Search results for "N-PENTANOL"

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Relaxation phenomena in mixed isomeric alcohols by Mandelstam-Brillouin scattering

1991

Mandelstam-Brillouin scattering data in mixed isomeric alcohols n-pentanol (nPe-OH) and 2-methyl-2-butanol (2Me-2BuOH) are presented. The hypersonic velocity and normalized absorption are measured as a function of the scattering angle, in the temperature range from - 15-degrees-C to + 45-degrees-C, and as a function of n-PeOH molar fraction going from the pure n-PeOH to the pure 2Me-2BuOH. The experimental results confirm the existence of a shear relaxation phenomenon in the GHz region, that has been previously detected in pure liquids. The temperature dependence of the relaxation time tau-s and of the shear modulus G-infinity evaluated within viscoelastic liquid models, support the existen…

DYNAMICS2-METHYL-2-BUTANOLBiophysicsThermodynamicsN-PENTANOLViscoelasticityShear modulusOpticsRAMAN-SPECTROSCOPYBrillouin scatteringTEMPERATURESSUPERCOOLED WATERPhysical and Theoretical ChemistryMolecular BiologyBulk modulusChemistrybusiness.industryScatteringRelaxation (NMR)STATIC DIELECTRIC-CONSTANTCondensed Matter PhysicsLIGHT-SCATTERINGShear (sheet metal)Shear flowbusinessBONDVISCOSITYMolecular Physics
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Viscosity studies of solutions of water inn-aliphatic alcohols at various temperatures

1979

Viscosity measurements have been made at 25°C on solutions of water inn-propanol, and at 15, 25, 35, and 45°C on solutions of water inn-butanol,n-pentanol, andn-hexanol over the respective solubility ranges. For most of the systems, water decreases the viscosity of the dry alcohols, while for the lower members of the series literature data report an increase in viscosity on addition of water. These results are rationalized in terms of two kinds of interaction between water molecules and alcohols: participation of water molecules in chain formation for the lower alcohols and formation of water-centered complexes for butanol and higher alcohols.

N-pentanolChemistryButanolBiophysicsBiochemistrychemistry.chemical_compoundViscosityChain formationChemical engineeringn-ButanolOrganic chemistryMoleculePhysical and Theoretical ChemistrySolubilityMolecular BiologyJournal of Solution Chemistry
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