Search results for "NF"
showing 10 items of 52916 documents
The high overtone and combination levels of SF6 revisited at Doppler-limited resolution: A global effective rovibrational model for highly excited vi…
2017
Abstract Sulfur hexafluoride is an important prototypal molecule for modeling highly excited vibrational energy flow and multi quanta absorption processes in hexafluoride molecules of technological importance. It is also a strong greenhouse gas of anthropogenic origin. This heavy species, however, features many hot bands at room temperature (at which only 30% of the molecules lie in the ground vibrational state), especially those originating from the lowest, v 6 =1 vibrational state. Using a cryogenic long path cell with variable optical path length and temperatures regulated between 120 and 163 K, coupled to Synchrotron Radiation and a high resolution interferometer, Doppler-limited spectr…
The ~2730 Ma onset of the Neoarchean Yilgarn Orogeny
2017
The timing of the onset of an orogeny is commonly constrained indirectly, because early orogenic structures are rarely exposed, or are overprinted. Establishing the onset of an Archean orogeny is considerably more challenging, because of the more fragmented geological record and the general lack of consensus about Archean geodynamics. We combine existing tectono-stratigraphic data with new structural and geophysical datasets to establish the onset of the Neoarchean Yilgarn Orogeny (Yilgarn Craton, Western Australia). We show that the surface of the c. 2960–2750 Ma deep-marine Yilgarn greenstone sequence was uplifted, eroded and unconformably overlain by a c. 2730 Ma, syntectonic clastic seq…
Plastic ingestion by pelagic and demersal fish from the North Sea and Baltic Sea
2015
Plastic ingestion by marine biota has been reported for a variety of different taxa. In this study, we investigated 290 gastrointestinal tracts of demersal (cod, dab and flounder) and pelagic fish species (herring and mackerel) from the North and Baltic Sea for the occurrence of plastic ingestion. In 5.5% of all investigated fishes, plastic particles were detected, with 74% of all particles being in the microplastic (<5mm) size range. The polymer types of all found particles were analysed by means of Fourier transform infrared (FT-IR) spectroscopy. Almost 40% of the particles consisted of polyethylene (PE). In 3.4% of the demersal and 10.7% of the pelagic individuals, plastic ingestion was …
Assessing optimal water quality monitoring network in road construction using integrated information-theoretic techniques
2020
Author´s accepted manuscript. The environmental impacts of road construction on the aquatic environment necessitate the monitoring of receiving water quality. The main contribution of the paper is developing a feasible methodology for spatial optimization of the water quality monitoring network (WQMN) in surface water during road construction using the field data. First, using the Canadian Council of Ministers of the Environment (CCME) method, the water quality index (WQI) was computed in each potential monitoring station during construction. Then, the integrated form of the information-theoretic techniques consists of the transinformation entropy (TE), and the value of information (VOI) we…
Titan's surface albedo variations over a Titan season from near-infrared CFHT/FTS spectra
2006
International audience; We have observed Titan in a series of campaigns from 1991 to 1996 with the Fourier Transform Spectrometer on the CFH telescope. The data acquired provide a lightcurve from the geometric albedos in the 0.9–View the MathML source spectral region. The 1991–1993 data were previously analyzed in Coustenis et al. [1995. Titan's surface: composition and variability from its near-infrared albedo. Icarus 118, 87–104] with a spherical particle code by McKay et al. [1989. The thermal structure of Titan's atmosphere. Icarus 80, 23–53]. We present here three new datasets from the 1994, 1995 and 1996 observations, with additional information from the 0.94-μm methane window on Tita…
A Plot-scale uncertainty analysis of saturated hydraulic conductivity of a clay soil
2021
Abstract Simulating soil hydrological processes at the plot or field scale requires using spatially representative values of the saturated soil hydraulic conductivity, Ks. Sampling campaigns should yield a reliable mean of Ks with a sustainable workload since measuring Ks at many points is challenging. Uncertainty analysis can be used to determine the lowest number of measurements that yield a mean Ks value with a specified accuracy level. Potential and limitations of this analysis were tested in this investigation for different extents of the sampled area and sampling densities. A clay soil was sampled intensively on two plots (plot area = 44 m2), two dates and using both small (0.15 m in …
Modelling Complex Volume Shape Using Ellipsoid: Application to Pore Space Representation
2017
Natural shapes have complex volume forms that are usually difficult to model using simple analytical equations. The complexity of the representation is due to the heterogeneity of the physical environment and the variety of phenomena involved. In this study we consider the representation of the porous media. Thanks to the technological advances in Computed Topography scanners, the acquisition of images of complex shapes becomes possible. However, and unfortunately, the image data is not directly usable for simulation purposes. In this paper, we investigate the modeling of such shapes using a piece wise approximation of image data by ellipsoids. We propose to use a split-merge strategy and a…
Testing simple scaling in soil erosion processes at plot scale
2018
Abstract Explaining scale effects for runoff and erosion improves our understanding and simulation ability of hydrological and erosion processes. In this paper, plot scale effects on event runoff per unit area (Qe), sediment concentration (Ce) and soil loss per unit area (SLe) were checked at El Teularet-Sierra de Enguera experimental site in Eastern Spain. The measurements were carried out for 31 events occurring in the years 2005 and 2007 in bare ploughed plots ranging from 1 to 48 m2. The analysis established the scaling relationship by dimensional analysis and self-similarity theory, and tested this relationship at different temporal scales ranging from event to annual scale. The dimens…
Historical analysis of rainfall-triggered rockfalls: the case study of the disaster of the ancient hydrothermal Sclafani Spa (Madonie Mts, northern-c…
2017
Abstract. In 1851, the region of Sicily experienced many rainstorm-induced landslides. On 13 March 1851, a rainstorm brought about a severe rockfall disaster near the small town of Sclafani (Madonie Mountains, northern-central Sicily, Italy). Rocks detached from the carbonate crest of Mt Sclafani (813 m above sea level) and fell downslope, causing the collapse of the ancient hydrothermal spa (about 430 m above sea level) and burying it. Fortunately, there were no injuries or victims. Given its geological, geomorphological and tectonic features, the calcareous–dolomitic and carbonate–siliciclastic relief of Mt Sclafani is extremely prone to landsliding. This study combines the findings of de…
Characterisation of the magmatic signature in gas emissions from Turrialba Volcano, Costa Rica
2014
The equilibrium composition of volcanic gases with their magma is often overprinted by interaction with a shallow hydrothermal system. Identifying the magmatic signature of volcanic gases is critical to relate their composition to properties of the magma (temperature, fO2, gas-melt segregation depth). We report measurements of the chemical composition and flux of the major gas species emitted from Turrialba Volcano during March 2013. Measurements were made of two vents in the summit region, one of which opened in 2010 and the other in 2012. We determined an average SO2 flux of 5.2 ± 1.9 kg s-1 using scanning ultraviolet spectroscopy, and molar proportions of H2O, CO2, SO2, HCl, CO and H2 ga…