Search results for "Methylene"

showing 10 items of 821 documents

Factor V Leiden, C>T MTHFR Polymorphism and Genetic Susceptibility to Preeclampsia

1997

SummaryWe performed a case-controlled study to investigate whether the FV Leiden mutation and the C>T677 polymorphism of the 5,10 methylene tetrahydrofolate reductase (MTHFR) are associated with the occurrence of preeclampsia in 96 otherwise healthy preeclamptic women and 129 parous women as controls. FV Leiden carriers were 10 (10.5%) in cases and 3 (2.3%) in controls (OR: 4.9, 95% Cl: 1.3-18.3). MTHFR TT homozygotes were 28 (29.8%) in cases and 24 (18.6%) in the control group (OR: 1.8,95% Cl 1.0-3.5). No difference in any of the polymorphisms was found between proteinuric (n = 45) and non-proteinur-ic (n = 51) patients. Moreover, MTHFR polymorphism does not affect the association betwe…

medicine.medical_specialtybiologybusiness.industryFactor VCase-control studyHematologymedicine.diseasefemale genital diseases and pregnancy complicationsPreeclampsiaEndocrinologyPolymorphism (computer science)Internal medicineMethylenetetrahydrofolate reductaseGenotypeFactor V Leidenmedicinebiology.proteinGenetic predispositionbusinessThrombosis and Haemostasis
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Zn2+ and Cu2+ complexes of a fluorescent scorpiand-type oxadiazole azamacrocyclic ligand: crystal structures, solution studies and optical properties

2020

A ligand comprised of a macrocyclic pyridinophane core having a pendant arm containing a secondary amine group linked through a methylene spacer to a pyridyl–oxadiazole–phenyl (PyPD) fluorescent system has been prepared (L). The crystal structures of [ZnL](ClO4)2 and [CuL](ClO4)2 show that M2+ is coordinated to all the nitrogen atoms of the macrocyclic core, the secondary amine of the pendant arm and the nitrogen atom of the pyridine group of the fluorescent moiety, the latter bond being clearly weaker than the one with the pyridine of the macrocycle. Solution studies showed the formation of a highly stable Cu2+ complex with 1 : 1 stoichiometry, whereas with Zn2+ least stable complexes were…

metal coordinationspectroscopic behaviourLigandzincOxadiazoleCrystal structureFluorescenceInorganic ChemistryCrystallographychemistry.chemical_compoundchemistryPyridineMoietyAzacyclophanes oxadiazole scorpiand metal coordination zinc spectroscopic behaviourAmine gas treatingMethyleneAzacyclophanesoxadiazolescorpiandDalton Transactions
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Non-conventional synthesis and photophysical studies of platinum(ii) complexes with methylene bridged 2,2′-dipyridylamine derivatives

2019

Methylene bridged 2,2′-dipyridylamine (dpa) derivatives and their metal complexes possess outstanding properties due to their inherent structural flexibility. Synthesis of such complexes typically involves derivatization of dpa followed by coordination on metals, and may not always be very efficient. In this work, an alternative synthetic approach, involving the derivatization step after – rather than prior to – coordination of dpa on metal center, is proposed and applied to synthesis of a number of platinum(II) complexes with substituted benzyldi(2-pyridyl)amines. Comparison with the more conventional synthetic route reveals greater efficiency and versatility of the proposed approach. The …

platinachemistry.chemical_element010402 general chemistry01 natural sciencesInorganic ChemistryMetalchemistry.chemical_compoundGlassy matrixPolymer chemistrycoordination complexesplatinumMethyleneDerivatizationta116kemiallinen synteesiphotochemistry010405 organic chemistrykompleksiyhdisteet0104 chemical scienceschemistryvisual_artvisual_art.visual_art_mediumvalokemiaPhosphorescenceLuminescencePlatinumchemical synthesisDalton Transactions
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CCDC 642893: Experimental Crystal Structure Determination

2007

Related Article: C.Peifer, D.Schollmeyer, M.Tschertsche, S.Laufer|2007|Acta Crystallogr.,Sect.E:Struct.Rep.Online|63|o1551|doi:10.1107/S1600536807009300

rac-(3E3aR6aR)-3-(Hydroxymethylene)-33a66a-tetrahydro-2H-cyclopenta(b)furan-2-oneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Treatment of oral lichen planus with photodynamic therapy mediated methylene blue: a case report.

2006

Oral lichen planus (OLP) is a common chronic disease of uncertain origin. Many patients with OLP are refractory to all available therapies. The photodynamic therapy (PDT) was used as a possible alternative method in the treatment of lichen planus. Two patients with five oral lichen planus lesions were treated using topical PDT mediated by methylene blue (MB-PDT). The patients were followed up on sessions 3, 7, 15 days and 1 to 9 months after PDT. Clinical improvement was achieved in four lesions. Two lesions showed complete remission, and another two lesions had about 50% clinically improvement 3-9 months after a single session of PDT. No response detected in one lesion. MB-PDT blue seems t…

stomatognathic diseasesphotodynamic therapystomatognathic systemUNESCO::CIENCIAS MÉDICASOral lichen planusmethylene blue:CIENCIAS MÉDICAS [UNESCO]eye diseases
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CCDC 846271: Experimental Crystal Structure Determination

2012

Related Article: G.Callebaut, S.Mangelinckx, L.Kiss, R.Sillanpaa, F.Fulop, N.De Kimpe|2012|Org.Biomol.Chem.|10|2326|doi:10.1039/c2ob06637h

syn-Ethyl 4-chloro-N-(diphenylmethylene)-3-(((4-methylphenyl)sulfinyl)amino)leucinateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 947463: Experimental Crystal Structure Determination

2013

Related Article: Anssi Peuronen, Esa Lehtimäki, and Manu Lahtinen|2013|Cryst.Growth Des.|13|4615|doi:10.1021/cg401246n

tetrakis(11'1''-(Benzene-135-triyltris(methylene))tris(4-aza-1-azoniabicyclo[2.2.2]octane)) tris(oxonium) pentadecakis(hexafluorophosphate) nonahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1054512: Experimental Crystal Structure Determination

2015

Related Article: Chandan Giri, Filip Topić, Massimo Cametti, Kari Rissanen|2015|Chemical Science|6|5712|doi:10.1039/C5SC01851J

tetrakis(mu2-35-bis(Oxy(pyridin-2-ylmethylene)carbonohydrazonoyl)benzenesulfonate)-tetra-zincSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1512900: Experimental Crystal Structure Determination

2017

Related Article: Shobhraj Haldar, Gonela Vijaykumar, Luca Carrella, Steven Batha, Ghezai T. Musie, Manindranath Bera|2017|ACS Omega|2|1535|doi:10.1021/acsomega.7b00189

tri-sodium (bis(mu-22'-((2-oxidopropane-13-diyl)bis((((pyridin-2-yl)methyl)azanediyl)methylene))dibenzoato)-(mu-phosphato)-tetra-copper) dihydroxide tetradecahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 761484: Experimental Crystal Structure Determination

2011

Related Article: L.M.Carrella, C.Forster, A.R.Kennedy, J.Klett, R.E.Mulvey, E.Rentschler|2010|Organometallics|29|4756|doi:10.1021/om100327w

tris(NNN'N'-Tetramethylethane-12-diamine)-potassium bis((mu~2~-bis(trimethylsilyl)amido)-(mu~2~-trimethylsilymethylene)-bis(trimethylsilyl)amido)-di-chromium-potassiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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