Search results for "NUMB"
showing 10 items of 3956 documents
Modulation of the ordering temperature in anilato-based magnets
2019
Abstract Four new 2D honeycomb anilato-based ferrimagnets with Mn(II) and Cr(III) have been prepared and characterized. These compounds, formulated as (NBu4)[MnCr(C6O4X2)3(PhCHO)]·PhY (X/Y = Cl/H (1), Br/H (2), Cl/CHO (3) and Br/CHO (4) show that it is possible to include benzaldehyde as a co-ligand coordinated to the Mn(II) metal atom in these 2D ferrimagnets. This inclusion increases the coordination number of Mn(II) to seven resulting in a change in the ordering temperatures of these 2D ferrimagnets (from ca. 10–11 K to ca. 7 K). Here we show the role played by the additional benzaldehyde ligand and by the crystallization solvent molecules (benzene in 1 and 2 and benzaldehyde in 3 and 4)…
Ligand Noninnocence in Cobalt Dipyrrin–Bisphenols: Spectroscopic, Electrochemical, and Theoretical Insights Indicating an Emerging Analogy with Corro…
2019
Three cobalt dipyrrin-bisphenol (DPPCo) complexes with different meso-aryl groups (pentafluorophenyl, phenyl, and mesityl) were synthesized and characterized based on their electrochemistry and spectroscopic properties in nonaqueous media. Each DPPCo undergoes multiple oxidations and reductions with the potentials, reversibility, and number of processes depending on the specific solution conditions, the specific macrocyclic substituents, and the type and number of axially coordinated ligands on the central cobalt ion. Theoretical calculations of the compounds with different coordination numbers are given in the current study in order to elucidate the cobalt-ion oxidation state and the innoc…
Effect of different concentrations of specific inhibitor of matrix metalloproteinases on the shear bond strength of self-adhesive resin cements to de…
2017
Background Considering the probability of chemical and enzymatic reactions between matrix metalloproteinases (MMPs) in the dentin structure and their specific inhibitors, the aim of the present study was to evaluate the effect of different concentrations of specific inhibitor of MMPs (galardin) on the shear bond strength of self-adhesive resin cements to dentin. Material and Methods Forty-eight sound human premolars were mounted in self-cured acrylic resin after removal of the enamel on the buccal and lingual surfaces. The dentin surfaces achieved were polished and prepared with 600-grit silicon carbide paper. The samples were divided into 3 groups (n=16) based on the concentration of galar…
Flow resistance equation for rills
2017
In this paper, a new flow resistance equation for rill flow was deduced applying dimensional analysis and self‐similarity theory. At first, the incomplete self‐similarity hypothesis was used for establishing the flow velocity distribution whose integration gives the theoretical expression of the Darcy–Weisbach friction factor. Then the deduced theoretical resistance equation was tested by some measurements of flow velocity, water depth, cross section area, wetted perimeter, and bed slope carried out in 106 reaches of some rills shaped on an experimental plot. A relationship between the velocity profile, the channel slope, and the flow Froude number was also established. The analysis showed …
Curve Numbers Seasonal Variation in Mid-Mediterranean Area
2018
AbstractThe curve number (CN) method is a popular technique for estimating a rainstorm event’s direct runoff (Q from its storm depth P). It relies on the parameter CN, a lumped expression of a wate...
The BepiColombo MORE gravimetry and rotation experiments with the ORBIT14 software
2016
The BepiColombo mission to Mercury is an ESA/JAXA cornerstone mission, consisting of two spacecraft in orbit around Mercury addressing several scientific issues. One spacecraft is the Mercury Planetary Orbiter, with full instrumentation to perform radio science experiments. Very precise radio tracking from Earth, on-board accelerometer and optical measurements will provide large data sets. From these it will be possible to study the global gravity field of Mercury and its tidal variations, its rotation state and the orbit of its centre of mass. With the gravity field and rotation state, it is possible to constrain the internal structure of the planet. With the orbit of Mercury, it is possib…
Blast waves from violent explosive activity at Yasur Volcano, Vanuatu
2013
[1] Infrasonic and seismic waveforms were collected during violent strombolian activity at Yasur Volcano (Vanuatu). Averaging ~3000 seismic events showed stable waveforms, evidencing a low-frequency (0.1–0.3 Hz) signal preceding ~5–6 s the explosion. Infrasonic waveforms were mostly asymmetric with a sharp compressive (5–106 Pa) onset, followed by a small long-lasting rarefaction phase. Regardless of the pressure amplitude, the ratio between the positive and negative phases was constant. These waveform characteristics closely resembled blast waves. Infrared imagery showed an apparent cold spherical front ~20 m thick, which moved between 342 and 405 m/s before the explosive hot gas/fragments…
Comment on “Rill erosion processes on steep colluvial deposit slope under heavy rainfall in flume experiments with artificial rain by F. Jiang et al.”
2020
Abstract Since rill flows are characterized by small water depths and steeply sloping channels, the corresponding hydraulic conditions are very different to those which are typically found in channels of streams and rivers. Furthermore, limited information is currently available on the effect of rainfall on flow resistance. The objective of this comment was to investigate the applicability of a recently theoretically deduced rill flow resistance equation, based on a power-velocity profile, using measurements carried out by Jiang et al. for both different slope steepness conditions and rainfall intensity. The relationship between the velocity profile parameter Γ, the channel slope and the fl…
Testing a theoretical resistance law for overland flow on a stony hillslope
2020
Overland flow, sediments, and nutrients transported in runoff are important processes involved in soil erosion and water pollution. Modelling transport of sediments and chemicals requires accurate estimates of hydraulic resistance, which is one of the key variables characterizing runoff water depth and velocity. In this paper, a new theoretical power–velocity profile, originally deduced neglecting the impact effect of rainfall, was initially modified for taking into account the effect of rainfall intensity. Then a theoretical flow resistance law was obtained by integration of the new flow velocity distribution. This flow resistance law was tested using field measurements by Nearing for the …
Comparing flow resistance law for fixed and mobile bed rills
2019
Rills caused by run-off concentration on erodible hillslopes have very irregular profiles and cross-section shapes. Rill erosion directly depends on the hydraulics of flow in the rills, which may differ greatly from hydraulics of flow in larger and regular channels. In this paper, a recently theoretically deduced rill flow resistance equation, based on a power–velocity profile, was tested experimentally on plots of varying slopes (ranging from 9% to 26%) in which mobile and fixed bed rills were incised. Initially, measurements of flow velocity, water depth, cross-section area, wetted perimeter, and bed slope, carried out in 320 reaches of mobile bed rills and in 165 reaches of fixed rills, …