Search results for "Methylene"

showing 10 items of 821 documents

CCDC 1014200: Experimental Crystal Structure Determination

2014

Related Article: Hai Yi, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|New J.Chem.|39|746|doi:10.1039/C4NJ01654H

11'-((22'33'55'66'-octafluorobiphenyl-44'-diyl)bis(methylene))bis-4-aza-1-azoniabicyclo[2.2.2]octane dibromideSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 816417: Experimental Crystal Structure Determination

2017

Related Article: Dieter Schollmeyer, Heiner Detert|2017|Tetrahedron Lett.|58|843|doi:10.1016/j.tetlet.2017.01.040

112455-hexachloro-3-(dichloromethylene)penta-14-dieneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 684679: Experimental Crystal Structure Determination

2009

Related Article: H.Detert, D.Lenoir, H.Zipse|2009|Eur.J.Org.Chem.|2009|1181|doi:10.1002/ejoc.200801076

1234-Tetrachloro-5-(dichloromethylene)-13-cyclopentadieneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Short X···N Halogen Bonds With Hexamethylenetetraamine as the Acceptor

2021

Hexamethylenetetramine (HMTA) and N-haloimides form two types of short (imide)X···N and X–X···N (X = Br, I) halogen bonds. Nucleophilic substitution or ligand-exchange reaction on the peripheral X of X–X···N with the chloride of N-chlorosuccinimide lead to Cl–X···N halogen-bonded complexes. The 1:1 complexation of HMTA and ICl manifests the shortest I···N halogen bond [2.272(5) Å] yet reported for an HMTA acceptor. Two halogen-bonded organic frameworks are prepared using 1:4 molar ratio of HMTA and N-bromosuccinimide, each with a distinct channel shape, one possessing oval and the other square grid. The variations in channel shapes are due to tridentate and tetradentate (imide)Br···N coordi…

116 Chemical scienceschemistry.chemical_elementHMTAN-haloimidechemistry.chemical_compoundkemialliset sidoksethalogen bond. hexamethylenetetraamine. N-haloimide.Nucleophilic substitutionsupramolekulaarinen kemiaQD1-999orgaaniset yhdisteetOriginal ResearchInterhalogenHalogen bondBrominehalogeenitChemistryhexamethylenetetraaminehalogen bond. hexamethylenetetraamine. N-haloimideGeneral ChemistryAcceptorChemistryCrystallographyCovalent bondinterhalogenHalogendihalogenhalogen bondHexamethylenetetramine
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Colorimetric quantitation of trace amounts of sodium lauryl sulfate in the presence of nucleic acids and proteins

1992

A fast and sensitive procedure for the colorimetric detection of sodium lauryl sulfate (SDS) is presented. The assay is based upon the formation of a chloroform-extractable ion pair between lauryl sulfate and methylene blue that is quantified spectrophotometrically with an estimated detection limit of 150 ng of SDS. The method is suitable for the monitoring of contaminating traces of SDS in protein or nucleic acid samples that have the potential to interfere with enzymatic manipulations such as proteolytic digest, restriction analysis, or reverse transcription. Since the procedure is extremely simple and no special equipment is required it is accessible to every researcher concerned with SD…

1303 BiochemistryTrace AmountsSodiumBiophysicschemistry.chemical_element10050 Institute of Pharmacology and Toxicology610 Medicine & healthBiochemistry1307 Cell Biologychemistry.chemical_compoundNucleic Acids1312 Molecular BiologyAnimalsSulfateColorimetryMolecular BiologyDetection limitChromatographyProteinsSodium Dodecyl SulfateCell BiologyDNAReference StandardsRatsMethylene BluechemistryNucleic acidRNA570 Life sciences; biologyCattleColorimetryQuantitative analysis (chemistry)Methylene blue1304 Biophysics
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CCDC 741667: Experimental Crystal Structure Determination

2009

Related Article: J.Zhao, V.Bohmer, M.Bolte|2009|Acta Crystallogr.,Sect.E:Struct.Rep.Online|65|o1658|doi:10.1107/S1600536809023344

22'-Dimethyl-22'-(m-phenylenedimethylene)propanedinitrileSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1554869: Experimental Crystal Structure Determination

2019

Related Article: Wenqian Shan, Valentin Quesneau, Nicolas Desbois, Virginie Blondeau-Patissier, Mario L. Naitana, Yoann Rousselin, Claude P. Gros, Zhongping Ou, Karl M. Kadish|2019|J.Porphyrins Phthalocyanines|23|213|doi:10.1142/S1088424619500214

25-bis((4-bromophenyl)(5-((4-bromophenyl)pyrrol-2-ylmethylidene)pyrrol-2-yl)methylene)pyrrole chloroform solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 658271: Experimental Crystal Structure Determination

2008

Related Article: K.Salorinne, M.Nissinen|2008|Tetrahedron|64|1798|doi:10.1016/j.tet.2007.11.103

281420-Tetraethyl-6121824-tetramethoxy-410:1622-bis(22'-(p-phenylenebis(methyleneoxy-o-phenoxy)diethoxy))calix(4)arene chloroform solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1414524: Experimental Crystal Structure Determination

2016

Related Article: Vanessa Soto-Cerrato, Pilar Manuel-Manresa, Elsa Hernando, Silvia Calabuig-Fariñas, Alicia Martínez-Romero, Víctor Fernández-Dueñas, Kristoffer Sahlholm, Thomas Knöpfel, María García-Valverde, Ananda M. Rodilla, Eloisa Jantus-Lewintre, Rosa Farràs, Francisco Ciruela, Ricardo Pérez-Tomás, and Roberto Quesada|2015|J.Am.Chem.Soc.|137|15892|doi:10.1021/jacs.5b09970

2-((hexylamino)methylene)-5-(1H-indol-2-yl)-3-methoxy-2H-pyrrolium chlorideSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Chiral Serum Pharmacokinetics of 4-Fluoroamphetamine after Controlled Oral Administration

2021

Abstract Over the last two decades, misuse of 4-fluoroamphetamine (4-FA) became an emerging issue in many European countries. Stimulating effects last for 4–6 hours and can impact psychomotor performance. The metabolism of amphetamine-type stimulants is stereoselective and quantification of (R)- and (S)-enantiomers has been suggested for assessing time of use. To date, no data on enantioselective pharmacokinetics is available for 4-FA in serum samples. An enantioselective liquid chromatography−tandem mass spectrometry (LC–MS-MS) method was developed using a chiral Phenomenex® Lux 3 μm AMP column. Validation of the method showed satisfactory selectivity, sensitivity, linearity (0.5–250 ng/mL…

3SAMPLESHealth Toxicology and MutagenesisNETHERLANDSAdministration OralAMPHETAMINEMETABOLISMMETHAMPHETAMINEToxicology01 natural sciencesSTEREOSELECTIVE PHARMACOKINETICSAnalytical Chemistry03 medical and health sciences4-Fluoroamphetamine0302 clinical medicinePharmacokineticsTandem Mass SpectrometryOral administrationmedicineHumansEnvironmental ChemistryIngestion030216 legal & forensic medicineChemical Health and SafetyChromatography34-METHYLENEDIOXYMETHAMPHETAMINEChemistryAmphetamines010401 analytical chemistryTRANSPORTERStereoisomerism4-METHYLENEDIOXYMETHAMPHETAMINESerum samples0104 chemical sciencesStereoselectivityFLUOROAMPHETAMINEEnantiomerPSYCHOACTIVE SUBSTANCES NPSTime of useChromatography Liquidmedicine.drugJournal of Analytical Toxicology
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