Search results for "Nucleogenic"
showing 4 items of 4 documents
Time integral and time differential Mössbauer measurements on [57Co/Mn(bipy)3](PF6)2
1994
The Mossbauer emission spectra of nucleogenic iron(II) complexes with a low spin (LS) ground state show two metastable iron(II) high spin (HS) states at low temperatures. In order to identify these metastable HS states, the compound [57Co/Mn(bipyridine)3](PF6)2 has been studied by time differential Mossbauer emission spectroscopy (TDMES) and optical lifetime measurements of excited electronic states in the corresponding Fe-doped Mn compound. The lifetime of one of the HS states of the nucleogenic iron(II) determined by TDMES has been measured to be the same as the lifetime of the laser-excited iron(II) electronic state.
Advances in Mössbauer Emission Spectroscopy
1990
After effects following nuclear transformation have been extensively studied in a large variety of matrices by Mossbauer Emission Spectroscopy (MES). The branching ratios of transient atomic charge states and energetically unstable states of the environment, excitations of electronic ligand field states and populations out of equilibrium within the electronic ground state manifold have been studied. Recent developments and also new insights and understandings of different aspects of the aftereffects of radioactive decay of57Co in semiconductors and molecular crystals are reviewed. A detailed picture of the decay process within the electronic states of the nucleogenic Fe3+ species could be o…
Comparative Mössbauer spectroscopic study of iron impurities in ZnSe
2001
Abstract An anomalous spectral doublet attributed to Fe 2+ impurity pairs is observed in Mossbauer absorption spectra of 57 Fe 0.01 Zn 0.99 Se below room temperature. In Mossbauer emission experiments, ZnSe: 57 Co polycrystal and powder sources exhibit below 45 K the nucleogenic Fe 1+ valence state born as an after effect of the electron-capture decay of 57 Co. Above 8 K, the proportion of the nucleogenic Fe 1+ decreases under the effect of the thermally activated Fe 1+ →Fe 2+ relaxation. The activation energy is estimated to 0.004 eV. While nucleogenic Fe 1+ is absent in ZnSe: 57 Co single crystal spectra, increasing proportions are detected in samples with an enhanced specific surface. Th…
MORB-type neon in an enriched mantle beneath Etna, Sicily
1997
Abstract Noble gas elemental and isotopic compositions were determined for five CO 2 –CH 4 samples collected around Etna, Sicily, to investigate the geochemical features of the mantle beneath the volcano. The samples contain mantle-derived noble gases. The measured helium isotopic ratios ( 3 He/ 4 He) vary between 5.9 and 6.4 times atmospheric ratio ( R a =1.4×10 −6 ), which are comparable to the ratios of olivines (6.1–8.2 R a ) in the lavas of the same volcano [1]. Neon in the samples is enriched in both 20 Ne and 21 Ne ( 20 Ne/ 22 Ne 9.95–10.7, 21 Ne/ 22 Ne 0.030–0.037), indicating derivation from the mantle. The δ ( 20 Ne/ 22 Ne)/ δ ( 21 Ne/ 22 Ne) values are identical with that of mid-…