Search results for "Nitrogen"

Molecular ND Band Spectroscopy in the Divertor Region of Nitrogen Seeded JET Discharges

2018

In this contribution we present OES measurements in the JET tokamak of the deuterated NH (ND) radical and the correlation between results of those experiments and measurement of ammonia production. The observation region covers most of the divertor and its outer throat. Measurements are performed in different magnetic configurations. The results include temporal and spatial dependence of the molecular emission intensity and study of the emission band shape (vibrational and rotational temperatures) during different JET pulses, with or without nitrogen seeding. Results are a step towards the understanding of nitrogen-containing molecule creation and destruction in the divertor plasma. For com…

Theoretical investigations of nitrogen doping on Co 3 O 4 for water dissociation catalytically activity

2018

We report the results of theoretical investigations of nitrogen doping on Co 3 O 4 (100) bulk by means of the plane-wave periodic density functional theory (DFT) calculations combined with the Hubbard-U approach and statistical thermodynamics.Using accurate DFT+U calculations, we have shown that bulk Co ions denote charges in value 0.017 - 0.57e. For further water adsorption process studies was selected structures with most changes in charges in Co ions: (3) structure for n = 25%, (2) structure forn = 12.5% and structure for (1) structure.

Optimising an outdoor membrane photobioreactor for tertiary sewage treatment

2019

[EN] The operation of an outdoor membrane photobioreactor plant which treated the effluent of an anaerobic membrane bioreactor was optimised. Biomass retention times of 4.5, 6, and 9 days were tested. At a biomass retention time of 4.5 days, maximum nitrogen recovery rate:light irradiance ratios, photosynthetic efficiencies and carbon biofixations of 51.7¿±¿14.3¿mg¿N·mol¿1, 4.4¿±¿1.6% and 0.50¿±¿0.05¿kg CO2·m3influent, respectively, were attained. Minimum membrane fouling rates were achieved when operating at the shortest biomass retention time because of the lower solid concentration and the negligible amount of cyanobacteria and protozoa. Hydraulic retention times of 3.5, 2, and 1.5 days …

Improvement of the nitrogen uptake induced by Ti(IV) supply in nitrogen stressed pepper crops

1996

The beneficial effect of titanium on plant metabolism can result in a more profitable use of fertilizers on many crops. An experiment was performed in a greenhouse with Capsicum annuum L. cv. Bunejo plants cultivated under different levels of nitrogen fertilization: 100% N — 250 N fertilizer units/ha (NFU); 75% N - 187.5 NFU; 50% N - 125 NFU; 25% N - 62.5 NFU. A third of the plants in each N support remained Ti-untreated and were used as a reference. Each of the other thirds received one and two 2 mg Ti/l, pH 6, leaf spray treatments respectively (35 ml/plant). Biomass production of the Ti-untreated references was only affected by N-supplies of 25%. Ti leaf spray treatments induced a biomas…

Different effectors of dimorphism in Yarrowia lipolytica

2002

Yarrowia lipolytica is an ascomycete with biotechnological potential. In common media, the fungus grows as a mixture of yeast-like and short mycelial cells. The environmental factors that affect dimorphism in the wild-type strain, W29, and its auxotrophic derivative, PO1a, were analyzed. In both strains, pH was the most important factor regulating the dimorphic transition. Mycelium formation was maximal at pH near neutrality and decreased as pH was lowered to become almost null at pH 3. Carbon and nitrogen sources, namely glucose and ammonium, were also important for mycelium formation; and their effect was antagonized by some alternative carbon and nitrogen sources. Citrate was an importan…

NMR spectral and X-ray structural investigation of 1,3-bis(2-quinolyl)-2-(p-chlorophenyl)-2-propanol

2000

Abstract 1,3-Bis(2-quinolyl)-2-(p-chlorophenyl)-2-propanol (BQCP) has been prepared and characterised by 1H, 13C, 15N NMR spectral and X-ray structural parameters. The methylene protons of BQCP are diastereotopic in solution (CDCl3) as revealed by 1H NMR. In crystalline state there exists an intramolecular hydrogen bond O–H⋯N with one of two nitrogen atoms in BQCP. Variable temperature 1H NMR and PFG 1H, 15N HMBC runs show that in solution BQCP shows C2v-symmetry (both CH2-2-quinolyl fragments are equivalent) in NMR-time scale due to a fast exchange of the hydrogen bond from one nitrogen to the other even at 223 K.

Study of the effect of H2S, MeSH and DMS on the sensory profile of wine model solutions by Rate-All-That-Apply (RATA)

2016

The effect of hydrogen sulfide (HS), methanethiol (MeSH) and dimethyl sulfide (DMS) on the odor properties of three wine models-WM- (young white, young red and oaked red wines) was studied. Wine models were built by mixing a pool of common wine volatile and non-volatile compounds and further spiked with eight different combinations of the three sulfur compounds present at two levels (level 0: 0 μg L and level 1: 40 μg L of HS, 12 μg L of MeSH; 55 μg L of DMS). For each wine matrix eight WMs were produced and further submitted to sensory description by Rate-All-That-Apply (RATA) method. Hydrogen sulfide and methanethiol were clearly involved in the formation of reductive aromas and shared th…

Effect of percentual water content in tissues and liquids on the diffusion coefficients of O2, CO2, N2, and H2.

1976

Long-term dynamics of water-borne nitrogen, phosphorus and suspended solids in the lower Don River basin (Russian Federation)

2011

A long-term study (1986–2002) of water-borne nutrient and suspended solids dynamics was undertaken on the lower Don River, which plays an extremely important role in the water supply of the Black Sea and Azov Sea basin. Suspended solids were greatest in spring and summer and were correlated to river discharge. Mean annual nitrogen concentrations increased from 1986 to 1995 and then decreased from 1996 to 2002. Unlike nitrogen, phosphorus concentrations (both phosphates and total phosphorus) gradually increased throughout the study period changing the river from an oligotrophic to upper mesotrophic status. If this trend continues phytoplankton could become nitrogen-limited leading to the dev…

Short-term emissions of CO 2 and N 2 O in response to periodic flood irrigation with waste water in the Mezquital Valley of Mexico

2015

Irrigation with waste water adds labile carbon and nitrogen compounds to the soil, and when applied by flooding it rapidly changes the soil's atmosphere and redox potential. In the Mezquital Valley more than 90 000 ha is irrigated with waste water from Mexico City, and enhanced emissions of CO2 and N2O follow each flooding. We measured the emissions of these two gases from a field irrigated periodically with waste water and under three crops, namely alfalfa, rye-grass and maize, using static chambers for 21 months. We also measured emissions from a field growing rain-fed maize before and shortly after two rain events. The data from repeated measurements from the same chambers are correlated…