Search results for "Metallurgy"
showing 10 items of 1419 documents
Large atomic disorder in nanostructured LaNi5 alloys: A la L3-edge extended X-ray absorption fine structure study
2010
Abstract Local structure of the nanostructured LaNi 5 alloys, prepared by ball-milling, has been studied using La L 3 -edge extended X-ray absorption fine structure spectroscopy. The near-neighbor distances tend to decrease with the ball-milling, and the mean square relative displacements (MSRD) show substantial increase suggesting an increased atomic disorder. High temperature annealing helps in partial recovery of atomic order in the ball-milled samples for milling times upto 20 h, however, the long-time ball-milled samples seems to gain only a local random order. The results suggest that reduced unit-cell volume together with large atomic-disorder might be causing a higher energy-barrier…
Internal-variable constitutive model for rate-independent plasticity with hardening saturation surface
1998
An elastic-plastic material model with internal variables and thermodynamic potential, not admitting hardening states out of a saturation surface, is presented. The existence of such a saturation surface in the internal variables space — a consequence of the boundedness of the energy that can be stored in the material's internal micro-structure — encompasses, in case of general kinematic/isotropic hardening, a one-parameter family of envelope surfaces in the stress space, which in turn is enveloped by a limit surface. In contrast to a multi-surface model, noad hoc rules are required to avoid the intersection between the yield and bounding/envelope surface. The flow laws of the proposed mode…
Mechanical and cohesion properties of brass plated steel cords in a sulphurizing environment
1986
The mechanical and cohesion properties of brass plated steel cords have been investigated in dry hydrogen sulphide between 25 and 450° C. The extents of elastic and plastic regions, obtained from slow strain rate technique data have been defined, and the preferential site of decohesion tends to be the brass-steel interface.
Microstructure and phase composition of bronze Montefortino helmets discovered Mediterranean seabed to explain an unusual corrosion
2021
AbstractTwo Monterfortino helmets, recovered in the Mediterranean seabed, show unusual features with respect to the more common helmets of the same period and found in underwater environments. Hence, they were investigated by a multi-analytical approach, which allowed us to identify the compounds constituting the helmets and to make some considerations about their metallurgy, although all the metal was converted to degradation products. The helmets, originally made in bronze, have maintained their original shape because of copper sulphides formation. The observed differences in composition between the two helmets were attributed to the position modification, of one of them, into the seabed …
The sea–air exchange of mercury (Hg) in the marine boundary layer of the Augusta basin (southern Italy): Concentrations and evasion flux
2013
Abstract The first attempt to systematically investigate the atmospheric mercury (Hg) in the MBL of the Augusta basin (SE Sicily, Italy) has been undertaken. In the past the basin was the receptor for Hg from an intense industrial activity which contaminated the bottom sediments of the Bay, making this area a potential source of pollution for the surrounding Mediterranean. Three oceanographic cruises have been thus performed in the basin during the winter and summer 2011/2012, where we estimated averaged Hg atm concentrations of about 1.5 ± 0.4 (range 0.9–3.1) and 2.1 ± 0.98 (range 1.1–3.1) ng m −3 for the two seasons, respectively. These data are somewhat higher than the background Hg atm …
Dynamical features of forest interactions
2000
Abstract The 3D computer simulations presented here were developed to study at the mesoscopic scale the formation of junctions and their impact on hardening of crystals. The simulations consider the evolution of a dislocation interacting with immobile dislocations in a fcc single crystal of copper where we incorporate well known dislocation interaction mechanisms. From these studies, we deduced a `breaking angle' which characterize the strength of the junctions.
Dilatometric Characterization of Micrograined Metallic Powders
1995
ChemInform Abstract: NbNi2.38Te3, a New Metal-Rich Niobium Telluride with a “Stuffed” TaFe1+ xTe3 Structure.
2010
The authors report the synthesis, structure, and electrical properties of NbNi{sub 2.38}Te{sub 3}. The structure of the compound was determined by X-ray crystallography and the electric conductivity of the compound was measured.
Electrochemical Age Determinations of Metallic Specimens—Utilization of the Corrosion Clock
2019
Dating needs an age-dependent phenomenon (a "clock"), a procedure for monitoring the advance of time by measuring a physicochemical quantity, and, in the case of archeological artifacts, a sampling procedure that guarantees the representativity and integrity of the dated objects. Metal corrosion in an aerobic atmosphere is a phenomenon whose advance can in principle be used as a clock that depends on the environmental conditions. In spite of the limitation imposed by differences in local conditions of corrosion, a new approach for age determinations has been developed and applied as a feasible tool for age determinations of metallic specimens studied by archeologists and historians. These t…