Search results for "Note"
showing 10 items of 10709 documents
Analysis of highly excited 'hot' bands in the SO2 molecule: ν2 + 3ν3 - ν2 and 2ν1 + ν2 + ν3 - ν2
2010
International audience; We set up a variational procedure of assignments of transitions and we applied it to the analysis very weak 'hot' bands, v(2) + 3v(3) - v(2) and 2v(1) + v(2) + v(3) - v(2), of the SO2 molecule. As the first step of the study, the 'cold' bands, 3v(3) and 2v(1) + v(3), are re-analysed and transitions belonging to those bands are assigned up to the values of quantum numbers J(max.) = 60, K-a(max.) = 19, and J(max.) = 69, K-a(max.) = 20 for the bands 3v(3) and 2v(1) + v(3), respectively. After 'cleaning' the experimental spectrum from transitions belonging to the 3v(3) and 2v(1) + v(3) bands, a variational procedure was used that allowed us to assign 230 and 115 transiti…
Structures of single, double and triple layers of lipids adsorbed on graphene: Insights from all-atom molecular dynamics simulations
2017
Abstract Non-covalent functionalization of graphene with phospholipids is a promising technique for biosensing applications and intracellular delivery of analytical probes and drugs. However, molecular details of the self-assembly of lipids on graphene surface is still poorly understood and hard to control. There is a clear lack of understanding of why various kinds of lipid aggregates can form on graphene. In the current work, we address this question by investigating equilibrium and dynamical properties of lipid layers adsorbed on graphene in water environment and in vacuum using all-atom Molecular Dynamics simulations. It is shown that a variety of lipid aggregates can form on top of gra…
Histoire d'un brise-glace : le festival Why Note et son public
2012
National audience
A new invariant-based method for building biomechanical behavior laws - Application to an anisotropic hyperelastic material with two fiber families
2013
Abstract In this article, we present a general constructive and original approach that allows us to calculate the invariants associated with an anisotropic hyperelastic material made of two families of collagen fibers. This approach is based on mathematical techniques from the theory of invariants: • Definition of the material symmetry group. • Analytical calculation of a set of generators using the Noether’s theorem. • Analytical calculation of an integrity basis. • Comparison between the proposed invariants and the classical ones.
Suivi de l'endommagement dans les structures en composites par une analyse optique in-situ
2009
National audience; Ce travail présente une technique de détection et de suivi de l'endommagement dans les structures en matériaux composites. Les mécanismes d'endommagement dans ces matériaux sont complexes. Dès lors que l'on souhaite modéliser le comportement d'une structure, il est important de comprendre comment celle-ci s'endommage. La méthode optique d'observation in-situ proposée est appliquée au cas d'une plaque trouée.
A physical-based constitutive model for surface integrity prediction in machining of OFHC copper
2017
International audience; Due to the rising interest in predicting machined surface integrity and sustainability, various models for metal cutting simulation have been developed. However, their accuracy depends deeply on the physical description of the machining process. This study aims to develop an orthogonal cutting model for surface integrity prediction, which includes a physical-based constitutive model of Oxygen Free High Conductivity (OFHC) copper. This constitutive model incorporates the effects of the state of stress and microstructure on the work material behavior, as well as a dislocation density-based model for surface integrity prediction. The coefficients of the constitutive mod…
Influence of cutting process mechanics on surface integrity and electrochemical behavior of OFHC copper
2014
The authors gratefully acknowledge the support received from IC ARTS and CEA Valduc; International audience; Superfinishing machining has a particular impact on cutting mechanics, surface integrity and local electrochemical behavior. In fact, material removal during this process induces geometrical, mechanical and micro-structural modifications in the machined surface and sub-surface. However, a conventional 3D cutting process is still complex to study in terms of analytical/numerical modeling and experimental process monitoring. So, researchers are wondering if a less intricate configuration such as orthogonal cutting would be able to provide information about surface integrity as close as…
Modelling of interference fits with taking into account surfaces roughness with homogenization technique
2013
International audience; The assembly technique by shrink fit is increasingly used today because it allows for the assembly of two pieces without any intermediary part simply by the tightening effect given by the difference in diameters of the two parts assembled. The definition of assemblies depends on calculation models available in the standard. They make very restrictive assumptions that limit the geometrical defects and the surface finish. It is increasingly common to use a finite element method to better adapt the model to the complex forms of industrial parts. However, the standard is limited with regard to the consideration of roughness which results in a loss of tightening. An easy …
Modeling of interference fits taking form defects of the surfaces in contact into account
2011
Abstract The technique of assembly by shrink fit is increasingly used today. However, the methodology of parts sizing has not changed in 50 years. Assembled parts are assumed to have accurate dimensions and very low form defects. This has the disadvantage of increasing the cost of parts production. To reduce manufacturing costs, the study of the influence of form defects on the characteristics of assembly strength is essential. Taking default form into account assumes that the tightening (difference between the diameters of the shaft and the bore) is defined. In the case under consideration, the tightening depends locally on the radius. Two definitions of the tightening are proposed: maximu…
Portlandite solubility and Ca 2+ activity in presence of gluconate and hexitols
2021
The current paper investigates the impact of gluconate, D-sorbitol, D-mannitol and D-galactitol on calcium speciation at high pH values by i) solubility measurements of portlandite (Ca(OH)2) and ii) potentiometric titration measurements of calcium salt solutions. Thermodynamic modeling was used to fit the chemical activities of Ca2+ and OH- ions and thus to determine the strength and kind of the different Ca-organic-hydroxide complexes. The strength of complex formation with Ca decreases in the order gluconate >> sorbitol > mannitol > galactitol, which follows the same order as sorption on portlandite. Heteropolynuclear gluconate complexes with calcium and hydroxide dominate the…