Search results for "Nanoparticle"
showing 10 items of 2198 documents
Structure, Composition and Magnetic Properties of Ferrofluid Nanoparticles after Separation / Feromagnētisko Šķidrumu Nanodaļiņu Struktūras, Sastāva …
2013
Abstract The structure, composition and magnetic properties of iron oxide nanoparticles are studied as dependent on the synthesis technology and method of separation in ferrofluids. The goal of the present study is to improve the magnetic properties of wet-synthesized nanoparticles and achieve a narrow nanoparticle size distribution. The results of measurements show that by varying the conditions of the chemical coprecipitation method, different compositions and structures of the nanoparticles could be obtained. The separation of ferrite nanoparticles of a polydisperse colloid by centrifugation as well as by HGMS provides the possibility to obtain a nanoparticle set with narrow size distrib…
High field magnetization of the colloidal Mn–Zn ferrite
1999
Abstract The magnetic properties of a hydrocarbon based colloid (stabilized by oleic acid) of polydisperse chemically co-precipitated Mn 0.5 Zn 0.5 Fe 2 O 4 particles are discussed in the paper. Two fractions are separated from an initial ferrofluid sample by centrifugation. X-ray diffraction measurements show the crystal structure of the particles and a broadened shape of the diffraction lines. Mean particle diameters 6.2 nm (the light fraction) and 9.7 nm (the heavy one) were determined by TEM measurements. The magnetization of the colloids is measured by VSM up to 12 T. A significant slope in the magnetization curves in the high field region is displayed for both samples in the temperatu…
Magnetically enhancing the Seebeck coefficient in ferrofluids.
2019
The influence of the magnetic field on the Seebeck coefficient (Se) was investigated in dilute magnetic nanofluids (ferrofluids) composed of maghemite magnetic nanoparticles dispersed in dimethyl-sulfoxide (DMSO). A 25% increase in the Se value was found when the external magnetic field was applied perpendicularly to the temperature gradient, reminiscent of an increase in the Soret coefficient (ST, concentration gradient) observed in the same fluids. In-depth analysis of experimental data, however, revealed that different mechanisms are responsible for the observed magneto-thermoelectric and -thermodiffusive phenomena. Possible physical and physico-chemical origins leading to the enhancemen…
Non-isothermal mass transfer of ferrocolloids through porous membrane
2011
Abstract The present paper deals with transport properties of ferrofluid nanoparticles in non-isothermal capillary-porous layer. Experiment establishes that the temperature difference, which is applied across the layer, induces a thermoosmotic pressure gradient directed toward increasing temperature. The measurement results are interpreted in a frame of phenomenology of linear irreversible thermodynamics. The transport coefficients are evaluated comparing the measured separation curves with approximate solution of the corresponding mass transfer problem.
Shape transitions of giant liposomes induced by an anisotropic spontaneous curvature
2000
International audience; We explore how a magnetic field breaks the symmetry of an initially spherical giant liposome filled with a magnetic colloid. The condition of rotational symmetry along the field axis leads either to a prolate or to an oblate ellipsoid. We demonstrate that an electrostatic interaction between the nanoparticles and the membrane triggers the shape transition. PACS numbers: 75.
Penetration efficiency of nanometer-sized aerosol particles in tubes under turbulent flow conditions
2012
Abstract In order to quantify losses of nanometer-sized particles in turbulent flows through tubes, their penetration efficiencies were measured as a function of the particle size, Stokes number and Reynolds number. The penetration efficiency of tungsten oxide and ammonium nitrate particles with diameters between 3 and 17 nm was investigated in turbulent flow conditions with Reynolds numbers (Re) extending from 4500 to 10,500. The measured penetration efficiencies in straight tubes were found to deviate from the empirical correlation of Lee and Gieseke (1994) . In contrast, the empirical equation of Fan and Ahmadi (1993) agrees better with our experimental results, also in comparison with t…
Determination of the Soret coefficient of magnetic particles in a ferrofluid from the steady and unsteady part of the separation curve
2004
Experiments on the particle separation in a vertical thermodiffusion column are used to investigate the separation (Soret effect) in ferrofluids. The use of a two-sectional column with internal walls of low thermal capacity allows analyzing the initial part of the unsteady separation curves as well as the steady state regime. The Soret coefficient calculated from the measurements of the separation dynamics agrees well with the one found from the steady separation limit reached in long-time experiments especially if the solutal buoyancy is low.
Experimental research of surfaced nanoparticle thermal transport in a porous medium
2018
Abstract Experimental research on thermally induced nanocolloid transport in a porous environment is presented. Addition of excess surfactant to a colloid with dispersed phase made of surfaced nanoparticles results in a decrease of effective Soret coefficient in a porous environment. It is shown that with sufficient amounts of surfactant added, this effect extends to a reversal of nanoparticle thermophoretic transport direction, and that the effect shows a tendency of saturation. A mechanism of thermal transport that involves slip velocity of surfactant molecules appearing near pore walls is evaluated as a possible cause of the decrease of Soret coefficient. Effects of temperature on partic…
Continuous-Flow Synthesis of Ni(0) Nanoparticles Using a Cone Channel Nozzle or a Micro Coaxial-Injection Mixer
2015
To synthesize nickel(0) nanoparticles by wet chemical reduction using hydrazine with an average size distribution below 100 nm, two different reactor concepts were developed. With a cone channel nozzle, the reactant solutions were sprayed into a batch for further processing and reduction at elevated temperatures. Another concept uses a micro-coaxial injection mixer connected to a heated tube to establish a fully continuously operating reactor. To shorten the time for reduction of the nickel, salt temperatures up to 180 °C are applied. To avoid uncontrolled residence time, the whole system was pressurized up to 80 bar. Approximately 80 L reactant solution, i.e., 1 kg nickel(0) nanoparticles,…
Optofluidic microconvection with magnetic nanoparticles: Novel interaction of thermal diffusion and magnetic field
2021
Abstract Light-matter interactions are exploited in many applications, whereas superparamagnetic nanoparticles allow to introduce magnetic field control in diverse fluid environments. We study the structure of laser-induced thermal lens in thin layers of ferromagnetic colloid and predict significant magnetoconvective motion around the beam spot. It was found that localized heating depletes/accumulates magnetic nanoparticles in the beam-spot by thermal diffusion and collective magnetic interactions of nanoparticles produce strong microconvective currents. This mode of mass transport can be controlled by magnetic field. We expect the novel magnetosolutal microconvective coupling, which we des…