Search results for "Nanopores"

showing 4 items of 34 documents

Metal ion affinity-based biomolecular recognition and conjugation inside synthetic polymer nanopores modified with iron-terpyridine complexes.

2011

Here we demonstrate a novel biosensing platform for the detection of lactoferrin (LFN) via metal-organic frameworks, in which the metal ions have accessible free coordination sites for binding, inside the single conical nanopores fabricated in polymeric membrane. First, monolayer of amine-terminated terpyridine (metal-chelating ligand) is covalently immobilized on the inner walls of the nanopore via carbodiimide coupling chemistry. Second, iron-terpyridine (iron-terPy) complexes are obtained by treating the terpyridine modified-nanopores with ferrous sulfate solution. The immobilized iron-terPy complexes can be used as recognition elements to fabricate biosensing nanodevice. The working pri…

chemistry.chemical_classificationLigandPolymersPyridinesSurface PropertiesMetal ions in aqueous solutionIronInorganic chemistrytechnology industry and agricultureGeneral ChemistryBiosensing TechniquesBiochemistryCombinatorial chemistryCatalysisNanoporechemistry.chemical_compoundLactoferrinNanoporesColloid and Surface ChemistrychemistryMonolayerNon-covalent interactionsTerpyridineNanodeviceBiosensorJournal of the American Chemical Society
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Computational methods and theory for ion channel research

2022

Ion channels are fundamental biological devices that act as gates in order to ensure selective ion transport across cellular membranes; their operation constitutes the molecular mechanism through which basic biological functions, such as nerve signal transmission and muscle contraction, are carried out. Here, we review recent results in the field of computational research on ion channels, covering theoretical advances, state-of-the-art simulation approaches, and frontline modeling techniques. We also report on few selected applications of continuum and atomistic methods to characterize the mechanisms of permeation, selectivity, and gating in biological and model channels.

continuum modelsmolecular dynamicselectivityIon channels; biomimetic nanopores; conductance; continuum models; gating; machine learning; molecular dynamics; rare events; selectivityGeneral Physics and AstronomyArticlemolecular dynamicsSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)rare eventsmachine learningcontinuum modelIon channelsgatingddc:530biomimetic nanoporesIon channelbiomimetic nanoporerare eventconductance
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A generalized noise study of solid-state nanopores at low frequencies

2017

Nanopore technology has been extensively investigated for analysis of biomolecules, and a success story in this field concerns DNA sequencing using a nanopore chip featuring an array of hundreds of biological nanopores (BioNs). Solid-state nanopores (SSNs) have been explored to attain longer lifetime and higher integration density than what BioNs can offer, but SSNs are generally considered to generate higher noise whose origin remains to be confirmed. Here, we systematically study low-frequency (including thermal and flicker) noise characteristics of SSNs measuring 7 to 200 nm in diameter drilled through a 20-nm-thick SiNx membrane by focused ion milling. Both bulk and surface ionic curren…

nanopore technologysolid-state nanoporesmelu
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Generalized Noise Study of Solid-State Nanopores at Low Frequencies.

2017

Nanopore technology has been extensively investigated for analysis of biomolecules, and a success story in this field concerns DNA sequencing using a nanopore chip featuring an array of hundreds of biological nanopores (BioNs). Solid-state nanopores (SSNs) have been explored to attain longer lifetime and higher integration density than what BioNs can offer, but SSNs are generally considered to generate higher noise whose origin remains to be confirmed. Here, we systematically study low-frequency (including thermal and flicker) noise characteristics of SSNs measuring 7 to 200 nm in diameter drilled through a 20-nm-thick SiNx membrane by focused ion milling. Both bulk and surface ionic curren…

noiseta221Analytical chemistryIonic bondingBioengineering02 engineering and technologyElectrolyte010402 general chemistry01 natural sciencesNoise (electronics)Flicker noiseInstrumentationFluid Flow and Transfer Processesta114ChemistryProcess Chemistry and TechnologyFlicker021001 nanoscience & nanotechnology0104 chemical sciencesNanoporenanopore technologyChemical physicssolid-state nanoporesIon milling machine0210 nano-technologyVoltageACS sensors
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