Search results for "Mixing ratio"

Tropical troposphere to stratosphere transport of carbon monoxide and long-lived trace species in the Chemical Lagrangian Model of the Stratosphere (…

2014

Variations in the mixing ratio of trace gases of tropospheric origin entering the stratosphere in the tropics are of interest for assessing both troposphere to stratosphere transport fluxes in the tropics and the impact of these transport fluxes on the composition of the tropical lower stratosphere. Anomaly patterns of carbon monoxide (CO) and long-lived tracers in the lower tropical stratosphere allow conclusions about the rate and the variability of tropical upwelling to be drawn. Here, we present a simplified chemistry scheme for the Chemical Lagrangian Model of the Stratosphere (CLaMS) for the simulation, at comparatively low numerical cost, of CO, ozone, and long-lived trace substances…

2021

Abstract. The formation of ice in clouds is an important processes in mixed-phase and ice-phase clouds. Yet, the representation of ice formation in numerical models is highly uncertain. In the last decade, several new parameterizations for heterogeneous freezing have been proposed. However, it is currently unclear what the effect of choosing one parameterization over another is in the context of numerical weather prediction. We conducted high-resolution simulations (Δx=250 m) of moderately deep convective clouds (cloud top ∼-18 ∘C) over the southwestern United Kingdom using several formulations of ice formation and compared the resulting changes in cloud field properties to the spread of an…

2015

Abstract. The convective transport module, CVTRANS, of the ECHAM/MESSy Atmospheric Chemistry (EMAC) model has been revised to better represent the physical flows and incorporate recent findings on the properties of the convective plumes. The modifications involve (i) applying intermediate time stepping based on a settable criterion, (ii) using an analytic expression to account for the intra-time-step mixing ratio evolution below cloud base, and (iii) implementing a novel expression for the mixing ratios of atmospheric compounds at the base of an updraft. Even when averaged over a year, the predicted mixing ratios of atmospheric compounds are affected considerably by the intermediate time st…

On the scavenging of SO2 by large and small rain drops: V. A wind tunnel and theoretical study of the desorption of SO2 from water drops containing S…

1993

An experimental and theoretical study has been carried out to investigate the rate of desorption of SO2 from water drops falling at terminal velocity in air. The experiments were carried out in the Mainz vertical wind tunnel in which water drops of various sizes containing S(IV) in various concentrations were freely suspended in the vertical airstream of the tunnel. The results of these experiments were compared with the predictions of three theoretical models, and with the experiments of Walceket al. This comparison shows that the predictions of the diffusion model of Kronig and Brink in the formulation given by Walcek and Pruppacher agree well with the experimental results for all relevan…

2019

Abstract. Recently, the aerosol microphysics submodel MADE3 (Modal Aerosol Dynamics model for Europe, adapted for global applications, third generation) was introduced as a successor to MADE and MADE-in. It includes nine aerosol species and nine lognormal modes to represent aerosol particles of three different mixing states throughout the aerosol size spectrum. Here, we describe the implementation of the most recent version of MADE3 into the ECHAM/MESSy Atmospheric Chemistry (EMAC) general circulation model, including a detailed evaluation of a 10-year aerosol simulation with MADE3 as part of EMAC. We compare simulation output to station network measurements of near-surface aerosol componen…

Molecular hydrogen (H2) mixing ratio and stable isotopic composition (dD) at the Cabauw tall tower in the Netherlands (2008-2012)

2016

Measurements of the stable isotopic composition (dD(H2) or dD) of atmospheric molecular hydrogen (H2) are a useful addition to mixing ratio (X(H2)) measurements for understanding the atmospheric H2 cycle. dD datasets published so far consist mostly of observations at background locations. We complement these with observations from the Cabauw tall tower at the CESAR site, situated in a densely populated region of the Netherlands. Our measurements show a large anthropogenic influence on the local H2 cycle, with frequently occurring pollution events that are characterized by X(H2) values that reach up to 1 ppm and low dD values. An isotopic source signature analysis yields an apparent source s…

On the structure of the extra-tropical transition layer from in-situ observations

2012

Abstract. In-situ observations of atmospheric tracers from multiple measurement campaigns over the period 1994–2007 were combined to investigate the Extra-tropical Transition Layer (ExTL) region and the properties of large scale meridional transport. We used potential temperature, equivalent latitude and distance relative to the local dynamical tropopause as vertical coordinates to highlight the behaviour of trace gases in the tropopause region. Vertical coordinates based on constant PV surfaces allowed us to relate the dynamical definition of the tropopause with trace gases distributions and vertical gradients and hence analyse its latitudinal dependence and seasonal variability. Analysis …

Global impact of monocyclic aromatics on tropospheric composition

2017

Abstract. Aromatic compounds are reactive species influencing ozone formation, OH concentrations and organic aerosol formation. An assessment of their impacts on the gas-phase composition at a global scale has been performed using a general circulation atmospheric-chemistry model. Globally, we found a small annual average net decrease (less than 3 %) in global OH, ozone, and NOx mixing ratios when aromatic compounds are included in the chemical mechanism. This inclusion of aromatics also results in CO mixing ratio increases, which cause a general decrease in OH concentrations. The largest changes are found in glyoxal and NO3, with increases in the atmospheric burden of 10 % and 6 %, respect…

A composite study on the structure and formation of ozone miniholes and minihighs over central Europe

2005

[1] Two different mechanisms have been proposed to be important for the formation of extreme total ozone events in mid-latitudes, so-called miniholes: (A) far-range meridional transport of air masses from regions with different climatological ozone mixing ratios, and (B) (local) adiabatic vertical displacement of isentropes. Here, the relative importance of these two mechanisms is studied using two different ozone profile reconstruction techniques for all miniholes and minihighs (events with anomalously high ozone) during the time period 1980–1989 over Switzerland. Composites for the two types of events of their vertical potential vorticity (PV) reveal a vertical dipole structure of PV anom…

2009

Abstract. The emission of nitric oxide (NO) by soils (SNOx) is an important source of oxides of nitrogen (NOx=NO+NO2) in the troposphere, with estimates ranging from 4 to 21 Tg of nitrogen per year. Previous studies have examined the influence of SNOx on ozone (O3) chemistry. We employ the ECHAM5/MESSy atmospheric chemistry model (EMAC) to go further in the reaction chain and investigate the influence of SNOx on lower tropospheric NOx, O3, peroxyacetyl nitrate (PAN), nitric acid (HNO3), the hydroxyl radical (OH) and the lifetime of methane (τCH4). We show that SNOx is responsible for a significant contribution to the NOx mixing ratio in many regions, especially in the tropics. Furthermore, …