Search results for "Modula"
showing 10 items of 1481 documents
Effect of modulator connectivity on promoting defectivity in titanium–organic frameworks
2020
The recognition of defect chemistry as a true synthetic tool for targeted creation of defects and controllable performance remains limited by the pool of frameworks explored. The value of defect engineering in controlling the properties of defective frameworks has been beautifully exemplified and largely demonstrated with UiO-type materials based on Zr(iv) nodes. However, titanium–organic frameworks remain largely unexplored in this context arguably due to the complex chemistry in solution of Ti(iv) and the difficulties in growing crystalline solids. We report a systematic study on the ability of mono- and dicarboxylic modulators (benzoic and isophthalic acid) to promote defect creation in …
Highly Modular Flow Cell for Electroorganic Synthesis
2017
A highly modular electrochemical flow cell and its application in electroorganic synthesis is reported. This innovative setup facilitates many aspects: an easy adjustment of electrode distance, quick exchange of electrode material, and the possibility to easily switch between a divided or undivided cell. However, the major benefit of the cell is the exact thermal positioning of the electrode material into a Teflon piece. Thereby, the application of expensive and nonmachinable electrode materials like boron-doped diamond or glassy carbon can easily be realized in flow cells. By this geometry, the maximum surface of such valuable electrode materials is exploited. The cell size can compete wit…
Large, Highly Modular Narrow-Gap Electrolytic Flow Cell and Application in Dehydrogenative Cross-Coupling of Phenols
2019
The successive scale-up of electrochemical reactions is crucial with regard to the implementation of technical electro-organic syntheses. Therefore, we developed a scalable modular parallel-plate e...
Modulating the polarization of broadband terahertz pulses from a spintronic emitter at rates up to 10 kHz
2021
Reliable modulation of terahertz electromagnetic waveforms is important for many applications. Here, we rapidly modulate the direction of the electric field of linearly polarized terahertz electromagnetic pulses with 1–30 THz bandwidth by applying time-dependent magnetic fields to a spintronic terahertz emitter. Polarity modulation of the terahertz field with more than 99% contrast at a rate of 10 kHz is achieved using a harmonic magnetic field. By adding a static magnetic field, we modulate the direction of the terahertz field between angles of, for instance, −53° and 53° at kilohertz rates. We believe our approach makes spintronic terahertz emitters a promising source for low-noise modula…
Characterization of Different Cable Ferrite Materials to Reduce the Electromagnetic Noise in the 2–150 kHz Frequency Range
2018
The gap of standardization for conducted and field coupled electromagnetic interferences (EMI) in the 2–150 kHz frequency range can lead to Electromagnetic Compatibility (EMC) problems. This is caused by power systems such as Pulse Width Modulation (PWM) controlled rectifiers, photovoltaic inverters or charging battery units in electric vehicles. This is a very important frequency spectral due to interferences generated in a wide range of devices and, specifically, communication problems in the new technologies and devices incorporated to the traditional grid to convert it into a Smart Grid. Consequently, it is necessary to provide new solutions to attenuate this kind of interference, which…
Programmable color tuning of a multiline laser by means of a twisted nematic liquid crystal display.
2012
An optical system useful to tune in a controlled way the color of a triline argon krypton (Ar–Kr) laser by means of a twisted nematic liquid crystal display (TNLCD) is presented. The optical setup employs a 4f system and two blazed gratings to first separate and then recombine the spectrum of the light beam. The TNLCD is included in the intermediate focal plane operating in the amplitude modulation mode to control the relative transmission of each spectral line. The resulting color is accurately predicted by using a previously developed physical model of the spectral and voltage dependence of the TNLCD birefringence. By simply changing the gray level image addressed to the display, the Ar–K…
Photothermal excitation setup for a modified commercial atomic force microscope
2014
High-resolution imaging in liquids using frequency modulation atomic force microscopy is known to suffer from additional peaks in the resonance spectrum that are unrelated to the cantilever resonance. These unwanted peaks are caused by acoustic modes of the liquid and the setup arising from the indirect oscillation excitation by a piezoelectric transducer. Photothermal excitation has been identified as a suitable method for exciting the cantilever in a direct manner. Here, we present a simple design for implementing photothermal excitation in a modified Multimode scan head from Bruker. Our approach is based on adding a few components only to keep the modifications as simple as possible and …
Q-switching of an erbium-doped fibre laser modulated by a Bragg grating fixed to a piezoelectric
2003
The performance of the Q-switched erbium-doped fibre laser with two fibre Bragg gratings as cavity mirrors was theoretically analysed, employing a set of rate equations for the ion populations and the photon flux inside the cavity. The simulation considers a system where the pulsed laser emission is produced by the temporal modulation of a Bragg grating fixed to a piezoelectric and operating in the 1550 nm spectral region. The temporal evolution of different frequency components of the laser emission produced is governed by the instantaneous overlap between the two gratings. Theoretical results are in agreement with previously reported experimental values.
Numerical simulations of the mechanical characteristics of glass fibre reinforced C-profiles
2006
A mechanical characterisation analysis on pultruded glass fibre reinforced C-shaped profiles, developed as modular construction elements to assemble fastening systems, such as doors, window frames and shutters is presented. The key idea is to perform the analysis, and all the related identification procedures of the material parameters, via a coupled approach, based on a limited number of standard laboratory tests and on the numerical finite element simulations of the same tests. The proposed approach allows one to identify all those material parameters which are difficult to detect, by means of simple laboratory experiments on specimens that are extracted from commercial products. It also …