Search results for "N-nitrosamines"

showing 2 items of 2 documents

Measurement of pollution levels of N-nitroso compounds of health concern in water using ultra-performance liquid chromatography–tandem mass spectrome…

2017

International audience; This paper reports the development of a highly sensitive analytical method combining solid-phase extraction (SPE) with ultra-high performance liquid chromatography coupled with tandem mass spectrometry (UHPLC–MS/MS), for the monitoring of ultra-trace levels of N-nitrosamines in water samples. Under optimized analytical conditions, chromatographic separation was performed in 3 min, in isocratic mode, using an Acquity UHPLC C18 column and a mobile phase consisting of acetonitrile, water, and formic acid (60:40:0.1, v/v/v) at a flow rate of 0.4 mL min−1. Electrospray ionization tandem interface was employed prior to mass spectrometric detection. Good linearity (R2 ≥ 0.9…

Environmental EngineeringFormic acidGeneral Chemical EngineeringElectrospray ionizationAnalytical chemistry010501 environmental sciencesTandem mass spectrometry01 natural scienceschemistry.chemical_compoundN-nitrosaminesLiquid chromatography–mass spectrometry[CHIM.ANAL]Chemical Sciences/Analytical chemistryEnvironmental ChemistrySolid phase extractionSafety Risk Reliability and QualitySolid phase extraction0105 earth and related environmental sciencesDetection limitChromatography[SDE.IE]Environmental Sciences/Environmental Engineering010401 analytical chemistryExtraction (chemistry)6. Clean water0104 chemical sciencesWater qualityUltra-high liquid chromatography–tandem mass spectrometrychemistry13. Climate actionWater quality[CHIM.OTHE]Chemical Sciences/Other
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N-Methyl-4-(4-nitrophenyl)-N-nitroso-1,3-thiazol-2-amine

2017

The title compound, C10H8N4O3S, is almost planar [dihedral angle between the rings = 2.2 (2)°; r.m.s. deviation for the non-H atoms = 0.050 Å]. In the crystal, C—H...O and C—H...N hydrogen bonds link the molecules into (10-2) layers.

crystal structureHydrogen bondthia­zoleNitrosoCrystal structureDihedral angle010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesMedicinal chemistry0104 chemical sciencesCrystalchemistry.chemical_compoundN-nitro­saminesN-nitrosamineschemistrylcsh:QD901-999NitroAmine gas treatinglcsh:CrystallographyThiazolethiazoleIUCrData
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