Search results for "Nitrogen"
showing 10 items of 1200 documents
Co-ordination of copper(II) ions by prolyl-α,β-dehydroamino acids: comparative studies and general considerations
1996
Potentiometric and spectroscopic measurements and theoretical calculations have revealed that α,β-dehydroamino acid residues have a considerable effect on the co-ordination ability of an adjacent amide nitrogen towards Cu2+ ions. Also the side chain of such residues affects the stability constants and, in some cases, the binding mode of short peptides containing α,β-dehydroamino acid residues. The theoretical calculations showed that all dehydroamino acids except α,β-dehydroalanine tend to bend a peptide chain towards a turn conformation. This has a very strong impact on the co-ordination ability of a dehydropeptide ligand.
Holothuria tubulosa Gmelin 1791 (Holothuroidea, Echinodermata) enhances organic matter recycling in Posidonia oceanica meadows
2014
Abstract The role of Holothuria tubulosa in organic matter recycling of Posidonia oceanica detritus was estimated in a laboratory feeding experiment. The individual mean ingestion rate of seagrass detritus by holothurians was evaluated and carbon and nitrogen stable isotopes, carbon and nitrogen content and C:N ratio analyzed in H. tubulosa , P. oceanica detritus and surface sediment. Results showed that H. tubulosa is capable of ingesting from 30% to 100% of the detritus produced by P. oceanica meadows, depending on the holothurian density. Stable isotope analysis provided evidence for the assimilation of seagrass detritus by H. tubulosa as their signatures were compatible with 1 trophic l…
Studies on the Content of Free Amino Acids in Needles of Undamaged and Damaged Spruce Trees at a Natural Habitat
1990
Summary Measurements of the amino acids in needles of undamaged and damaged 90-year-old spruce trees ( Picea abies ) showed different patterns. During the summer months a reduction in total amino acid content of about 60 % was found. In autumn the content of total amino acids rose again. The courses of the single amino acids behave similarly to that of the total amino acids. Quantitatively, the main amino acids were GLU, ASP and GLN with about 37 %, 21 % and 10 %, respectively, followed by PRO, ALA and SER with about 3–4 % each. In the needles of healthy trees large variations in ARG content could be observed. These variations correlate neither with the damage degree of the trees nor with t…
The effect of arbuscular mycorrhizal fungi on total plant nitrogen uptake and nitrogen recovery from soil organic material
2013
SUMMARYArbuscular mycorrhizal (AM) fungi increase nitrogen (N) uptake by their host plants, but their role in plant N capture from soil organic material is still unclear. In particular, it is not clear if AM fungi compete with the host plant for the N coming from the decomposing organic matter (OM), especially when the AM extraradical mycelium (ERM) and plant roots share the same soil volume. The goal of the present research was to study the effects of AM fungi on wheat N capture after the addition of 15N-labelled OM to soil. Durum wheat (Triticum durum) was grown under controlled conditions in a sand:soil mix and the following treatments were applied: (1) AM inoculation with Glomus mosseae…
Nitrate leaching in soil: Tracing the NO3− sources with the help of stable N and O isotopes
2007
Abstract Legumes increase the plant-available N pool in soil, but might also increase NO3− leaching to groundwater. To minimize NO3− leaching, N-release processes and the contribution of legumes to NO3− concentrations in soil must be known. Our objectives were (1) to quantify NO3−-N export to >0.3 m soil depth from three legume monocultures (Medicago x varia Martyn, Onobrychis viciifolia Scop., Lathyrus pratensis L.) and from three bare ground plots. Furthermore, we (2) tested if it is possible to apply a mixing model for NO3− in soil solution based on its dual isotope signals, and (3) estimated the contribution of legume mineralization to NO3− concentrations in soil solution under field co…
and variability in Posidonia oceanica associated with seasonality and plant fraction
2003
Abstract The carbon and nitrogen isotopic compositions of fractions of the seagrass Posidonia oceanica (L.) Delile in a Mediterranean shallow environment (Stagnone di Marsala, western Sicily) were investigated seasonally throughout 1998. The stable isotope ratios of seagrass leaves (intermediate and adult), rhizomes, leaf litter and aegagropiles were compared over 1 year in order to distinguish between seasonal and plant part variability. Significant differences in the isotopic composition tested using ANOVA were observed as a function of both plant fraction and season. There was an overall trend towards less discrimination against 13 C in summer (average δ 13 C ∼ −10‰) than in winter (aver…
Production of 6-pentyl-?-pyrone byTrichoderma harzianum from 18?n fatty acid methyl esters
1992
Biosynthesis of 6-pentyl-α-pyrone byTrichoderma harzianum in two different media was evaluated. Best yields were found in nitrogen deficient medium (C/N=60). Limited growth seems to favour the production of this lactone. When fungal cells, precultured in low nitrogen medium, were incubated on methyl ricinoleate (10 g/l, C/N=60) an increase in 6-pentyl-α-pyrone production was observed in comparison with the media containing methyl oleate or methyl linoleate.
Influence of Nitrogen Content on Grape Non-Saccharomyces Glycosidic Activities
2019
This study investigated the influence of nitrogen content on both β-glucosidase and β-xylosidase activities from non-Saccharomyces yeasts. Enzymatic activities were induced by the presence of xylan polysaccharides in the medium. Results show that optimizing β-glucosidase and β-xylosidase enzymatic activities can be determined not only by sugar or ethanol content or pH, but also by the concentration of N in the medium. This is the first work studying the influence of N content on glycolytic enzymes produced by non-Saccharomyces yeasts.
An alternative route to 2H-naphtho[1,2-b]thiete and its cycloaddition products
1998
2-(1H-Benzotriazol-1-ylmethyl)-1-naphthalenol (1) can be transformed in high yields to the corresponding thiol 4. Flash vacuum pyrolysis of 4 leads to 2H-naphtho[1,2-b]thiete (5). The benzotriazolyl group proved to be a good leaving group; however, a subsequent nitrogen extrusion takes place under flash vacuum pyrolysis conditions and cyclopentadienecarbonitriles 6a,b are formed by a ring contraction (Scheme 1). Cycloaddition reactions of 5 and dienophiles or heterodienophiles yield the naphtho-condensed sulfur heterocycles 8, 10, 12 and 14 (Scheme 2).
Effective Removal and Mineralization of 8-Hydroxyquinoline-5-sulfonic Acid through a Pressurized Electro-Fenton-like Process with Ni−Cu−Al Layered Do…
2020
Ni−Cu−Al layered double hydroxide (Ni−Cu−Al LDH) was proposed as an electro‐Fenton‐like catalyst for 8‐hydroxyquinoline‐5‐sulfonic acid (8‐HQS) removal in water. The properties of the prepared catalysts were characterized by using X‐ray, SEM and EDAX analyses. The effect of numerous operative parameters on the removal of 8‐HQS and total organic carbon (TOC) was studied. Very high level removal of both 8‐HQS and TOC (87 and 79 %, respectively) were obtained by using a pressurized electro‐Fenton‐like process (PrEFL‐LDH) at P=10 bars, using a Ti/IrO2‐Ta2O5 anode for 6 h. The process presented good performances in a large range of pH (3–10) and gave better removals of 8‐HQS and TOC with respect…