Search results for "Metals"
showing 10 items of 2013 documents
Crystal structures of new ternary compounds in RE–Pt–Pb and RE–Au–Pb systems (RE=rare earth metal)
2012
Abstract The crystal structures of the compounds RE 2 Pt 2 Pb (RE = Y, La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; Mo 2 FeB 2 structure type, space group P 4/ mbm , Pearson code tP10 ), REPtPb (RE = La, Ce, Pr, Nd, Sm; ZrNiAl structure type, space group P 6 ¯ 2 m , Pearson code hP9 ), RE 2 Au 2 Pb (RE = Y, La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; Er 2 Au 2 Sn structure type, space group P 4 2 / mnm , Pearson code tP20 ) and REAuPb (RE = Tm, Yb and Lu) were determined using X-ray powder diffraction.
Early-stage detection of surface stress corrosion cracking at the subgranular level
2014
The strain field at the interface between an alloy and its oxide layer has been mapped using nanopatterned gauges resistant to the environment of the primary nuclear medium. It was found that oxidation has decreased the alloy ductility, thereby enabling some grain boundary opening to be detectable from 1.8 % strain. It is shown that statistics of extreme rare events of hotspots quantify the occurrence of the local opening of intergranular cracks, and thereby the ageing process.
Local analysis of the mechanical behaviour of inclusions-containing stainless steels under straining conditions
2003
Abstract A numerical method is described for determining the surface stress distribution under straining conditions from the real microstructure of materials containing local heterogeneities. The method is applied to resulfurized steels with a high density of MnS and oxide inclusions. The results are compared to those obtained from surface observations.
Immobilization and controlled release of prostaglandin E2 from poly-L-lactide-co-glycolide microspheres.
2009
Prostaglandin E(2) (PGE(2)) is an arachidonic acid metabolite involved in physiological homeostasis and numerous pathophysiological conditions. Furthermore, it has been demonstrated that prostaglandins have a stimulating effect not only on angiogenesis in situ and in vitro but also on chondrocyte proliferation in vitro. Thus, PGE(2) represents an interesting signaling molecule for various tissue engineering strategies. However, under physiological conditions, PGE(2) has a half-life time of only 10 min, which limits its use in biomedical applications. In the present study, we investigated if the incorporation of PGE(2) into biodegradable poly-L-lactide-co-glycolide microspheres results in a …
Rapid one-pot propargylamine synthesis by plasmon mediated catalysis with gold nanoparticles on ZnO under ambient conditions
2013
Surface plasmon excitation of gold nanoparticles on ZnO in the presence of an aldehyde, an amine and phenylacetylene led to rapid and selective formation of propargylamines with good yields (50-95%) at room temperature. Plasmon mediated catalysis is the best available route for this ternary coupling.
Comparative assessment of surface roughness produced by hard machining with mixed ceramic tools including 2D and 3D analysis
2005
Abstract This paper provides a new comprehensive analysis of part surface finish in continuous dry turning of a hardened construction steel when using mixed alumina cutting tools. Consequently, the surface profiles (2D arragement) and surface microstereometries (3D arragement) generated during different hard part turning operations on a 40H low chromium alloy steel (equivalent to AISI 5140 or DIN 41Cr4), heat treated to the hardness of about 60 HRC, were evaluated. As a result, this paper aggregates the multi-parameters characterization of the surface roughness with the machined surface structure obtained at the three selected feed rates and constant cutting speed of 100 m/min. Results show…
Computer simulation of metal flow in the hot upsetting of a high-strength aluminium alloy
1993
Abstract The effects of metal-working temperature on the hot axisymmetric upsetting of AA 7012 aluminium alloy were investigated in the temperature range of from 250 to 400°C, at a strain rate of 4 s −1 . The material behaviour was studied by means of simulative methods based on the analysis of torsion-test results which have shown that when the strain increases, the flow stress increases to a peak value and then decreases to a fracture value. Furthermore, the flow stress decreases with decreasing strain rate and with increasing temperature. Constitutive equations, describing accurately the hot deformation behaviour of the material, were defined and used subsequently in a numerical model th…
Dense nanostructured materials obtained by spark plasma sintering and field activated pressure assisted synthesis starting from mechanically activate…
2004
The preparation of highly dense bulk materials with a grain size in the range of a few to a few hundreds nanometers is currently the objective of numerous studies. In our research we have achieved a measure of success in this regard by using the methods of mechanically-activated, field-activated, pressure-assisted synthesis, MAFAPAS, which has been patented, and mechanically-activated spark plasma sintering, MASPS. Both methods, which consist of the combination of a mechanical activation step followed by a consolidation step under the simultaneous influence of an electric field and mechanical pressure, have led to the formation of dense nanostructured ceramics, intermetallics, and composite…
On the influence of tool path in friction stir spot welding of aluminum alloys
2008
Abstract Friction stir spot welding (FSSW) has been proposed as an effective technology to spot weld the so-called “difficult to be welded” metal alloys. In the paper, a variation of the FSSW process has been considered. A tool path is given after the sinking phase nearby the initial penetration site; in this way a larger welding spot is obtained and more material is involved in the bonding process. The process mechanics of such modified FSSW process is highlighted and the joint strength undergoing tensile tests is considered at the varying both of the assigned tool path and of a few process parameters. Macro- and micro-analyses are made in order to analyze the local material microstructure…
On microstructural phenomena occurring in friction stir welding of aluminium alloys
2006
Abstract The results of experimental activity on friction stir welding (FSW) of aluminum alloys are reported. Butt joints of two different materials, namely AA2024-T4 and AA7075-T6, were investigated from a metallurgical point of view. Grain dimensions and insoluble particle densities were investigated both in the parent materials and in the joints. Furthermore, the effect of post-welding heat treatments on the joint strength was studied.