Search results for "Metals"
showing 10 items of 2013 documents
WEAR PERFORMANCE OF CERAMIC CUTTING-TOOL MATERIALS WHEN CUTTING STEEL
1991
Abstract Some test cycles have been carried out in continuous cutting conditions, employing cutting parameters (feed, depth of cut and cutting speed) chosen following experimental planes and suitable test fields. The wear tests have been carried out on AISI 1040 steel with cutting speeds from 5m/sec to 11m/sec. The silicon nitride, sintered carbide, cubic boron nitride and alumina reinforced with SiC whiskers inserts, have shown, at each assigned cutting parameter, poor wear resistance when cutting steel. Alumina and alumina in submicron grain, which has been toughened by ZrO2 phase transformation, and the oxide-based alumina, have been the better wear resistance. The mixed based alumina ha…
Physical chemistry of the powder metallurgy of beryllium: Chemical characterization of the powder in relation to its granularity
1996
Combining the systematic quantitative chemical analysis of the light impurities H, C, N, and O, the quantitative thermal desorption of molecular H2O and H2, and X ray diffractometry of various size fractions of a commercial Be powder (SP-65 grade from Brush-Wellman) allowed the precise de-termination of the mean composition and equivalent mean thickness of the surface impurity phases in the passivation-contamination layer on the surface of the particles. The overall surface stoichi-ometry is as follows: 0.2 BeOcrystallized, 0.8 [BeO - 0.59 H2O]amorphous, 0.14 H2Oads The result of the elemental analysis by X-ray photoelectron spectroscopy of the unetched surface of a powder pellet is compare…
Composite layer-based analytical models for tool–chip interface temperatures in machining medium carbon steels with multi-layer coated cutting tools
2006
Abstract This investigation is devoted to the thermal problems in dry orthogonal turning of a C45 medium carbon steel with natural contact tools treated with multi-layer coatings with an intermediate Al 2 O 3 layer. New hybrid analytical models for estimating heat partition to the chip and the tool–chip interface temperatures were proposed. Furthermore, the physics-based modelling concept, which applies composite layer approach was developed to estimate the average and maximum steady-state tool–chip interface temperatures in orthogonal turning. The model predictions were compared to appropriate experimental process data using natural tool-work thermocouples and other simulated and measured …
Amorphous and crystalline polyetheretherketone: Mechanical properties and tissue reactions during a 3-year follow-up.
2007
The study was aimed to test the mechanical strength, structural stability, and tissue reactions of optically amorphous and crystalline polyetheretherketone (PEEK) plates during a 3-year follow-up in vivo and in vitro. The injection-moulded PEEK plates were implanted to the dorsal subcutis of 12 sheep, which were sacrificed at 6-156 weeks. Thereafter, the plates were subjected to tensile tests, and levels of crystallinity were assessed by differential scanning calorimetry (DSC). Histological evaluation was carried out using the paraffin technique. In vitro properties were examined with the tensile test and DSC at 0-156 weeks. Tissue reactions were mild and fairly similar for the amorphous an…
One step continuous hydrothermal synthesis of very fine stabilized superparamagnetic nanoparticles of magnetite
2011
International audience; Stable suspensions of citrated SPIO nanoparticles were synthesised in one step using a hydrothermal continuous process. Citrates control the crystallite size and the oxidation degree of metallic ions despite the very short reaction time (4 s). Magnetite particles, Fe2.94O4, with an average size of 4 nm and good monodispersity were obtained.
Microstructure-oxidation resistance relationship in Ti3AlC2 MAX phase
2020
International audience; Spark Plasma Sintering and Hot Isostatic Pressing were used to synthesize coarse-grained and fine-grained Ti3AlC2 specimens. Moreover, Spark Plasma Sintering processing parameters were modified in order to vary the TiC, Al2O3 and TixAly impurity and the porosity contents in the fine-grained samples. The influence of the Ti3AlC2 microstructure on the oxidation resistance was assesed. It is demonstrated that the grain size can drastically modify the oxidation resistance. The higher density of grain boundaries, in fine-grained specimens, increases the number of Al diffusion paths and leads to the formation of a protective alumina scale. In coarse-grained sample, Al diff…
A model of biomass char gasification describing the change in catalytic activity of ash
2012
A comprehensive description of catalytic effects during char gasification under various conditions relevant to biomass gasification was made. A three-parallel reaction model was proposed to describe the dynamic change in catalytic activity of ash during gasification of biomass char particles. Three different regimes of conversion were identified by analyzing char reactivity experiments conducted in a vertical TGA with nine biomasses under a wide range of operating conditions (temperature: 1023–1123 K, pressure: 0.1–3.0 MPa and gasification mixtures of CO2–CO–H2O–H2): (1) catalytic char gasification with deactivation of catalyst, (2) non-catalytic char gasification, and (3) catalytic char ga…
Energy structure and electro-optical properties of organic layers with carbazole derivative
2014
Abstract Phosphorescent organic light emitting diodes are perspective in lighting technologies due to high efficient electroluminescence. Not only phosphorescent dyes but also host materials are important aspect to be considered in the devices where they are a problem for blue light emitting phosphorescent molecules. Carbazole derivative 3,6-di(9-carbazolyl)-9-(2-ethylhexyl)carbazole (TCz1) is a good candidate and has shown excellent results in thermally evaporated films. This paper presents the studies of electrical properties and energy structure in thin films of spin-coated TCz1 and thermally evaporated tris[2-(2,4-difluorophenyl)pyridine]iridium(III) (Ir(Fppy)3). The 0.46 eV difference …
A modular approach towards functional supramolecular aggregates - subtle structural differences inducing liquid crystallinity.
2016
Herein we report an efficient modular approach to supramolecular functional materials. Hierarchical self-assembly of azopyridine derivatives and hydrogen-bond donors yielded discotic assemblies. Subtle differences in the core units introduced mesomorphic behaviour and fast photo-response of the liquid crystals based on phloroglucinol. The presented results prove the benefits of a modular methodology towards highly responsive materials with tailor-made properties.
Effect of driving method on the degradation of organic light emitting diodes
2003
Abstract Lifetime testing results are reported for organic light emitting diodes (OLEDs) having the structure ITO (anode)/ N , N ′-diphenyl- N , N ′-bis(3-methylphenyl)-1,1′-diphenyl-4,4′-diamine (TPD)/tris-(8-hydroxyquinoline)aluminum (AlQ)/Al (cathode) and operated using dc and pulsed waveforms for comparison. In ambient atmosphere non-encapsulated devices show a lifetime of about 70 h in pulsed operation at an initial luminance of 500 cd/m 2 , almost four times longer than in dc operation. A fast initial decay of luminance is observed for dc operation. It is most probably due to a combination of Joule heating and mobile ionic impurities migration within the OLED structure under the conti…