Search results for "Microcell"
showing 10 items of 11 documents
Numerical modelling of the electrochemical behaviour of 316L stainless steel based upon static and dynamic experimental microcapillary-based techniqu…
2008
Microcapillary-based techniques allow the selection and interrogation of single metallurgical sites and are therefore becoming increasingly popular to investigate the electrochemical behaviour of metallic phases and non-metallic heterogeneities in alloys. This study has been carried out to assess the differences between current measurements made using a 'closed' microcapillary system (the electrochemical microcell technique) with current measurements derived from a flowing 'open' microcapillary droplet cell (the scanning droplet cell). The experimental results were compared with calculations derived from a model system adopting a finite element approach. The corrosion system consists of fou…
Numerical modelling of the galvanic coupling in aluminium alloys: A discussion on the application of local probe techniques
2010
Abstract A discussion is proposed on the determination of the input values and the experimental validation of finite element modelling of the galvanic coupling in aluminium alloys by local probe techniques such as the Scanning Vibrating Electrode Technique (SVET) and the microcapillary electrochemical cell (microcell). Polarization curves obtained by the microcell were introduced as input conditions in the model based on Laplace or Nernst–Planck equation. SVET measurements were performed to determine the coupling current distribution on an Al/Al4%Cu bimetallic system. Agreement was found between simulated and experimental current distributions depending on the input conditions and the solve…
Use of the electrochemical microcell technique and the SVET for monitoring pitting corrosion at MnS inclusions
2004
The purpose of this paper is to report on use of the electrochemical microcell technique and the scanning vibrating electrode technique for monitoring pitting corrosion on the same stainless steel microstructure. First, the electrochemical behaviour of sites containing a single inclusion was investigated in order to the determine both the successive steps occurring during the inclusions activation and some key-parameters such as the onset potential for MnS dissolution and the pitting potential. Then, the local current distribution around a pitting site was monitored at open circuit potential in order to locate anodic and cathodic regions and to obtain informations on the galvanic coupling b…
Etude des effets cohérents dans la vapeur de rubidium atomique sous irradiation laser bi-chromatique
2013
The effect of electromagnetically induced transparency is observed, using nanocelland microcell. The EIT-resonance with good parameters (high contrast and small FWHM) is obtained in thick cells. The EIT-resonance splitting in magnetic field is observed for the cases of D1-line of 85Rb and 85Rb. The theoretical model, explaining the EIT-resonance components frequency shift dependence on magnetic field strength is presented. The theoretical and experimental results are compared and good agreement is shown. Also the EIT-resonance behavior in hyperfine Paschen-Back regime is presented and explained. For the first time the N-type resonance in microcell is observed. Good parameters of theN-type r…
Cell Association With Load Balancing in Nonuniform Heterogeneous Cellular Networks: Coverage Probability and Rate Analysis
2017
To meet the ever-growing traffic demand and address the cell capacity shortage problem, associating end users to various tiers of cells in a multitier cellular network appears to be a promising approach. In this paper, we consider a nonuniform heterogeneous cellular network (NuHCN) and propose a cell association scheme that selectively mutes certain small-cell base stations (BSs) and covers end users by cell range extension (via cell biasing) for achieving load balancing. The envisaged NuHCN is comprised of two tiers of BSs, i.e., macro- and small-cell BSs, deployed according to three independent homogeneous Poisson point processes for BSs and end users, respectively. Accordingly, the avail…
Solid state 13C-NMR methodology for the cellulose composition studies of the shells of Prunus dulcis and their derived cellulosic materials.
2020
Lignocellulosic fibers and microcellulose have been obtained by simple alkaline treatment from softwood al- mond shells. In particular, the Prunus dulcis Miller (D.A.) Webb. was considered as a agro industrial waste largely available in southern Italy. The materials before and after purification have been characterized by 13C CPMAS NMR spectroscopy methodology. A proper data analysis provided the relative composition of lignin and holo- cellulose at each purification step and the results were compared with thermogravimetric analysis and FT-IR. To value the possibility of using this material in a circular economy framework, the fibrous cellulosic material was used to manufacture a handmade c…
Performance of sensl C-Series SiPM with high photoelectron resolution at cryogenic temperatures
2016
The C-Series of silicon photomultipliers (SiPM) from SensL provides devices with a fast response and high performance at low cost. The device's ability to detect light at temperatures of liquid nitrogen (77K) and liquid helium (4 K) with high photoelectron resolution was demonstrated. Results include relative photon detection efficiency (PDE), gain, microcell capacitance, and cross-talk probability at different over-voltages, both at room and at cryogenic temperatures. At 77K the SiPM demonstrated significantly improved operating characteristics while at 4K the observed increase in break-down voltage, the reduction of PDE by a factor of 2-3, and the extensively dropped microcell capacitance…
Numerical modelling of the electrochemical behaviour of 316 stainless steel based upon static and dynamic experimental microcapillary-based technique…
2008
objective of this work was to determine the parameters that affect the mass transport and the distribution of species in microcapillaries close to the specimen surface. Local experiments were carried out under static and flow conditions on type 316L stainless steel in 1.7 M NaCl, pH = 3, by means of the electrochemical microcell and the scanning droplet cell technique. The polarisation behaviour of pure iron (used as a model system) in an aqueous environment was calculated adopting a finite element approach and was compared to the experimental results. The corrosion system consists of three parallel electrochemical reactions: the oxygen reduction reaction (ORR), the hydrogen evolution react…
Contribution to the modeling of microstructural corrosion on aluminium alloys : definition of a methodology to study the bimetallic corrosion phenome…
2008
The initiation and the propagation of aluminum alloys microstructural corrosion is mainly based on the bimetallic corrosion phenomenon. This type of corrosion is caused by galvanic coupling at a local scale between the different phases contained in the alloy. The description of the localized corrosion phenomenon has been largely studied. Their complexity can explain why they are so difficult to predict by the way of numerical tools and why the works that have been done on this subject are so scarce. The present thesis brings a new contribution to this field by suggesting a methodology based on the complementary use of local electrochemical techniques and the finite element simulation of bim…
Extensive electrical model of large area silicon photomultipliers
2011
Abstract In this paper the full electrical model of silicon photomultipliers fabricated at STMicroelectronics Catania R&D clean room facilities is presented. An accurate investigation on both SiPM single microcell and entire SiPM structure to extrapolate all the electrical elements has been executed by means of dedicated characterizations carried out on appropriate layout structure. The electrical simulations results are compared to the experimental data showing a good fit and therefore verifying the accuracy of the proposed model. This model can be used to describe all the SiPMs with different sizes manufactured using the same technology. Moreover, starting from this extensive electrical m…