Search results for "Mixing"
showing 10 items of 795 documents
On the use of mixing reactors in flow injection analysis with thermal lens calorimetric detection
1993
Abstract In flow injection analysis with thermal lens calorimetric detection, mixing of reagent streams of different composition before the detection cell produces a large background noise. The noise is due to the heterogeneity of the mixture which produces refractive changes in the probe beam direction. Procedures to measure the homogeneity of the mixture of solutions are derived, and used to evaluate and improve the mixing efficiencies of packed bead reactors. Using well-designed reactors, the mixing noise can be reduced below the noise levels due to other sources.
Enhanced [4+2] cycloadditions by solvophobic effects and gravity-induced mixing in core-shell droplets
2017
A new way to perform reactions in core—shell double emulsions is reported herein. The phase boundaries of the threephase droplet flow were used to pressurize the reactants in the shell liquid, enhancing the reaction rate of a cycloaddition greatly in comparison to known methods. As key parameters, solvophobic effects and precise control over the droplet sizes were used to exploit a reaction with a negative volume of activation. The internal pressure of the reaction solution was regulated purely by the thickness of the shell liquid without adding additional reagents. Additionally, the reaction performed better when the core droplet was used to stir the shell droplet, considerably improving t…
A geometric approach for predicting vertical stationary profiles of weakly inertial advecting-diffusing particles in closed incompressible flows
2004
Abstract Mixing of weakly inertial particles in closed flows is often addressed by considering individual particles as passive advecting-diffusing tracers, subjected to an additional settling velocity resulting from body forces (e.g. gravity). We show that the qualitative and quantitative features of the vertical particle distribution (i.e. the horizontal cross-sectional averages of particle concentration) can be predicted from the structure of the flow resulting from the superposition of the stirring field and the settling velocity. The prediction is based upon the observation that the resulting flow can be divided into two nonoverlapping regions, namely trajectories that are confined with…
Active mixing inside double emulsion segments in continuous flow
2015
Fast mixing is essential for many microfluidic applications, especially for flow at low Reynolds numbers. A capillary tube-in-tube coaxial flow setup in combination with a glass microreactor was used to produce immiscible multiphase segments. These double emulsion segments are composed of an organic solvent as the shell (outer) phase and a completely fluorinated liquid (Fluorinert® FC-40) as the core (inner) phase. Due to the higher density of the core droplets, they are responsive to changing their position to the force of gravity (g-force). By gently shaking or jiggling the reactor, the core drop flows very fast in the direction of the g-field without leaving the shell organic phase segme…
Time-resolved velocity measurements in a magnetic micromixer
2015
Abstract Mixing efficiency is lower in passive micromixers due to viscous forces and substantial research effort is focused on designing high performance micromixers. Active micromixers make use of external forces to enhance mixing efficiency. Among these, magnetic forces are popular because they are non-contact and therefore the micromixer design can be kept simple. Laser-based diagnostic tools have great potential in providing multi-parameter information in microfluidics research on mixing. MicroPIV experiments are performed to investigate the transient flow field in a magnetic micromixer undergoing labyrinthine instability. Velocity and interface front information is extracted from a seq…
Self-pumped phase conjugation in a BaTiO3:Rh waveguide
2002
We present a self-pumped phase conjugator originated by self-bending of the incident beam at λ = 515 nm in a BaTiO3:Rh waveguide elaborated by three successive He+ ion implantations. Phase conjugate reflectivity reached is 28 %.
Nonrecursive multiple shock formation via four-wave mixing: theory and experiment
2002
We show theoretically and experimentally that a beat signal propagating along a normally dispersive fiber can trigger the formation of multiple shocks. This phenomenon critically depends on the input frequency separation and power of the beat signal.
Crazy about science: The difficulties to mix accountability and caregiving
2016
The general model for evaluating scientific production fits into the accountability system: a way of measuring scientific output which does not usually acknowledge the presence of gender imbalances in academic institutions. Here we take the need to rethink this system and the indicators it uses to measure productivity and scientific quality, as well as the social conditions in which these activities are measured, as a starting point. In particular, we urge the review of this system, considering the administration of caregiving to dependents, be they young or old, as an example, because it is an unresolved problem that affects scientific work as well as progress in gender equality in univers…
Direct numerical simulations of creeping to early turbulent flow in unbaffled and baffled stirred tanks
2018
Abstract It has been known for a long time that the fluid flow and several global quantities, such as the power and pumping numbers, are about the same in baffled and unbaffled mechanically stirred vessels at low Reynolds numbers, but bifurcate at some intermediate Re and take drastically different values in fully turbulent flow. However, several details are not yet completely understood, notably concerning the relation of this bifurcation with the flow features and the transition to turbulence. In order to shed light on these issues, computational fluid dynamics was employed to predict the flow field in two vessels stirred by a six-bladed Rushton turbine at Reynolds numbers from 0.2 to 600…