Search results for "Near-infrared spectroscopy"
showing 10 items of 138 documents
Hyperfine structure of some near-infrared Xe I and Xe II lines
2011
International audience; This work reports on the experimental determination of the hyperfine splitting of the Xe I lines at 828.01 nm and 834.68 nm and the Xe II line at 834.72 nm. Measurements were performed by means of Doppler-free saturation spectroscopy in a low-pressure radio-frequency discharge. The absolute wavelength of all hyperfine components is obtained by way of a high-precision wavemeter backed-up with the absorption spectrum of the NO 2 molecule. We provide an accurate estimate of hyperfine constants for the lower level of the Xe II transition at 834.72 nm. The two Xe I transition outcomes of our experimental study are compared with data available in the literature.
Visible-NIR reflectance spectroscopy and manifold learning methods applied to the detection of fungal infections on citrus fruit
2015
Abstract The development of systems for automatically detecting decay in citrus fruit during quality control is still a challenge for the citrus industry. The feasibility of reflectance spectroscopy in the visible and near infrared (NIR) regions was evaluated for the automatic detection of the early symptoms of decay caused by Penicillium digitatum fungus in citrus fruit. Reflectance spectra of sound and decaying surface parts of mandarins cv. ‘Clemenvilla’ were acquired in two different spectral regions, from 650 nm to 1050 nm (visible–NIR) and from 1000 nm to 1700 nm (NIR), pointing to significant differences in spectra between sound and decaying skin for both spectral ranges. Three diffe…
Measurement of haemodynamics of exercising and non-exercising vastus lateralis muscle with hybrid diffuse optics
2016
We present simultaneous diffuse correlation spectroscopy (DCS) and time resolved spectroscopy (TR NIRS) measurements on exercising and non-exercising vastus lateralis muscle. We discuss the results at two different exercise levels.
Design and development of a fNIRS system prototype based on SiPM detectors
2014
Functional Near Infrared Spectroscopy (fNIRS) uses near infrared sources and detectors to measure changes in absorption due to neurovascular dynamics in response to brain activation. The use of Silicon Photomultipliers (SiPMs) in a fNIRS system has been estimated potentially able to increase the spatial resolution. Dedicated SiPM sensors have been designed and fabricated by using an optimized process. Electrical and optical characterizations are presented. The design and implementation of a portable fNIRS embedded system, hosting up to 64 IR-LED sources and 128 SiPM sensors, has been carried out. The system has been based on a scalable architecture whose elementary leaf is a flexible board …
Near infrared dyes by combination of squaraine and ferrocene chromophores
2000
Abstract Squaraines represent a class of compounds which attracts a lot of attention in materials science. A synthetic sequence for the preparation of the symmetrical squaraines 12a , b , which contain ferrocene units as electron donors, is described. The compounds exhibit, in dichloromethane or chloroform, two intense absorption bands. One of them is located at 641/650 nm—a normal region for squaraines; however, the other band is strongly shifted to long wavelengths and has its maximum at 921/961 nm. Alkyl sidechains enhance the solubility of 12a , b , which represent a new type of NIR dyes.
Vibrational spectroscopy in soil and sediment analysis
2014
The literature concerning the use of vibrational spectroscopy for soil and sediment analysis, published in the last years, has been revised in order to provide a picture of the strengths and weaknesses of these direct techniques to characterize soil composition and properties. Many soil components as water, organic matter, like humic substances, and minerals, can be determined together with physicochemical parameters as pH, conductivity or redox potential. The main strategies to obtain sample spectra and to extract, as many as possible, useful information were evaluated, taking into account the progress on chemometrics and discussing the whole analytical process, from sampling to sample pre…
Twisted hexaazatrianthrylene: synthesis, optoelectronic properties and near-infrared electroluminescent heterojunctions thereof
2015
The synthesis, optoelectronic properties and near-infrared electroluminescent heterojunctions of a twisted and soluble 7,8,15,16,23,24-hexaazatrianthrylene derivative are reported.
Determination of fatty acids and lipid classes in salmon oil by near infrared spectroscopy
2017
International audience; Near-infrared (NIR) spectroscopy was evaluated as a rapid method for the determination of oleic, palmitic, linoleic and linolenic acids as well as omega-3, omega-6, and to predict polyunsaturated, monounsaturated and saturated fatty acids, together with triacylglycerides, diglycerides, free fatty acids and ergosterol in salmon oil. To do it, Partial Least Squares (PLS) regression models were applied to correlate NIR spectra with aforementioned fatty acids and lipid classes. Results obtained were validated in front of reference procedures based on high performance thin layer and gas chromatography. PLS-NIR has a good predictive capability with relative root mean squar…
Comparison of adsorption properties of commercial silica and rice husk ash (RHA) silica: A study by NIR spectroscopy
2021
Abstract Adsorption properties of Silica gel (commercial silica), rice husk ash (RHA) silica, and their hydrothermally treated products towards water molecules were studied in this work. RHA silica was prepared by heating rice husk to 650°C for 4 h after pretreatment with hydrochloric acid. Portions of the samples of silica were evacuated at 200℃ and then allowed to adsorb water molecules from the surrounding air at either 42 or 50% humidity. The near infrared spectra of these samples were measured at different time intervals during their adsorption of water molecules. The evolved near infrared spectra were analyzed using second derivative techniques. Adsorption properties of these samples …
En-Face differential absorption optical coherence tomography with gold nanorods as the contrast agent
2008
A new variety of nanoparticles showing unique and characteristic optical properties, appeals for its use as contrast agents in medical imaging. Gold nanospheres, nanorods and nanoshells with a silica core are new forms of promising contrast agents which can be tuned to specific absorption or scattering characteristics within the near-infrared (NIR) spectrum ranging from 650 - 1300 nm. They have the ability to be used for both image enhancement and as photosensitive markers due to their well designable scattering and absorption properties. Furthermore, their strong optical absorption permits treatment of malignant cells by photoablation processes, induced when heating them with a matched lig…