Search results for "Mécanisme"
showing 10 items of 31 documents
Free riding as méchanism
1998
Free-riding is methodologically puzzling. It is at the same time important and often not observed as an actual phenomenon. The paper explores the possibility of treating free riding as an underlying or causal mechanism. As such, free riding is to be treated as part of the real world rather than of the world of models or theories. However, the free riding mechanism is particularly prone to operate not in isolation but together with other mechanisms. This feature has consequences on issues such as empirical content, testability or relevance. These questions are discussed in the light of some recent work in philosophy of science and with special attention given to the development of experiment…
Structure of matrices based on pectin : formulation, characterization, functionality and controlled release during the encapsulation
2016
In this thesis, we studied the interactions between an anionic polysaccharide (pectin) and monovalent cation (Na+) and divalent cations (Ca2+, Zn2+, Ba2+, Mg2+) in dilute regime (c Ca2+ > Zn2+ > Mg2+; this may be related to the affinity between the water molecules from the coordination sphere and the cation. Indeed, the affinity of the cation for water molecules increases in the reverse order: Ba2+ < Ca2+ < Zn2+ < Mg2+. Finally, we have used the three polysaccharides (PGA, LMP and ALMP - amidated low methoxyl pectin) in association with calcium ions to produce microparticles containing rutin to target drug release in the intestine. We have linked the rutin release kinetics to the network st…
Influence of the Madden-Julian Oscillation on Southern African summer rainfall
2007
Rain-causing mechanisms over Southern Africa (south of 15˚S) involve both tropical and temperate dynamics. Most studies focused on the synoptical timescale, while the intraseasonal (20-120 days) variability has more been neglected to date. This study aims at determining whether the dominant mode of intraseasonal variability in the Tropics, namely the Madden-Julian Oscillation (MJO), has a significant impact on Southern African rainfall and associated atmospheric dynamics. The examination of outgoing longwave radiation (OLR) over Southern Africa shows indeed significant intraseasonal fluctuations at the 30-60 day timescale, i.e. in the pe- riods that are typically reminiscent of the MJO. In ord…
Study of the hydrolysis of lithium hydride
2015
The hydrolysis of LiH at room temperature and under low water vapor pressure (PH2O < 10 hPa) is investigated by thermogravimetry and FTIR spectroscopy with low sample mass. Then, to be closer to industrial conditions, hydrolysis of LiH is studied by manometry either in closed (adjustable PH2O) or open (constant PH2O) system using larger amounts of sample and heavy water. Products of the reaction are characterized by X-ray diffraction and FTIR spectroscopy. The first set of experiments show that the mechanism of hydrolysis starts with the formation of lithium oxide Li2O. Then, when the oxide layer is sufficiently thick, the hydrolysis reaction is followed by the formation of lithium hydroxid…
Study of a chromia-forming alloy behavior as interconnect material for High Temperature Vapor Electrolysis
2011
In High Temperature Vapor Electrolysis (HTVE) system, the materials chosen for the interconnectors should have a good corrosion behaviour in air and in H2-H2O mixtures at 800°C, and keep a high electronic conductivity over long durations as well. In this context, the first goal of this study was to evaluate a commercial ferritic alloy (the K41X alloy) as interconnect for HTVE application. Oxidation tests in furnace and in microbalance have therefore been carried out in order to determine oxidation kinetics. Meanwhile, the Area Specific Resistance (ASR) was evaluated by Contact Resistance measurements performed at 800°C. The second objective was to improve our comprehension of chromia-formin…
G6PD protects from oxidative damage and improves healthspan in mice
2016
S.N.-P. and P.J.F.-M. have been funded by the Spanish Association Against Cancer(aecc). Work in the laboratory of M.S. is funded by the CNIO and by grants from the Spanish Ministry of Economy co-funded by the European Regional Development Fund(SAF project), the European Research Council (ERC Advanced Grant), the Regional Government of Madrid co-funded by the European Social Fund (ReCaRe project), the European Union (RISK-IR project), the Botin Foundation and Banco Santander(Santander Universities Global Division), the Ramon Areces Foundation, and the AXA Foundation. Work in the laboratory of J.V. was supported by grants SAF2013-44663-R,from the Spanish Ministry of Education and Science (MEC…
Specific adduction of plant lipid transfer protein by an allene oxide generated by 9-lipoxygenase and allene oxide synthase
2006
International audience; Lipid transfer proteins (LTPs) are ubiquitous plant lipid-binding proteins that have been associated with multiple developmental and stress responses. Although LTPs typically bind fatty acids and fatty acid derivatives in a non-covalent way, studies on the LTPs of barley seeds have identified an abundantly occurring covalently modified form, LTP1b, the lipid ligand of which has resisted clarification. In the present study, this adduct was identified as the {alpha}-ketol 9-hydroxy-10-oxo-12(Z)-octadecenoic acid. Further studies on the formation of LTP1b demonstrated that the ligand was introduced by nucleophilic attack of the free carboxylate group of the Asp-7 residu…
Tunisian start up support systems : what challenges facing young graduates entrepreneurs? : Sfax case study
2015
In this dissertation we identify the determinants of the longevity and the probability of survival of small businesses created by young graduates benefiting from bank loans at enhanced rates. The focus is on the policy impact of public support for the creation of companies. The data are based on a survey conducted in 2013 under the tutelage of the University of Sfax (Tunisia) of a cohort of 160 companies five years after they were first formed. The response rate was 81.25%. After discussing the issue of the survival of newly-established companies and the factors that promote their survival, we use duration models specifically the Cox model (1972). This analysis allows us to shed light on a …
La céramique médiévale et moderne du bassin de la Loire moyenne, chrono-typologie et transformation des aires culturelles dans la longue durée (6e—19…
2022
La présente publication, en accès libre sur Huma-Num, résulte d’un Projet Collectif de Recherche (PCR) sur la céramique médiévale et moderne du bassin de la Loire moyenne qui s’inscrit dans la longue durée, puisqu’il a commencé en 1996 et a déjà fait l’objet de deux suppléments à la RACF (Husi 2003 dir. https://www.persee.fr/issue/sracf_1159-7151_2003_ant1 et Husi 2013 dir. https://journals.openedition.org/racf/1860).Cette publication a comme objectif d’appréhender : (i) la question de la chronologie à partir d’une démarche archéo-statistique originale ; (ii) les questions économiques sociales et culturelles notamment liées aux traditions de fabrication, aux flux et aux échanges de récipien…
Polygalacturonate hydrogels using Fe2+ as cross-linkers : impact of the local association mode on gelation mechanisms, control of the multiscale stru…
2018
This pHD thesis describes the design of polygalacturonate hydrogels (polyGal) cross-linked by the Fe2+ cations, and their experimental characterization from the molecular scales up to the macroscopic scales, by combining EXAFS spectroscopy, Small Angle Neutron Scattering (SANS) and rheological measurements. We designed a robust gelling protocol that allowed to obtain reproducible cylindrical gels with controlled concentration gradients from the lower side to the upper side of the gel. The ratio [Fe]/[Gal] has a constant value all along the gel, which demonstrate that the Fe2+ cations are associated with 4 galacturonate units. The comparison of EXAFS measurements and molecular dynamics simul…