Search results for "Numeral system"
showing 10 items of 124 documents
Thermodynamic properties of water-β-cyclodextrin-dodecylsurfactant ternary systems
1995
Densities, heat capacities and conductivities of water-surfactant-β-cyclodextrin (β-CD) ternary systems were determined at 25°C. The surfactants studied were sodium dodecylsulfate (NaDS) and dodecyltrimethylammonium bromide (DTAB). From conductivity data, apparent critical micelle concentrations (cmc*) and degree of ionization of micelles were obtained at a fixed β-CD concentration (mCD). From the cmc* value and that in water (cmc) the stoichiometry of the surfactant-β-CD complex was calculated. At a given mCD, the apparent molar volume Vϕ,CD and heat capacity Cϕ,CD of β-CD in the two surfactants were calculated as functions of surfactant concentration mS. For both NaDS and DTAB, Vϕ,CD incr…
Thermodynamics of a polymer blend solution system studied by gel permeation chromatography and viscosity
1999
Binary and ternary interaction parameters and their derivatives have been calculated with the Flory-Huggins formalism developed for a ternary polymer system. The equilibrium compositions of the ternary system tetrahydrofuran/polybutadiene/polystyrene that forms two phases in equilibrium at 25°C have been used to solve the binodal equations. With this set of parameters, the viscosimetric interaction parameters have been computed. For the sake of comparison, the experimental viscosimetric parameter has been determined from intrinsic viscosity data of a polymer (3) in a "binary solvent" (solvent + polymer (2)). It has been clearly shown that composition-dependent parameters are necessary to re…
Isobaric Vapor−Liquid and Liquid−Liquid Equilibria for Chloroform + Methanol + 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate at 100 kPa
2009
Isobaric vapor−liquid equilibria for the binary system chloroform + methanol as well as the vapor−liquid equilibria for the chloroform + methanol + [emim][triflate] ternary system have been obtained at 100 kPa using a recirculating still. The ternary ionic liquid (IL) system presents an immiscibility zone at high chloroform composition, which increases with the temperature. Liquid−liquid equilibria for this system have also been determined. The measured ternary vapor−liquid equilibrium data were correlated using the Mock’s electrolyte nonrandom two-liquid (NRTL) model which reproduces reasonably well the experimental values and predicts the total disappearance of the azeotrope when the mole…
Phase behavior of aqueous solutions of bovine serum albumin in the presence of dextran, at rest, and under shear.
2006
The demixing conditions for aqueous solutions of bovine serum albumin (BSA, fraction V) and for joint solutions of BSA plus dextran (DEX, M(w) = 2000 kg/mol) were determined by turbidimetric measurements as a function of composition, temperature, and shear rate. Aqueous solutions of BSA phase separate upon heating. Within the region of BSA concentrations between 0.05 and 32 wt %, the demixing temperature, T1, falls from ca. 65 degrees C to an almost constant value of 45 degrees C. Adding DEX to the BSA solutions reduces the homogeneous region of the mixture drastically where the amount of DEX required to lower T1 to 25 degrees C decreases rapidly as the concentration of BSA is raised. Exper…
N-Isopropylacrylamide andN-Isopropylmethacryl-amide: Cloud Points of Mixtures and Copolymers
2001
The cloud point curve of aqueous solutions of poly(N-isopropylacrylamide), poly(N-isopropylmethacrylamide) and their statistical copolymers were determined turbidimetrically. All the Systems demix upon heating at the cloud point temperature and mix reversibly upon cooling. The cloud points are independent of the total concentration of the solutions (dilute range) and of the sample thickness. Mixtures of the homopolymers poly(N-isopropylacrylamide) and poly(N-isopropylmethacrylamide) in water (ternary systems) exhibit two cloud points, which are nearly the same as the cloud points of the two binary systems homopolymer/water. A quantitative correlation was found between the cloud point temper…
Short article: Does the brain regularize digits and letters to the same extent?
2009
The cognitive system does not just act as a mirror from the sensory input; instead, it tends to normalize this information. Given that letter processing seems to be much more specialized than digit processing in the cortex, we examined whether the regularization process occurs differently from digits to letters than from letters to digits: We employed a masked priming same/different experiment (e.g., probe, VESZED; prime, V35Z3D; and target, VESZED). When embedded in letter strings, digits that resemble letters (e.g., 3 and 5 in V35Z3D-VESZED) tend to be encoded in a letter-like manner, whereas when embedded in digit strings, letters that resemble digits (e.g., E and S in 9ES7E2–935732) te…
Isobaric vapor–liquid equilibria for the system 1-pentanol–1-propanol–water at 101.3 kPa
2001
Consistent vapor–liquid equilibrium data for the ternary system 1-pentanol–1-propanol–water is reported at 101.3 kPa at temperatures in the range of 362–393 K. The VLE data were satisfactorily correlated with UNIQUAC model. The authors wish to thank the Generalitat Valenciana (Spain) for the financial help of the Project GV-3174/95 and DGES for the financial aids of the Project PB96-0338.
The article <i>a(n)</i> in English quantifying expressions: A default marker of cardinality
2020
Certain English quantificational expressions feature what appears to be an indefinite article, e.g. a bunch, a few, a hundred. These can be divided into three types of quantifying expressions: pseudopartitives (a lot, a bunch, a ton), article-requiring quantifiers (a few, a couple, a hundred), and article-free quantifiers (three, many, several); article-free quantifiers have an article under certain circumstances, e.g. modification by an adjective (a surprising 30 …). While standard analyses would take the article in these expressions to be a D head, it is argued here that the article is not in D, nor is it singular or count, as evidenced by its (lack of an) interaction with verbal agreemen…
Isobaric Vapor−Liquid Equilibria for Ethyl Acetate + Ethanol + 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate at 100 kPa
2007
Isobaric vapor−liquid equilibria for the binary systems ethyl acetate + ethanol, ethyl acetate + 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([emim][triflate]), and ethanol + [emim][triflate] as well as the vapor−liquid equilibria for the ethyl acetate + ethanol + [emim][triflate] ternary system have been obtained at 100 kPa using a recirculating still. NRTL fitting parameters for the ethyl acetate + ethanol and ethanol + [emim][triflate] systems were calculated. The measured ternary data were correlated using the Mock electrolyte NRTL model, which reproduces reasonably well the experimental values. The results suggest that the addition of [emim][triflate] to the ethyl acetate + e…
Calorimetric investigation on the formation of palladium nanoparticles in water/AOT/n-heptane microemulsions
1995
The formation enthalpy of palladium nanoparticles in water/sodium bis(2-ethylhexyl) sulfosuccinate (AOT)n-heptane microemulsions as a function of the waterAOT molar ratio (R = [water][AOT]) was measured by a calorimetric technique. The results indicate that at R < 10 the energetic state of the palladium nanoparticles compartmentalized within the reversed AOT micelles is signficantly different from that in bulk water. Effects due to the small size of the palladium nanoparticles and to interactions between nanoparticles and the waterAOT interface are discussed.