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showing 10 items of 20410 documents
ASSESSING TRACE ELEMENT (DIS)EQUILIBRIUM AND THE APPLICATION OF SINGLE ELEMENT THERMOMETERS IN METAMORPHIC ROCKS
2018
Abstract Empirical and experimental calibration of single element solubility thermometers, such as Zr-in-rutile, Zr-in-titanite, Ti-in-zircon, and Ti-in-quartz, within the past 13 years has greatly expanded our ability to assess the pressure and temperature conditions of individual minerals associated with specific textures in metamorphic rocks. Combined with advances in in situ techniques for analyzing trace concentrations, this has led to an increase in the combined use of single element thermometers, geochronometers, and isotope ratios, often simultaneously, in metamorphic minerals. Here we review the calibration and application of single element thermometers at the pressure and temperat…
Element variations in rhyolitic magma resulting from gas transport
2013
Tuffisite veins are glass-filled fractures formed when magma fragments during degassing within the conduit. These veins form transient channels through which exsolved gases can escape from magma. The purpose of this study is to determine the extent to which chemical heterogeneity within the melt results from gas transport, and assess how this can be used to study magma degassing. Two tuffisite veins from contrasting rhyolitic eruptions at Torfajökull (Iceland) and Chaitén (Chile) were studied in detail. The tuffisite vein from Torfajökull is from a shallow dissected conduit (~70. ka) that fed a degassed lava flow, while the sample from Chaitén was a bomb ejected during the waning phases of …
Prodigious emission rates and magma degassing budget of major, trace and radioactive volatile species from Ambrym basaltic volcano, Vanuatu island Arc
2016
Abstract Ambrym volcano, in the Vanuatu arc, is one of the most active volcanoes of the Southwest Pacific region, where persistent lava lake and/or Strombolian activity sustains voluminous gas plume emissions. Here we report on the first comprehensive budget for the discharge of major, minor, trace and radioactive volatile species from Ambrym volcano, as well as the first data for volatiles dissolved in its basaltic magma (olivine-hosted melt inclusions). In situ MultiGAS analysis of H 2 O, CO 2 , SO 2 and H 2 S in crater rim emissions, coupled with filter-pack determination of SO 2 , halogens, stable and radioactive metals demonstrates a common magmatic source for volcanic gases emitted by…
Using mosses as biomonitors to study trace element emissions and their distribution in six different volcanic areas
2017
Volcanoes emit SO2, CO2, and H2S, but also trace elements gases and particles such as As, Cd, Cr, Cu, Hg, Ni, Pb, and Sb. Active moss bag biomonitoring, an easy to apply and low budget method, was used to determine trace element release from volcanic areas of different geological context and climates. Exposure height variations (0.7â1.6 m above ground) due to different availability of natural tie points did not affect the results. Accumulation was linear for exposure durations from three days to nine weeks, so values were comparable by normalization to moss exposure time. Uncovered moss bags showed higher accumulation than co-exposed covered ones because of additional dust and wet deposit…
Shallow vent architecture during hybrid explosive-effusive activity at Cordón Caulle (Chile, 2011-12): Evidence from direct observations and pyroclas…
2013
International audience; In June 2011, an eruption of rhyolite magma began at the Puyehue-Cordón Caulle volcanic complex, southern Chile. By January 2012, explosive activity had declined from sustained pyroclastic (Plinian to sub-Plinian) fountaining to mixed gas and ash jetting punctuated by Vulcanian blasts. This explosive activity was accompanied by synchronous effusion of obsidian lava in a hybrid explosive-effusive eruption. Fortuitous climatic conditions permitted ground-based observation and video recording of transient vent dynamics as well as real-time collection of proximal juvenile ash as it sedimented from the active plume. The main eruptive vent complex and site of lava effusion…
Calculating pressure with elastic geobarometry: A comparison of different elastic solutions with application to a calc-silicate gneiss from the Rhodo…
2020
Abstract Raman elastic geobarometry has increasingly been used complementary to metamorphic phase equilibria to estimate the conditions of recrystallization in metamorphic rocks. The procedure of applying Raman elastic barometry to host-inclusion mineral systems requires several steps that involve various assumptions. One of the most essential assumptions is that the mineral host-inclusion system behaves in an elastic and reversible manner. We discuss the discrepant results obtained by different authors employing different analytical solutions for elasticity and explore the assumptions lying behind each method. Furthermore, we evaluate numerically linear and non-linear elastic solutions and…
Trace elements in the thermal groundwaters of Vulcano Island (Sicily)
2000
The chemical concentrations of many trace elements that have never before been examined in Vulcano Island groundwaters are reported. Chemical data indicate that rock composition is not the only factor determining the metal content in the aqueous system. The observed concentrations depend mainly on: (1) the chemical composition of the host rocks; (2) the chemical–physical conditions of the weathering solution (temperature, acidity, redox conditions); (3) input of magmatic gases; (4) adsorption of metal ions on oxide particles, formation of soluble complexes and/or precipitation of solid phases. Chloride complexes in solution are of minimal significance for all elements with the exception of …
The effect of microscale pore structure on matrix diffusion—a site-specific study on tonalite
1997
Abstract The matrix diffusion of non-sorbing tracers was studied in rocks from the Syyry area, Central Finland (SY1). The effect of alteration and weathering on rock matrix porosity and on the available pore space, which affects diffusivity, are discussed. The main rock type in the crystalline bedrock of Syyry is a slightly foliated, gray tonalite with mica gneiss inclusions as well as minor, more mafic inclusions. The total porosity and the spatial porosity distribution and microstructure of the rocks were investigated using infiltration of carbon- 14-methylmethacrylate, electron microscopy and Hg-porosimetry. The laboratory-scale diffusion experiments were performed using (1) the out-leac…
Quantifying geological uncertainty in metamorphic phase equilibria modelling; a Monte Carlo assessment and implications for tectonic interpretations
2016
AbstractPseudosection modelling is rapidly becoming an essential part of a petrologist's toolkit and often forms the basis of interpreting the tectonothermal evolution of a rock sample, outcrop, or geological region. Of the several factors that can affect the accuracy and precision of such calculated phase diagrams, “geological” uncertainty related to natural petrographic variation at the hand sample- and/or thin section-scale is rarely considered. Such uncertainty influences the sample's bulk composition, which is the primary control on its equilibrium phase relationships and thus the interpreted pressure–temperature (P–T) conditions of formation. Two case study examples—a garnet–cordierit…
Abiotic and biotic controls on methane formation down to 2.5 km depth within the Precambrian Fennoscandian Shield
2017
Abstract Despite a geological history characterised by high temperature and pressure processes and organic carbon deprived crystalline bedrock, large amounts of hydrocarbons are found in deep groundwaters within Precambrian continental shields. In many sites, methane comprises more that 80% of the dissolved gas phase reaching concentrations of tens of mmol l −1 . In this study, we used isotopic methods to study the carbon isotope systematics and sources of crustal methane within the Fennoscandian Shield. The main study sites were the Outokumpu Deep Drill Hole and the Pyhasalmi mine in Finland, both of which allow groundwater sampling down to 2.5 km depth and have been previously studied for…