Search results for "Mole"

showing 10 items of 35882 documents

Serum Vitamin D as a Biomarker in Autoimmune, Psychiatric and Neurodegenerative Diseases.

2022

Vitamin D is a steroid hormone regulating calcium-phosphorus homeostasis, immune response and brain function. In the past thirty years, an increasing number of cohort studies, meta-analyses and randomized controlled trials (RTCs) evaluated the serum levels of 25-hydroxyvitamin D [25(OH)D], which is considered the Vitamin D status biomarker, in patients affected by neurological, psychiatric and autoimmune diseases. Although an association between low 25(OH)D serum levels and the prevalence of these diseases has been found, it is still unclear whether the serum 25(OH)D measurement can be clinically useful as a biomarker for diagnosis, prognosis and predicting treatment response in neurodegene…

standardizationMedicine (General)25(OH)DClinical Biochemistrypsychiatric diseasesvitamin DReviewmultiple sclerosisR5-920Settore BIO/12 - Biochimica Clinica E Biologia Molecolare Clinicabiomarkerautoimmune diseasesneurodegenerative diseasesAlzheimer’s diseaseDiagnostics (Basel, Switzerland)
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The XMM-Newton Extended Survey of the Taurus Molecular Cloud (XEST)

2007

(abridged:) The XMM-Newton Extended Survey of the Taurus Molecular Cloud (XEST) surveys the most populated ~5 square degrees of the Taurus star formation region, using the XMM-Newton X-ray observatory to study the thermal structure, variability, and long-term evolution of hot plasma, to investigate the magnetic dynamo, and to search for new potential members of the association. Many targets are also studied in the optical, and high-resolution X-ray grating spectroscopy has been obtained for selected bright sources. The X-ray spectra have been coherently analyzed with two different thermal models (2-component thermal model, and a continuous emission measure distribution model). We present ov…

stars : pre-main sequence010504 meteorology & atmospheric sciencesAstrophysics::High Energy Astrophysical PhenomenaBrown dwarfFOS: Physical sciencesAstrophysicsAstrophysics::Cosmology and Extragalactic AstrophysicsAstrophysics01 natural sciencesLuminosity[PHYS.ASTR.CO]Physics [physics]/Astrophysics [astro-ph]/Cosmology and Extra-Galactic Astrophysics [astro-ph.CO]Observatory0103 physical sciencesProtostarAstrophysics::Solar and Stellar Astrophysics010303 astronomy & astrophysicsAstrophysics::Galaxy Astrophysics0105 earth and related environmental sciencesPhysicsstars : formationStar formationMolecular cloudAstrophysics (astro-ph)Astronomy and AstrophysicsAccretion (astrophysics)Starsgravitational waves13. Climate actionSpace and Planetary ScienceX-rays : star
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Spectral properties of X-ray bright variable sources in the Taurus Molecular Cloud

2006

We analyze 19 bright variable X-ray sources detected in the XMM-Newton Extended Survey of the Taurus Molecular Cloud (XEST), in order to characterize the variations with time of their coronal properties and to derive informations on the X-ray emitting structures. We performed time-resolved spectroscopy of the EPIC PN and MOS spectra of the XEST sources, using a model with one or two thermal components, and we used the time evolution of the temperatures and emission measures during the decay phase of flares to derive the size of the flaring loops. The light curves of the selected sources show different types of variability: flares, long-lasting decay or rise through the whole observation, sl…

stars : pre-main sequence010504 meteorology & atmospheric sciencesAstrophysics::High Energy Astrophysical PhenomenaX-rays : starsFOS: Physical sciencesFluxAstrophysicsAstrophysics01 natural sciences7. Clean energySpectral linelaw.inventionlaw0103 physical sciencesAstrophysics::Solar and Stellar AstrophysicsSpectroscopy010303 astronomy & astrophysics0105 earth and related environmental sciencesPhysicsMolecular cloudAstrophysics (astro-ph)Astronomy and Astrophysicsstars : late-typeRadiusPlasmaLight curve13. Climate actionSpace and Planetary Sciencestars : coronaeFlare
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Steroidal supramolecular metallogels

2020

The review deals with an expanding number of steroidal compounds that are capable of forming a metallogel providing a multitude of novel materials rich in their properties. The future of steroidal metallogels holds a myriad of potential applications as new intelligent materials. Detection of potentially harmful compounds without expensive instrumentation, entrapment of environmentally hazardous substances, and sensitive and selective nanomaterials represent only a few of these potential applications. This article reviews the design, synthesis, characterization, and applications of steroidal metallogels. peerReviewed

steroidal metallogelsMaterials sciencesteroidal compoundssupramolekulaarinen kemiaSupramolecular chemistryNanotechnologyGeneral ChemistryInstrumentation (computer programming)metallogelsChemical Society Reviews
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Photoluminescence and Electron Spin Resonance of Silicon Dioxide Crystal with Rutile Structure (Stishovite)

2018

This work was supported by ERANET MYND. Also, financial support provided by Scientific Research Project for Students and Young Researchers Nr. SJZ/2017/2 realized at the Institute of Solid State Physics, University of Latvia is greatly acknowledged. The authors express our gratitude to R.I. Mashkovtsev for help in ESR signal interpretation. The authors are appreciative to T.I. Dyuzheva, L.M. Lityagina, N.A. Bendeliani for stishovite single crystals and to K. Hubner and H.-J. Fitting for stishovite powder of Barringer Meteor Crater.

stishovitesMaterials sciencePhotoluminescenceSilicon dioxideFOS: Physical sciences02 engineering and technology01 natural sciencesMolecular physicslaw.inventionCrystalchemistry.chemical_compoundlaw0103 physical sciences:NATURAL SCIENCES:Physics [Research Subject Categories]luminescenceMaterials Chemistryelectron spin resonancesElectrical and Electronic Engineering010306 general physicsElectron paramagnetic resonancedefectsStishoviteCondensed Matter - Materials Sciencedense silicon dioxidesMaterials Science (cond-mat.mtrl-sci)Surfaces and Interfaces021001 nanoscience & nanotechnologyCondensed Matter PhysicsSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialschemistryExcited state0210 nano-technologyLuminescenceSingle crystal
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Analysis of the effects of co-exposure to antibiotics and cadmium on sea urchin embryos

2014

In order to understand the mechanisms of responses to changes in the physical and chemical environment, as well as the mechanisms of developmental pathways, we investigated by RT-qPCR assays and light microscopy observations the impact of antibiotics and cadmium in P. lividus sea urchin embryos. In particular we inspected development and biomarkers for free radical damage and apoptosis. During development embryos were exposed to an antibiotic mix (Ab mix, usually added to sea urchin cultures) or to sulfamethoxazole/trimethoprim mix (TMP/SMX, usually added to aquacultures) and/or levels of 10-5, 10-4, 10-3 M CdCl2. Even though treatment with TMP/SMX apparently did not affect development, it …

stress Echinodermata cadmium antibiotics marine organismsSettore BIO/11 - Biologia Molecolare
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Metallothionein genes in the sea urchin Paracentrotus lividus

2014

Metallothioneins (MTs) constitute a heterogeneous superfamily of cysteine rich proteins, which coordinate divalent (Zn2+, Cd2+) or monovalent (Cu+) metal ions. Several functions have been proposed for these peptides, ranging from toxic metal protection to physiological metal homeostasis, free radical scavenging, oxidative stress protection, antiapoptotic defense, control of the redox status of the cell and also a role during development. Regarding the MT system in vertebrates’ nearest kin, little information is available at present. Recently MTs were also characterized in cephalochordates. Hence in order to shed some light on MT origin and functional differentiation through evolution, we st…

stressmetalSettore BIO/11 - Biologia Molecolaretranscription regulationmetallothioneindevelopmentsea urchin
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Compared Binding Properties between Resveratrol and Other Polyphenols to Plasmatic Albumin: Consequences for the Health Protecting Effect of Dietary …

2014

International audience; Phytophenols are considered to have beneficial effects towards human physiology. They are food microcomponents with potent chemopreventive properties towards the most three frequent contemporary human diseases, e.g., cardiovascular alterations, cancer and neurodegenerative pathologies. Related to this, the plasmatic form and plasmatic level of plant polyphenols in the body circulation are crucial for their efficiency. Thus, determinations of the binding process of resveratrol and of common flavonoids produced by major edible plants, berries and fruits to plasma proteins are essential. The interactions between resveratrol and albumin, a major plasma protein, were comp…

structural changes[SDV]Life Sciences [q-bio]Pharmaceutical ScienceReviewResveratrolresveratrol01 natural sciencesAnalytical Chemistryquercetinchemistry.chemical_compound[ SDV.BBM.BC ] Life Sciences [q-bio]/Biochemistry Molecular Biology/Biomolecules [q-bio.BM]Resveratrol bindingDrug DiscoveryStilbenesBovine serum albuminComputingMilieux_MISCELLANEOUS0303 health sciencesbiologyfood and beveragesBlood proteins[SDV.BBM.BC]Life Sciences [q-bio]/Biochemistry Molecular Biology/Biomolecules [q-bio.BM]3. Good healthBiochemistryChemistry (miscellaneous)HealthMolecular MedicinefluorescencePlants EdibleQuercetinSerum albuminlcsh:QD241-44103 medical and health scienceslcsh:Organic chemistryHumans[SDV.BBM.BC]Life Sciences [q-bio]/Biochemistry Molecular Biology/Biochemistry [q-bio.BM]Physical and Theoretical ChemistryBinding siteSerum Albumin030304 developmental biologyFlavonoidsBinding Sites010405 organic chemistryOrganic ChemistryAlbuminPolyphenols0104 chemical sciencesDietchemistryFoodbiology.proteinaffinityMolecules
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Design, synthesis and structure-activity relationship of 2-(3',4',5'-trimethoxybenzoyl)-benzo[b]furan derivatives as a novel class of inhibitors of t…

2009

The biological importance of microtubules in mitosis and cell division makes them an interesting target for the development of anticancer agents. Small molecules such as benzo[b]furans are attractive as inhibitors of tubulin polymerization. Thus, a new class of inhibitors of tubulin polymerization based on the 2-(3′,4′,5′-trimethoxybenzoyl)-benzo[b]furan molecular skeleton, with electron-donating (Me, OMe or OH) or electron-withdrawing (F, Cl and Br) substituents on the benzene ring, was synthesized and evaluated for antiproliferative activity, inhibition of tubulin polymerization and cell cycle effects. Adding a methyl group at the C-3 position resulted in increased activity. The most prom…

structure-activityStereochemistryClinical BiochemistryPharmaceutical ScienceAntineoplastic Agentsmacromolecular substancesBiochemistryChemical synthesisArticleStructure-Activity Relationshipchemistry.chemical_compoundbenzo[b]furansMicrotubuleCell Line TumorFuranDrug DiscoveryHumansStructure–activity relationshipMolecular BiologyBenzofuransCell ProliferationBinding SitesDose-Response Relationship DrugbiologyChemistryTubulin ModulatorsCell growthCell CycleOrganic ChemistrySmall moleculeTubulin Modulatorstubulin polymerizationTubulinDrug Designbiology.proteinMolecular MedicineProtein MultimerizationColchicine
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Crystal structure and Hirshfeld surface analysis of [N(CH3)4][2,2′-Fe(1,7-closo-C2B9H11)2]

2017

Abstract This work investigates the meta -ferrabis(dicarbollide) anion that was isolated as salt of tetramethylammonium. The structure of the obtained crystal consisted of discrete [2,2′-Fe(1,7- closo -C 2 B 9 H 11 ) 2 ] − anions and disordered [N(CH 3 ) 4 ] + cations. The anion had a considerable chemical stability ensured by ionic and Van der Waals interactions. Thus, Hirshfeld surfaces and fingerprint plot were used to visualize, explore, and quantify intermolecular interactions in the crystal lattice of the title compound. This investigation proved that close contacts were dominated by H⋯H interactions.

structures: crystalsIonic bondingCrystal structure010402 general chemistrychemistry01 natural sciencesBiochemistryIonInorganic ChemistryCrystalchemistry.chemical_compoundsymbols.namesakeComputational chemistrymeta-carboraneMaterials ChemistryPhysical and Theoretical Chemistryta116x-ray crystallographyTetramethylammoniummetallabis(dicarbollide)010405 organic chemistryOrganic ChemistryIntermolecular forcex-ray technology0104 chemical sciencesCrystallographydihydrogen bondschemistrysymbolsChemical stabilityvan der Waals forceHirshfeld studyJournal of Organometallic Chemistry
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