Search results for "Mineral"

Efficient Capture of Organic Dyes and Crystallographic Snapshots by a Highly Crystalline Amino-Acid-Derived Metal-Organic Framework

2018

The presence of residual organic dyes in water resources or wastewater treatment systems, derived mainly from effluents of different industries, is a major environmental problem with no easy solution. Herein, an ecofriendly, water-stable metal-organic framework was prepared from a derivative of the natural amino acid l-serine. Its functional channels are densely decorated with highly flexible l-serine residues bearing hydroxyl groups. The presence of such a flexible and functional environment within the confined environment of the MOF leads to efficient removal of different organic dyes from water: Pyronin Y, Auramine O, Methylene Blue and Brilliant Green, as unveiled by unprecedented snaps…

Bader’s topological analysis of the electron density in the pressure-induced phase transitions/amorphization in α-quartz from the catastrophe theory …

2013

In this work, the Bader's topological analysis of the electron density, coupled with Thom's catastrophe theory, was used to characterize the pressure-induced transformations in α-quartz. In particular, ab initio calculations of the α-quartz structures in the range 0-105 Gpa have been performed at the HF/DFT exchange-correlation terms level, using Hamiltonians based on a WC1LYP hybrid scheme. The electron densities calculated throughout the ab initio wave functions have been analysed by means of the Bader's theory, seeking for some catastrophic mechanism in the sense of Thom's theory. The analysis mainly showed that there is a typical fold catastrophe feature involving an O-O interaction at …

A Bader’s topological approach for the investigation of the high pressure stability field of the Mg-perovskite phase

2014

Disertacion physico-medica, de las virtudes medicinales, uso, y abuso de las aguas thermales de la Villa de Archena ...

Sign.:[calderó]-2[calderó]8, 3[calderó]4, 4[calderó]3, 5[calderó]4, A-H8 Error tip. de sign., en D2 consta C2

A new historical perspective regarding the baptismal font of the cathedral of Monreale (Sicily): the identification of a reused Roman labrum by an an…

2017

The Cathedral of Monreale (not far from the city of Palermo) is one of the most famous monuments of the Arab-Norman period in Sicily recently added to the World Heritage list by UNESCO. It is well known above all for its structure and the magnificence mosaic decorations inside. In the church it is also conserved a Baptismal Font made of coloured limestone and dated back to the first decade of the 17th century. The present study deals with this valuable object with the aim of obtaining information about the nature and provenance of the coloured limestone constituting the basin. Laboratory analyses were thus carried out on representative stone samples by means of polarized light microscopy as…

Hydrothermal macroscopic Fe-sepiolite from Oujda Mounts (Middle Atlas, Eastern Morocco)

2008

The Triassic-Jurassic series in the Oujda Mounts (Middle Atlas, NE Morocco) includes two basaltic units. The whole sequence is crosscut by veins filled with Fe-sepiolite + chalcedony + calcite + smectite and mixed layer talc-saponite. Fe-sepiolite occurs as macroscopic fibres and is one of the latest mineral phases in the filling sequence of the veins. The compositional relationships and crystallographic parameters obtained on carefully selected samples of sepiolite are compared with previous data, and support the actual development of Mg-Fe substitution in this clay mineral, given the adequate hydrothermal conditions. Genesis of this uncommon variety of sepiolite in veins is interpreted as…

Occurrence of Fibrous Sepiolite in Alkaline Basalt in the Valley of Alfara (Baix Ebre, Tarragona, Spain)

1994

Trace element partitioning in lamproitic magmas—the Gaussberg olivine leucitite

2004

Abstract Partition coefficients for compatible and incompatible trace elements for use in modelling the origin and evolution of lamproitic and other potassic rocks are reported. These are based on values obtained by in situ determination using laser ablation microprobe-inductively coupled plasma-mass spectrometry (LAM-ICP-MS) on mineral/glass pairs in examples of the Gaussberg olivine leucitite, a classic leucite lamproite. Leucite/melt partition coefficients for 32 elements show values above 1 only for Cs and Rb, whereas values for Ni, Ga and Co are 0.4–0.1. DLc/Lq for most other elements are in the range 0.07–0.0005, and delineate a gently sloping pattern to lower values for elements gene…

Experimental calibration and implications of olivine-melt vanadium oxybarometry for hydrous basaltic arc magmas

2018

The strong dependence of vanadium partitioning between olivine and silicate melt (DVOl-M) on redox conditions (fO2) can be used as sensitive oxybarometer in magmatic systems. Here we extend the experimental database on DVOl-M, obtained so far at high temperatures (mainly above 1250 °C), to lower temperatures that are typical for island-arc basalts. Crystallization experiments were performed using a composition from Mutnovsky volcano (Kamchatka), and the investigated temperature, pressure, and oxygen fugacity ranges were 1025–1150 °C, 0.1 and 0.3 GPa, and ΔQFM of –0.5 to +3.2, respectively. The water content in melts ranged from 0.6 to ∼6.5 wt% H2O. The data demonstrate a strong negative cor…

Visible and near-infrared multispectral analysis of geochemically measured rock fragments at the Opportunity landing site in Meridiani Planum

2010

[1] We have used visible and near-infrared Panoramic Camera (Pancam) spectral data acquired by the Opportunity rover to analyze 15 rock fragments at the Meridiani Planum landing site. These spectral results were then compared to geochemistry measurements made by the in situ instruments Mossbauer (MB) and Alpha Particle X-ray Spectrometer (APXS) to determine the feasibility of mineralogic characterization from Pancam data. Our results suggest that dust and alteration rinds coat many rock fragments, which limits our ability to adequately measure the mineralogy of some rocks from Pancam spectra relative to the different field of view and penetration depths of MB and APXS. Viewing and lighting …