Search results for "Note"
showing 10 items of 10709 documents
Surface topography of membrane domains
2010
金沢大学理工研究域数物科学系
Application of fractal geometry to dissolution kinetic study of a sweetener excipient
2001
Abstract In the context of relationship study between dissolution kinetic and particle morphology using the fractal geometry tool, we use a commercially available quality of saccharin powder. The characterization of molecular feature and image analysis study allows us to conclude to the statistic self-similarity of particles of four sieved particles size fractions, permitting the fractal approach. Calculation of reactive fractal dimension is performed using two forms of mass transfer equation: −d Q /d t = kQ D R /3 Δ C and −d Q /d t = k′R D R −3 Δ C , with Δ C ={ C f /[ln C s /( C s − C f )]}. Based on comparison of the surface fractal dimension D S on the two values of reactive fractal di…
Surface segregation trends in transition metal alloys
2013
In this work, we revisit the problem of predicting the surface segregation trends in binary transition metal alloys from the knowledge of the basic features of the pure component $d$-band electronic structure within tight-binding approximation. In contrast to previous trend studies, the present one includes, within the fourth-moment approximation (FMA) of the tight-binding scheme, both the difference in the average band energies (diagonal disorder) and the difference in the band widths (off-diagonal disorder) of the two components. We show that treating on the same footing these two effects is essential for a correct prediction of surface segregation. The presented study, giving a natural l…
Standardization of Methods for Characterizing the Surface Geometry of Solids
2003
Since a comprehensive survey published in 1999 [1] much work was done in standardizing measuring methods to characterize the surface geometry of dispersed and/or porous solids and to certify reference materials. The present paper is an extension of a short communication [2]. It gives a survey on existing standards and reports on new drafts and proposals.
New insight into the aptamer conformation and aptamer/protein interaction by surface-enhanced Raman scattering and multivariate statistical analysis
2021
International audience; We study the interaction between one aptamer and its analyte (the MnSOD protein) by the combination of surface-enhanced Raman scattering and multivariate statistical analysis. We observe the aptamer structure and its evolution during the interaction under different experimental conditions (in air or in buffer). Through the spectral treatment by principal component analysis of a large set of SERS data, we were able to probe the aptamer conformations and orientations relative to the surface assuming that the in-plane nucleoside modes are selectively enhanced. We demonstrate that the aptamer orientation and thus its flexibility rely strongly on the presence of a spacer …
Applying Experimental Research Management to a Technological Process using Taguchi's Method
2018
Abstract The surface quality is dependent on certain cutting process parameters that can vary, causing variations on the surface roughness. The main subject of this paper focuses on the experimental research management applied to a technological process whose final purpose was to determine an equation of the surface roughness depending on the process parameters, obtained by the Al7136 end milling process. The research method used in this paper is the Taguchi's method. According to the research management steps, in order to perform the experimental determination of the surface roughness, an experimental stand used to determine the objective function was presented. The surface roughness equat…
Mixed Polymer Brushes: Switching of Surface Behavior and Chemical Patterning at the Nanoscale
2005
The dielectric α -relaxation in polymer films: A comparison between experiments and atomistic simulations
2013
The question of whether the glass transition temperature in thin polymer films depends on the film thickness or not has given rise to heated debate for almost two decades now. One of the most puzzling findings is the seemingly universal thickness independence of the dielectric α-relaxation observed for supported films. It is puzzling not only in view of the fact that other techniques or other geometries sometimes showed a significant shift of as a function of film thickness, but more so, because computer simulations for all types of polymer film models revealed changes in the structure and dynamics close to a hard surface or a free surface. Our results suggest to explain this apparent contr…
Controlling the Interactions between Soft Colloids via Surface Adsorption
2013
By employing monomer-resolved computer simulations and analytical considerations based on polymer scaling theory, we analyze the conformations and interactions of multiarm star polymers strongly adsorbed on a smooth, two-dimensional plane. We find a stronger stretching of the arms as well as a stronger repulsive, effective interaction than in the three dimensional case. In particular, the star size scales with the number of arms $f$ as $\sim f^{1/4}$ and the effective interaction as $\sim f^{2}$, as opposed to $\sim f^{1/5}$ and $\sim f^{3/2}$, respectively, in three dimensions. Our results demonstrate the dramatic effect that geometric confinement can have on the effective interactions and…
Modular approach towards multi-functional surfaces with adjustable and dual-responsive wettability using a hybrid polymer toolbox
2009
Poly(methylsilsesquioxane)-based hybrid polymers carrying orthogonally reactive moieties demonstrate an effective modular approach to creating multi-reactive surface coatings. By a sequential surface-analogous reaction different functions could be immobilized in a defined ratio, resulting in dual- or triple-functionalized surfaces.