Search results for "Metals"
showing 10 items of 2013 documents
TeO2-ZnO-La2O3 tellurite glass system investigation for mid-infrared robust optical fibers manufacturing
2021
Abstract TeO2-ZnO-La2O3 (TZL) ternary glasses were investigated in order to manufacture step-index optical fibers with low optical losses in the near- and mid-infrared ranges and superior mechanical properties. To identify appropriate TZL glass compositions for optical fibers manufacturing, the whole vitreous domain of the ternary diagram was explored by characterizing bulk samples from thermal and optical point of view. Investigations were focused on understanding how the refractive index evolves as a function of the composition. For this, several parameters were analyzed such as density, molar volume, oxygen packing density, molar refractivity, polarizability and optical basicity. Finally…
A frequency-output fiber optic voltage sensor with temperature compensation for power systems
2003
Abstract We present a frequency-output fiber optic voltage sensor for power systems with temperature compensated response. The sensor employs PZT-type ceramic tubes, which are interrogated by a length of single-mode fiber coiled onto the tubes and a Mach–Zehnder interferometer. The combination of piezoelectric tubes with properties exhibiting opposite behavior to temperature changes is successfully exploited to passively compensate the temperature sensitivity of the sensor. The prototype reported here exhibits a resolution of 13 mV rms and the deviations of the sensor’s response due to temperature changes are within 1% over the temperature range between −30 and 70 °C. The device presented h…
Absorption Properties of Metal–Semiconductor Hybrid Nanoparticles
2011
The optical response of hybrid metal-semiconductor nanoparticles exhibits different behaviors due to the proximity between the disparate materials. For some hybrid systems, such as CdS-Au matchstick-shaped hybrids, the particles essentially retain the optical properties of their original components, with minor changes. Other systems, such as CdSe-Au dumbbell-shaped nanoparticles, exhibit significant change in the optical properties due to strong coupling between the two materials. Here, we study the absorption of these hybrids by comparing experimental results with simulations using the discrete dipole approximation method (DDA) employing dielectric functions of the bare components as input…
The application of AI techniques in the optimal design of multi-pass cold drawing processes
2001
Abstract In the paper the problem of optimal pass schedule design in multi-pass wire drawing process is investigated. An automatic design procedure based on an effective artificial intelligence (AI) technique, namely simulated annealing (SA), is proposed. The developed algorithm is aimed to achieve a satisfactory balance of the drawing stresses on the material along the reduction sequence, maintaining in the meantime the drawing stress at each pass below a safety value. In this way both the optimal number of passes and the optimal drawing sequence are determined. The effectiveness of the design procedure is tested through the comparison of the sequences suggested by the algorithm with a set…
Untreated Opuntia ficus indica for the Efficient Adsorption of Ni(II), Pb(II), Cu(II) and Cd(II) Ions from Water
2023
The raw cladode of Opuntia ficus indica (OFI) was evaluated as a sustainable biosorbent for the removal of heavy metals (Ni, Pb, Cu, and Cd) from aqueous solutions. The functional groups of OFI were identified by employing DRIFT-FTIR and CP-MAS-NMR techniques before and after contact with the ions in an aqueous media, showing a rearrangement of the biomass structure due to the complexation between the metal and the functional groups. The adsorption process was studied in both single- and multi-component systems under batch conditions at different pHs (4.0, 5.0, and 6.0), different metal concentrations, and different biomass amounts. The results show that the raw OFI had a removal capacity a…
(o-Phenyleno)naphthalene diimides: a pink fluorescent chromophore
2017
(o-Phenyleno)naphthalene dianhydride 7 was synthesized by a six-step reaction. Imidizations of 7 led to various diimides 8. Their optical and electrochemical properties hold promise for organic electronics.
Determination of charge carrier mobility of hole transporting polytriarylamine-based diodes
2010
Hole transport properties of three different side chain poly(triarylamines) have been determined by means of the analysis of steady-state current-voltage characteristics using co-planar diode structures. The interpretation is based on space-charge limited models with field-dependent mobility. Mobilities between ~ 10- 8 and 10- 6 cm2 V- 1 s- 1 are obtained. The highest mobility is achieved for poly(tetraphenylbenzidine) devices and the lowest for poly(triphenylamine) devices. Electron-rich methoxy substituents increase the mobility of poly(triphenylamine)s. A comparison of the mobility values with those obtained using organic field-effect transistors is also given. © 2009 Elsevier B.V. All r…
Efficient deep-red light-emitting electrochemical cells based on a perylenediimide-iridium-complex dyad
2009
A two-layer light-emitting electrochemical cell device based on a new perylenediimide-iridium-complex dyad is presented emitting in the deep-red region with high external quantum efficiencies (3.27%). Costa Riquelme, Ruben Dario, Ruben.Costa@uv.es ; Orti Guillen, Enrique, Enrique.Orti@uv.es ; Bolink, Henk, Henk.Bolink@uv.es ; Gierschner, Johannes, Johannes.Gierschner@uv.es
Polymer solar cells with novel fullerene-based acceptor
2004
Abstract Alternative acceptor materials are possible candidates to improve the optical absorption and/or the open circuit voltage of polymer–fullerene solar cells. We studied a novel fullerene-type acceptor, DPM-12, for application in polymer–fullerene bulk heterojunction photovoltaic devices. Though DPM-12 has the identical redox potentials as methanofullerene PCBM, surprisingly high open circuit voltages in the range V OC =0.95 V were measured for OC 1 C 10 -PPV:DPM-12-based samples. The potential for photovoltaic application was studied by means of photovoltaic characterization of solar cells including current–voltage measurements and external quantum yield spectroscopy. Further studies …
Demand for life annuities from married couples with a bequest motive
2006
The aim of this paper is to explain the ‘annuities puzzle’ in greater depth by introducing the bequest motive. It will try to determine whether this motive really is a relevant feature influencing the demand for life annuities from married couples. With this aim in mind, we develop an optimization model of the utility provided by purchasing a life annuity with contingent survivor benefit or a joint survivor life annuity. Our model is based on that first put forward by Brown and Poterba (2000), to which we have added elements from other models, such as Friedman and Warshawsky's (1990) and Vidal and Lejárraga's (2004), which include the bequest motive. This will enable us to calculate the ann…