the most promising joining technologies, especially when it is applied to light alloys. Focusing attention on FSW of T-joints, several parameters have to be considered, and due to thermo-mechanical features of process, T joints need a dedicated approach. A set of previously developed experiments has shown that the tilt angle plays a relevant role in the joint strength. Furthermore it should be observed that T-joints are very often utilized in aerospace industries since the produced structures are composed of joined skins and stingers. Numerous data are rep…