Search results for "Microscope"
showing 10 items of 1412 documents
On-Surfaces Synthesis on Insulating Substrates
2016
On-surface synthesis has attracted great attention in recent years due to its promising potential for creating functional structures on surfaces. An important aspect of on-surface synthesis is the capability to arrive at covalently linked thermally stable structures that offer the possibility for application even in harsh environments outside ultra-high vacuum conditions. Additionally, covalent linking allows for fabricating conjugated structures with superior electron transport properties. Especially, the latter is of tremendous interest when considering future applications in the field of molecular electronics. Having molecular electronics applications in mind explains the need for decoup…
Fluoride-induced precipitates on enamel surface and subsurface areas visualised by electron microscopy and confocal laser scanning microscopy
1997
The present study examined the enamel surface after in vitro topical treatments with a neutral 2% NaF solution. For minimising the risk of artefacts, samples were inspected without pre-treatment as fresh, naturally wet specimens by complementary techniques: variable pressure electron microscopy (VP-SEM) and confocal laser scanning microscopy (CLSM). VP-SEM provided information on the surface morphology, whereas CLSM allowed non-destructive visualisation of subsurface areas. Neutral NaF solutions induced globular precipitates on the enamel surfaces. If the globules formed may be described as "calcium fluoride like material", the additional information of this experiment is that, after intera…
Tetrathiotetracene thin film morphology and electrical properties
2015
The electrical properties of organic thin films are determined by their chemical constituents and the morphology of the films deposited. In this paper the morphology of vacuum sublimed (7?10-6 mbar) tetrathiotetracene (TTT) thin films is shown to be strongly affected by the thermal deposition temperature (222-350 K) and rate of deposition. Mostly needle-like morphologies are identified by scanning electron microscopy. Optimal TTT purity (a pre-requisite for device preparation via subsequent oxidation) is evidenced by their initially low electrical conductivity. Altering the TTT morphology, by variation of the evaporation parameters, strongly affects this base electrical conductivity. Four p…
Young’s modulus and indirect morphological analysis of Bi2Se3nanoribbons by resonance measurements
2017
An electrostatically induced resonance behaviour of individual topological insulator Bi2Se3 nanoribbons grown by a catalyst free vapour-solid synthesis was studied in situ by scanning electron microscopy. It was demonstrated that the relation between the resonant frequencies of vibrations in orthogonal planes can be applied to distinguish the nanoribbons with rectangular cross-sections from the nanoribbons having step-like morphology (terraces). The average Young's modulus of the Bi2Se3 nanoribbons with rectangular cross-sections was found to be 44 ± 4 GPa.
Morphology and transport parameters of cold-rolled low-density polyethylene
1986
Abstract Sheets of low-density polyethylene were rolled at room temperature. Samples with two different degrees of rolling were obtained. The structural changes induced by the rolling treatments were investigated using scanning electron microscopy and by analyzing the transport properties. Results suggest that in the analyzed range of deformation, the rolling induces a domain structure as a consequence of a nonhomogeneous distribution of the deformation. At lower local deformation the initial morphology is still present, while at higher deformation clumps of folded chains oriented along the rolling directions are observable. The transport properties indicate that the rolling treatment reduc…
Physical behavior and morphology of biaxially rolled low-density polyethyleneX
1989
Abstract Biaxial rolling was carried out on low-density polyethylene, and the rolled samples were studied using various techniques. Scanning electron microscopy and analysis of transport properties were used to obtain structural information, which was correlated to thermomechanical and dynamic-mechanical behavior. Results indicate that the initial morphology is destroyed by rolling and that clumps of molecules, like fibrils, are generated parallel to the rolling plane. The molecular orientation in the plane is mainly radial, with some reinforcement, particularly at high rolling degree, along axes diagonal with respect to the rolling directions. The rolling drastically reduces the molecular …
In vitro degradation and bioactivity of composite poly-l-lactic (PLLA)/bioactive glass (BG) scaffolds: comparison of 45S5 and 1393BG compositions
2017
The objective of this study was to compare the effect of two bioglass (BG) compositions 45S5 and 1393 in poly-l-lactic composite scaffolds in terms of morphology, mechanical properties, biodegradation, water uptake and bioactivity. The scaffolds were produced via thermally induced phase separation starting from a ternary polymer solution (polymer/solvent/non-solvent). Furthermore, different BG to polymer ratios have been selected (1, 2.5, 5% wt/wt) to evaluate the effect of the amount of filler on the composite structure. Results show that the addition of 1393BG does not affect the scaffold morphology, whereas the 45S5BG at the highest amount tends to appreciably modify the scaffold archite…
'Cold' crystallization in nanostructurized 80GeSe2-20Ga2Se3 glass
2015
International audience; 'Cold' crystallization in 80GeSe 2-20Ga 2 Se 3 chalcogenide glass nanostructurized due to thermal annealing at 380°C for 10, 25, 50, 80, and 100 h are probed with X-ray diffraction, atomic force, and scanning electron microscopy, as well as positron annihilation spectroscopy performed in positron annihilation lifetime and Doppler broadening of annihilation line modes. It is shown that changes in defect-related component in the fit of experimental positron lifetime spectra for nanocrystallized glasses testify in favor of structural fragmentation of larger free-volume entities into smaller ones. Nanocrystallites of Ga 2 Se 3 and/or GeGa 4 Se 8 phases and prevalent GeSe…
Nanostructured metal/oxide coatings
2007
Al based nanocomposite coatings on Cu and glass substrates were obtained in the conditions of severe shear stresses by deformation scheme similar to that of friction. Structure, composition and micromechanical properties were investigated using AFM, XRD, SIMS, electron, optical microscopy and precision microindentation techniques. Coatings are characterized by the high microhardness and good adhesion to the substrates. This is determined by the formation of nanostructured Al-oxide composite stabilized by the presence of oxidized interlayers, which are barriers for the grain growth and intermetallic phase formation. The annealing in vacuum leads to the development of oxygen redistribution pr…
Graphene oxide-silica nanohybrids as fillers for PA6 based nanocomposites
2014
Graphene oxide (GO) was prepared by oxidation of graphite flakes by a mixture of H2SO4/H3PO4 and KMnO4 based on Marcano's method. Two different masterbatches containing GO (33.3%) and polyamide-6 (PA6) (66.7%) were prepared both via solvent casting in formic acid and by melt mixing in a mini-extruder (Haake). The two masterbatches were then used to prepare PA6-based nanocomposites with a content of 2% in GO. For comparison, a nanocomposite by direct mixing of PA6 and GO (2%) and PA6/graphite nanocomposites were prepared, too. The oxidation of graphite into GO was assessed by X-ray diffraction (XRD), Micro-Raman spectroscopy, scanning electron microscopy (SEM), X-ray photoelectron spectrosco…