Search results for "Mineral"
showing 10 items of 2711 documents
Fluorine speciation in topsoils of three active volcanoes of Sicily (Italy)
2008
Fluorine is one of the many environmental harmful elements released by volcanic activity. The content of total oxalate-extractable and water-extractable fluorine was determined in 96 topsoils of three active volcanic systems of southern Italy (Mt Etna, Stromboli and Vulcano). Total fluorine (F) content (F TOT) ranges from 112 to 7,430 mg kg−1, F extracted with oxalate (F OX) ranges from 16 to 2,320 mg kg−1 (2–93% of F TOT) and F extracted with distilled water ( $$ F_{{{\text{H}}_{{\text{2}}} {\text{O}}}} $$ ) ranges from 1.7 to 159 mg kg−1 (0.2–40 % of F TOT). Fluorine in the sampled topsoils derives both from the weathering of volcanic rocks and ashes and from the enhanced deposition due t…
H2S fluxes from Mt. Etna, Stromboli, and Vulcano (Italy) and implications for the sulfur budget at volcanoes
2005
Abstract We present here new measurements of sulfur dioxide and hydrogen sulfide emissions from Vulcano, Etna, and Stromboli (Italy), made by direct sampling at vents and by filter pack and ultraviolet spectroscopy in downwind plumes. Measurements at the F0 and FA fumaroles on Vulcano yielded SO 2 /H 2 S molar ratios of ≈0.38 and ≈1.4, respectively, from which we estimate an H 2 S flux of 6 to 9 t · d −1 for the summit crater. For Mt. Etna and Stromboli, we found SO 2 /H 2 S molar ratios of ≈20 and ≈15, respectively, which combined with SO 2 flux measurements, suggest H 2 S emission rates of 50 to 113 t · d −1 and 4 to 8 t · d −1 , respectively. We observe that “source” and plume SO 2 /H 2 …
Intercomparison of volcanic gas monitoring methodologies performed on Vulcano Island, Italy
2004
[1] Volcanic gas emissions from fumaroles on the rim of La Fossa crater, Vulcano Island, Italy, were measured simultaneously using direct sampling (for H2O, CO2, total sulfur, HCl and HF), filter packs (for SO2, HCl, HF) and short-path active-mode FTIR measurements (for H2O, CO2, SO2, HCl and HF) in an intercomparison study in May 2002. The results show that Cl/F ratios were in good agreement between all three methods, and that FTIR and direct sampling determined comparable proportions of CO2 and H2O. Amounts of total S observed in direct sampling data were approximately double the amounts of SO2 measured with filter packs and FTIR. This difference could be attributed either to the fact FTI…
Tunable diode laser measurements of hydrothermal/volcanic CO<sub>2</sub> and implications for the global CO<sub&am…
2014
Abstract. Quantifying the CO2 flux sustained by low-temperature fumarolic fields in hydrothermal/volcanic environments has remained a challenge, to date. Here, we explored the potential of a commercial infrared tunable laser unit for quantifying such fumarolic volcanic/hydrothermal CO2 fluxes. Our field tests were conducted between April 2013 and March 2014 at Nea Kameni (Santorini, Greece), Hekla and Krýsuvík (Iceland) and Vulcano (Aeolian Islands, Italy). At these sites, the tunable laser was used to measure the path-integrated CO2 mixing ratios along cross sections of the fumaroles' atmospheric plumes. By using a tomographic post-processing routine, we then obtained, for each manifestati…
Major-ion bulk deposition around an active volcano (Mt. Etna, Italy)
2005
Bulk atmospheric deposition of major cations (Na, K, Ca, Mg) and anions (Cl, F, SO4) were measured at 15 sites around an active volcano, Mount Etna, from 2001 to 2003. Their composition indicates several natural sources, among which deposition of plume-derived volcanogenic gas compounds is prevalent for F, Cl and S. Plume-derived acidic compounds are also responsible for the prevailing acidic composition of the samples collected on the summit of the volcano (pH in the 2.45–5.57 range). Cation species have complex origin, including deposition of plume volcanogenic ash and aerosols and soil-dust wind re-suspension of either volcanic or carbonate sedimentary rocks. Variation of the deposition …
Magmatic signature in acid rain at Masaya volcano, Nicaragua: Inferences on element volatility during lava lake degassing
2021
Abstract Major, minor and trace element concentrations of single rainfall events were investigated at Masaya volcano (Nicaragua) in order to determine the relative contributions of volcanogenic elements. Most of the samples were collected in the summit area of the volcano around the Santiago crater, and two samples, representative of the local background, were collected at a 4.3 km upwind site. Samples from the summit are very acidic with pH down to 2.14 and contain large amounts of volcanogenic elements that can be clearly distinguished from the local background. These elements are released into the atmosphere from the continuously degassing lava lake of the Santiago crater, Masaya volcano…
Laminar Micrite Crusts and Associated Foreslope Processes, Red Sea
1991
ABSTRACT Forereef slopes in the Red Sea of Sudan exhibit a uniform biozonation that is independent from the topography of the slopes. Below - 120 m, ledges protrude horizontally from sleep cliffs of barrier reefs and atolls as well as from patches of in situ lithified slope sediment on inclined fringing reef slopes. Free surfaces and cavities within these ledges are partly covered by laminar micrite crusts of 7-20 mm thickness. The ledges are formed by an organic framework of living azooxanthellate corals, bryozoans, serpulids and fossil red algae. They are affected by repeated episodes of boring, infilling, and cementation which obliterate much of the original fabric. Concomitant cementati…
Using calculated chemical potential relationships to account for coronas around kyanite: an example from the Bohemian Massif
2010
Corona textures around kyanite, involving for example zoned plagioclase separating kyanite from the matrix, reflect the instability of kyanite with the matrix on changing P-T conditions, commonly related to decompression. The chemical potential gradients set up between the kyanite and the matrix as a consequence of slow Al diffusion drive corona development, with the zoning of the plagioclase reflecting the gradients. Calculated mineral equilibria are used to account for corona textures involving plagioclase ± garnet around kyanite, and replacement of kyanite by plagioclase + spinel symplectite, in quartz + plagioclase + K-feldspar + garnet + kyanite granulite facies gneiss from the Blanský…
Trace metal modeling of groundwater–gas–rock interactions in a volcanic aquifer: Mount Vesuvius, Southern Italy
2005
We report a detailed study of trace metals in groundwaters from the Somma-Vesuvius volcanic complex and present a model of the chemical processes that control the fate of these components during gas–water–rock interactions. Trace metal concentrations in Vesuvian groundwaters range from 0.01 to 0.1 Ag/l for ultra-trace elements (Sb, Cs, Co, Cd, and Pb) up to 0.1–10 mg/l for minor elements (Fe and Sr), leading to water–rock ratios from ~0.5 to 10 � 9 when normalized to trace element concentrations in the host rocks. Our results indicate non-isochemical dissolution of local volcanic rocks by groundwaters, during which mobile trace elements (As, Se, Mo, V, Li) are enriched and elements such as …
The viscous-brittle transition of crystal-bearing slilic melt: direct observation of magma rupture and healing
2012
Magmas may fl ow or break depending on their deformation rate. The transition between such viscous and brittle behavior controls the style of volcanic eruptions. While the brittle failure of silicate melts is reasonably well characterized, the effect of crystals on the viscous-brittle transition has not yet been constrained. Here we examine the effect of suspended crystals on the mechanical failure of magmas using torsion experiments performed at temperatures (600‐ 900 °C), strain rates (10 ‐4 ‐10 ‐1 s ‐1 ), and confi ning pressures (200‐300 MPa) relevant for volcanic systems. We present a relationship that predicts the critical stress and associated strain rate at which magmas fail as a fu…