Search results for "Names"
showing 10 items of 6843 documents
Thermodynamic and Neutron-Diffraction Studies of H2 and D2 Multilayers Physisorbed on Graphite
1991
The evolution of physisorbed films from two-dimensional (2D) to bulk behavior is a topic of high current interest.1 In this context the behavior of the quantum systems H2, HD and D2 is of particular relevance because of the following reasons: 1. Due to the strong influence of the quantum zero-point energy the hydrogen isotopes are highly compressible. This leads to strongly compressed monolayers2,3 before further layer condensation occurs. This property makes these systems significant for the exploration of conditions of multilayer growth. It is generally believed,1,4–6 that the incompatibility between the adsorbate and bulk lattice structures gives rise to lateral strains between the overl…
High-pressure Raman study of theN2stretching vibration in argon-nitrogen mixtures at room temperature
1996
We present room-temperature Raman investigations of the nitrogen molecule stretching vibration in ${\mathrm{Ar}}_{1\mathrm{\ensuremath{-}}\mathit{x}}$(${\mathrm{N}}_{2}$${)}_{\mathit{x}}$ from x=1 to x=0.59 in the pressure range 1\ensuremath{\le}p\ensuremath{\le}31 GPa. Ar substitution leads to an inhomogeneous broadening of the vibrational signal. The \ensuremath{\beta}-\ensuremath{\delta} phase transition of pure ${\mathrm{N}}_{2}$ is shifted to higher pressures for x=0.75. The substituted Ar atoms preferentially occupy the 2a sites of the cubic elementary cell of the orientationally disordered \ensuremath{\delta} phase. This interpretation of the experimental data is supported by our mod…
Electrochemical impedance spectroscopy of polyelectrolyte multilayer modified gold electrodes: influence of supporting electrolyte and temperature.
2005
Electrochemical impedance spectroscopy and cyclic voltammetry are employed to characterize poly(styrenesulfonate)/poly(allylamine hydrochloride) multilayers assembled onto cysteamine-modified gold surfaces. The influence of the supporting electrolyte and temperature on the impedance response is studied because of both its practical interest and the need to test further the capillary membrane model recently developed by Barreira et al. [J. Phys. Chem. B 2004, 108, 17973]. The results obtained are interpreted quite satisfactorily in terms of this model, thus providing additional support to its usefulness for the description of ionic transport through polyelectrolyte multilayers. It is observe…
Supported iridium catalysts for the total oxidation of short chain alkanes and their mixtures: Influence of the support
2021
13 figures, 3 tables.-- Supplementary information available.-- © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
Computation of the topological type of a real Riemann surface
2014
We present an algorithm for the computation of the topological type of a real compact Riemann surface associated to an algebraic curve, i.e., its genus and the properties of the set of fixed points of the anti-holomorphic involution τ \tau , namely, the number of its connected components, and whether this set divides the surface into one or two connected components. This is achieved by transforming an arbitrary canonical homology basis to a homology basis where the A \mathcal {A} -cycles are invariant under the anti-holomorphic involution τ \tau .
Inflection points and topology of surfaces in 4-space
2000
We consider asymptotic line fields on generic surfaces in 4-space and show that they are globally defined on locally convex surfaces, and their singularities are the inflection points of the surface. As a consequence of the generalized Poincare-Hopf formula, we obtain some relations between the number of inflection points in a generic surface and its Euler number. In particular, it follows that any 2-sphere, generically embedded as a locally convex surface in 4-space, has at least 4 inflection points.
On the Interaction of Carbon Nanowires with Noble Metals through a Study of Their Surface-Enhanced Raman Spectra
2008
This paper deals with the interaction of linear carbon chains (polyynes) with silver and gold surfaces in the form of nanometer-sized clusters. Surface-enhanced Raman signals have been detected rev...
GEPOL: An improved description of molecular surfaces. III. A new algorithm for the computation of a solvent-excluding surface
1994
To understand and calculate the interactions of a solute with a solvent, a good method of computing the molecular surface is needed. Three kinds of surfaces may be used: the van der Waals Surface, the Accessible Surface, and the Molecular Surface. The latter is redefined in this article as the Solvent-Excluding Surface. The new algorithm for computing the Solvent-Excluding Surface included in the GEPOL93 program is described. GEPOL93 follows the same concept as former versions of GEPOL but with a full new algorithm. Thus, it computes the Solvent-Excluding Surface by filling the spaces not accessible to the solvent with a set of new spheres. The computation is controlled by three parameters:…
Towards a full Heusler alloy showing room temperature half-metallicity at the surface
2007
In this article we investigate the surface spin polarization in a 100 nm Co2Cr0.6Fe0.4Al (CCFA) film grown ex situ epitaxially on MgO(100) with a 10 nm Fe buffer layer by means of spin resolved photoemission. We show that a careful in situ preparation of the sample surface leads to values for the room temperature spin polarization up to 45% at the Fermi level. To our knowledge, this is the highest value measured so far at the surface region of a full Heusler alloy at room temperature.
New construction of algebro-geometric solutions to the Camassa-Holm equation and their numerical evaluation
2011
An independent derivation of solutions to the Camassa-Holm equation in terms of multi-dimensional theta functions is presented using an approach based on Fay's identities. Reality and smoothness conditions are studied for these solutions from the point of view of the topology of the underlying real hyperelliptic surface. The solutions are studied numerically for concrete examples, also in the limit where the surface degenerates to the Riemann sphere, and where solitons and cuspons appear.