Search results for "Mineral"
showing 10 items of 2711 documents
Lead in the Bones of Cows from a Medieval Pb-Ag Metallurgical Settlement: Bone Mineralization by Metalliferous Minerals
2021
Pb contents (13-53 mg kg−1) and pathological changes in almost complete cow skeletonsdiscovered in graves adjacent to Pb and Ag smelting furnaces active in the Silesian-Cracovian region, in the mid-12th century are reported in the article. In addition to Pb,elements such as Zn, Cd, Fe, Mn, Cd, and Ba characteristic of Zn-Pb-Ag ores in the regionwere identified. Bone fragments and the soil in which they had lain for almost 800 yearswere examined by SEM, EDS. XRD was used to identify minerals present in soils. Theenrichment of the bones with Zn, Pb, Fe, Mn, and Cd is associated with the remobilisationof elements from soil contaminated with primary and synthetic phase-rich metals. In bioticmat…
Changes of shell microstructural characteristics of Cerastoderma edule (Bivalvia) — A novel proxy for water temperature
2017
Abstract Shells of bivalves potentially provide an excellent archive for high-resolution paleoclimate studies. However, quantification of environmental variables, specifically water temperature remains a very challenging task. Here, we explore the possibility to infer water temperature from changes of microstructural characteristics of shells of the common cockle, Cerastoderma edule . The size and elongation of individual microstructural units, i.e., prisms, in the outer shell layer of seven three to five year-old, specimens collected alive from the intertidal zone of the North Sea near Texel, The Netherlands, and Schillig, Germany, were measured by means of automatic image processing. Grow…
Diagenesis of clay minerals and K-bentonites in Late Permian/Early Triassic sediments of the Sichuan Basin (Chaotian section, Central China).
2014
10 pages; International audience; Detailed clay mineralogical analyses were carried out on Late Permian/Early Triassic carbonate sediments exposed on the Chaotian section (Sichuan Basin, Central China). The clay assemblages are dominantly composed of illite in platform carbonates and clay seams, and illite-smectite mixed-layers (I/S) in tuff layers (K-bentonites) intercalated in the carbonate succession. Detrital and authigenic volcanogenic clay minerals have been partially replaced through illitisation processes during burial, raising questions about diagenetic effects. The precise determination of I/S occurring in K-bentonites shows that the sediments reached a temperature of about 180 °C…
Conjunctive use of spectral gamma-ray logs and clay mineralogy in defining late Jurassic-early Cretaceous palaeoclimate change (Dorset, U.K.).
2006
Abstract Detrital clay mineralogy is controlled by weathered source rock, climate, transport and deposition that in turn influence the spectral gamma-ray (SGR) response of resultant sediments. Whilst a palaeoclimate signal in clay mineralogy has been established in some ancient successions, the SGR response remains contentious, largely because the data sets have yet to be collected at the same or appropriate vertical scales to allow comparison. In addition, the influence of organic matter on SGR is not always considered. Here, we present clay mineralogical, total organic carbon (TOC) and SGR analyses from the late Jurassic and early Cretaceous of the Wessex Basin, a period of previously doc…
Bone diagenesis in arid environments; An intra-skeletal approach
2014
Bone trace element content and isotopic composition are closely related to human nutrition. The investigation of archaeological bone geochemistry can help us to better understand the relationship between past populations and their environment alongside cultural practices as inferred from dietary reconstruction. However, dietary in- formation may be altered post-mortem by diagenetic processes in soil. In this study, bone mineralogy (Ca/P, sec- ondary minerals, organic matter content and bone apatite crystallinity), histology, element content (Mg, Na, F, Sr, Ba, Mn, Fe, La, Ce and U) and stable isotope composition (δ13Candδ18O carbonate) were investigated at the intra- individual scale in ord…
Influence of dissolved organic matter on rare earth elements and yttrium distributions in coastal waters
2010
International audience; Data collected during this study indicate that dissolved Y and REE (rare earth element) behaviour can be monitored through shale-normalised ratios. Relationships occurring between these ratios suggest that leaching from lithogenic materials is the main source of REE in the studied area. This process involves riverine detrital matter in the inner area of the Gulf of Palermo. Features of shale-normalised patterns and the relationship recognised between dissolved Fe and Y/Ho suggest that REE are released from Fe-rich coatings of atmospheric dust. Observed similarities between dissolved Fe and chlorophyll- content suggest that leaching of Fe-rich atmospheric particulates…
Highly-resolved radiocarbon measurements on shells from Kalba, UAE, using carbonate handling system and gas ion source with MICADAS
2019
Abstract The Mini Carbon Dating System (MICADAS) represents a flexible AMS system for measuring radiocarbon samples either in the form of graphite or CO2 gas. We used the possibility to attach a carbonate handling system (CHS) to the gas ion source (GIS) to measure smaller amounts of carbonates ( 3) are used to clean the system. We tested the CHS-GIS combination on heated and unheated archaeological shells of Anadara uropigimelana from Kalba, Sharjah Emirate, United Arab Emirates (UAE). Even though the amount of carbon in the samples was small (4–22 µg C) the performance of the CO2 dating system permits the comparison of trends in the 14C data to stable isotope measurements (δ18O and δ13C)…
High-resolution clay mineralogy as a proxy for orbital tuning: example of the Hauterivian-Barremian transition in the Betic Cordillera (SE Spain).
2012
11 pages; International audience; The response of clay mineral assemblages to potential orbital forcing is tested in Mesozoic hemipelagic marl- limestone rhythmites of the Río Argos section (Betic Cordillera, Southeastern Spain). Along the section, marls are pervasively enriched in kaolinite and illite, whereas limestones are enriched in smectite-rich illite/smectite mixed-layers, suggesting that marl-limestone alternations are produced by cyclic high-frequency fluctuations of continental runoff. Spectral analyses show that clay mineral assemblages evolve accordingly to precession, obliquity and eccentricity cycles. Durations of ammonite zones are assessed at 535 kyr for the Late Hauterivia…
Regional provenance of dolerite prehistoric objects through mineral analysis
2016
Abstract A methodology based on the mineral analysis determination has been developed to identify the origin of dolerite stone outcrops collected to fabricate lithic objects during the Prehistoric period. The method is based on the use of inductively coupled plasma mass spectrometry (ICP-MS) to analyse rare earth elements (REE) and trace elements. Additionally a no destructive geochemical analysis based on X-ray fluorescence (XRF) was employed for major elements analysis. The aforementioned methodologies were applied to samples from different archaeological fields or natural outcrops located in the Mediterranean area of Spain, between Valencia and Alicante. Principal component analysis (PCA…
Micro-PIXE/PIGE analysis of Palaeolithic mammoth ivory: Potential chemical markers of provenance and relative dating
2014
Abstract Micro-Proton Induced X-ray and Gamma-ray Emission (micro-PIXE/PIGE) provide non-destructive methods for the evaluation of the major, minor and trace element compositions of archaeological material. The current study applies micro-PIXE/PIGE analysis to mammoth ivory artefacts from four Palaeolithic sites (Abri Castanet, Vogelherd Cave, Grottes de la Verpilliere I and II) in France and Germany in order to assess the effectiveness of this approach to material older than 30,000 y BP. It has thus far not been established whether such methods of analysis can yield results of scientific and archaeological interest on ivory material that has undergone such extended periods of diagenesis. T…