Search results for "Names"
showing 10 items of 6843 documents
Phase separation in multi-component mixtures: the four-component case
2002
Abstract Calculation of ternary phase diagrams for several mixtures formed by two salts and a neutral component is presented here. The phase diagrams are obtained by inspection of the shape of the Gibbs free energy of mixing surface (Gmix) as a function of the composition at constant temperature and pressure. The Gmix surface is calculated by the mean spherical approximation (MSA). The model for the mixtures is represented by hard spheres, with the charged components interacting via a Coulomb potential. The results are interpreted in terms of a thermodynamic analysis of the contributions to the Gibbs free energy of mixing, i.e., the configurational energy, the volume and the entropy of mixi…
Lyapunov exponent and topological entropy plateaus in piecewise linear maps
2013
We consider a two-parameter family of piecewise linear maps in which the moduli of the two slopes take different values. We provide numerical evidence of the existence of some parameter regions in which the Lyapunov exponent and the topological entropy remain constant. Analytical proof of this phenomenon is also given for certain cases. Surprisingly however, the systems with that property are not conjugate as we prove by using kneading theory.
Fractal eigenstates in disordered systems
1990
Abstract The wave functions of the non-interacting electrons in disordered systems described by a tight-binding model with site-diagonal disorder are investigated by means of the inverse participation ratio. The wave functions are shown to be fractal objects. In three-dimensional samples, a critical fractal dimension can be defined for the mobility edge in the band centre, which yields the mobility edge trajectory in the whole energy range in good agreement with previous calculations based on the investigation of the exponentially decaying transmission coefficient.
Statistics of return times for weighted maps of the interval
2000
For non markovian, piecewise monotonic maps of the interval associated to a potential, we prove that the law of the entrance time in a cylinder, when renormalized by the measure of the cylinder, converges to an exponential law for almost all cylinders. Thanks to this result, we prove that the fluctuations of Rn, first return time in a cylinder, are lognormal.
Componentwise adaptation for high dimensional MCMC
2005
We introduce a new adaptive MCMC algorithm, based on the traditional single component Metropolis-Hastings algorithm and on our earlier adaptive Metropolis algorithm (AM). In the new algorithm the adaption is performed component by component. The chain is no more Markovian, but it remains ergodic. The algorithm is demonstrated to work well in varying test cases up to 1000 dimensions.
Adaptive Metropolis algorithm using variational Bayesian adaptive Kalman filter
2013
Markov chain Monte Carlo (MCMC) methods are powerful computational tools for analysis of complex statistical problems. However, their computational efficiency is highly dependent on the chosen proposal distribution, which is generally difficult to find. One way to solve this problem is to use adaptive MCMC algorithms which automatically tune the statistics of a proposal distribution during the MCMC run. A new adaptive MCMC algorithm, called the variational Bayesian adaptive Metropolis (VBAM) algorithm, is developed. The VBAM algorithm updates the proposal covariance matrix using the variational Bayesian adaptive Kalman filter (VB-AKF). A strong law of large numbers for the VBAM algorithm is…
Equivalence Testing With Particle Size Distribution Data: Methods and Applications in the Development of Inhalative Drugs
2017
ABSTRACTKey criteria of the quality of inhalative drugs are assessed in experiments generating so-called particle size distributions as data. Many experiments of that kind are carried out to demonstrate that necessary modifications to whatever part of the manufacturing process do not substantially change basic characteristics of an inhalable drug product. The equivalence testing procedures we derive for that purpose rely on different models accommodating the specific structure of such data and on different ways of specifying the region of nonrelevant differences. For each hypotheses formulation, three different tests are derived (two parametric and one asymptotically distribution-free proce…
Bayesian analysis of a Gibbs hard-core point pattern model with varying repulsion range
2014
A Bayesian solution is suggested for the modelling of spatial point patterns with inhomogeneous hard-core radius using Gaussian processes in the regularization. The key observation is that a straightforward use of the finite Gibbs hard-core process likelihood together with a log-Gaussian random field prior does not work without penalisation towards high local packing density. Instead, a nearest neighbour Gibbs process likelihood is used. This approach to hard-core inhomogeneity is an alternative to the transformation inhomogeneous hard-core modelling. The computations are based on recent Markovian approximation results for Gaussian fields. As an application, data on the nest locations of Sa…
Objective Priors for Discrete Parameter Spaces
2012
This article considers the development of objective prior distributions for discrete parameter spaces. Formal approaches to such development—such as the reference prior approach—often result in a constant prior for a discrete parameter, which is questionable for problems that exhibit certain types of structure. To take advantage of structure, this article proposes embedding the original problem in a continuous problem that preserves the structure, and then using standard reference prior theory to determine the appropriate objective prior. Four different possibilities for this embedding are explored, and applied to a population-size model, the hypergeometric distribution, the multivariate hy…
Bayesian Smoothing in the Estimation of the Pair Potential Function of Gibbs Point Processes
1999
A flexible Bayesian method is suggested for the pair potential estimation with a high-dimensional parameter space. The method is based on a Bayesian smoothing technique, commonly applied in statistical image analysis. For the calculation of the posterior mode estimator a new Monte Carlo algorithm is developed. The method is illustrated through examples with both real and simulated data, and its extension into truly nonparametric pair potential estimation is discussed.