Search results for "O2"

Electrochemical conversion of carbon dioxide to formic acid at Sn and BDD cathodes

2019

Electrochemical reduction of CO2 to useful compounds in the aqueous electrolyte has been actively investigated as alternative technologies to contribute to curbing the rising levels of CO2 in the atmosphere. Many researchers have focused on the CO2 reduction to formic acid, which is considered one of the main target-products owing to its usefulness for agriculture, chemical and pharmaceutical industry, and it is expected to be a good hydrogen storage medium for an upcoming H2-energy-based society [1,2]. In the last few years, an increasing attention was devoted to the utilization of tin electrode for its low cost, low toxicity as well as the high selectivity towards the synthesis of formic …

How far are we from the valorization of waste-CO2 to formic acid via electrochemical routes for the applicative scale?

To date, the decarbonization of the world economy and storage and production of energy from alternative C-based sources is considered a relevant topic. The electrochemical conversion of CO2 has been widely investigated since the 1870s as a promising strategy to convert waste-CO2 into value-added chemicals [1,2]. Recently, it was highlighted that, among the several emerging technologies for CO2 conversion to value-added products on an applicative scale, electrochemical technologies are the closest to commercialization due to the numerous start-ups and established companies being invested in this area (e.g., Opus-12, Dioxide Material, and Carbon Recycling International) [3]. These technologie…

Effect of Pressure on the Electrochemical Conversion of CO2 to CO

2017

To minimize the negative effect of carbon dioxide as a greenhouse gas and introduce renewable energy in the chemical and energy chain, an interesting approach is the Carbon Capture and Conversion. In this context, one of more appealing conversion strategies is the el Ectrochemical reduction of CO2, which could combines the utilization of excess electric energy from intermittent renewable sources with CO2 (1). Furthermore, CO2 can be selectively converted into various useful chemicals by changing the operating conditions of electrolysis. In particular, an increasing attention has been devoted to the electrochemical conversion of carbon dioxide to carbon monoxide (2,3). The main obstacle of t…

Influence of Material-Related Aspectsof Additive and Subtractive Ti-6Al-4VManufacturing on Energy Demandand Carbon Dioxide Emissions

2017

The additive manufacturing of metal parts represents a promising process that could beused alongside traditional manufacturing methods. The research scenario in this field isstill largely unexplored, as far as the technological solutions adopted to integrate differentprocesses are concerned and in terms of environmental and economic impact assessment.In this article, an electron beam melting (EBM) process and a machining process have beenanalyzed and compared using a cradle-to-grave life cycle–based approach. The productionof components made of the Ti-6Al-4V alloy has been assumed as a case study. Theproposed methodology is able to account for all of the main factors of influence on energydem…

Challenges Faced by the Eu’s Energy Policy on CO2 Emissions From 1997-2017, Including Bilaterial Trade Between The EU and the US

2020

Purpose of research: The European Union has three main objectives in its energy policy. The most crucial one is due by 2020, to reduce greenhouse gas emissions (mainly CO2) by at least 20% below 1990 levels. This research attempts to calculate Actual-Open CO2 emission in the EU countries for the years 1997-2017, including in the calculation export and import of CO2 in products and services from the USA. Design/methodology/approach: This study takes into account the USA and 27 European countries (all the EU members without Malta). Actual-Open CO2 emissions were obtained by applying the appropriate Actual Emission Factor. The calculation takes into consideration the transfer of CO2 in exporte…

In situ polymerization of soil organic matter by oxidative biomimetic catalysis

2017

Abstract Background Agricultural practices that enhance organic matter content in soil can play a central role in sequestering soil organic carbon (SOC) and reducing greenhouse gases emissions. Methods We used a water-soluble iron-porphyrin to catalyze directly in situ oxidative polymerization of soil organic matter in the presence of H2O2 oxidant, with the aim to enhance OC stabilization, and, consequently, reduce CO2 emissions from soil. The occurred SOC stabilization was assessed by monitoring soil aggregate stability, OC distribution in water-soluble aggregates, soil respiration, and extraction yields of humic and fulvic acids. Results Soil treatment with H2O2 and iron-porphyrin increas…

Energy potential and CO2 budget of residual biomass in the Menfi wine district, Sicily

2008

Quantifying carbon dioxide flux from dormant volcanoes with low-temperature fumarolic activity: demonstration from measurements at La Soufrière, Guad…

2013

Quantifying the flux of magma derived CO2 dissipated by fumarolic fields at dormant volcanoes is fundamental to assess their current state of hydrothermal activity and, therefore, the likelihood of a future phreatic/magmatic eruption. There is, in fact, documented evidence that gas fluxes, and CO2 flux in particular, can increase substantially during volcanic unrests and prior to eruption, due to either degassing of new ascending magma or changes in the hydrothermal system physical regime. Quantifying CO2 emissions is relatively straightforward at open-conduit volcanoes with high-temperature gas venting, which release high enough quantities of SO2 remotely measurable with UV spectroscopy an…

Chemical Fixation of Carbon Dioxide Catalysed by Multilayered Supported Ionic Liquids

2011

• Volcanic CO2 measurements via Tunable Diode Laser Spectrometer

2014

The analysis of volcanic gas datasets offer key information to build/validate geological models relevant to a variety of volcanic processes and behaviours, including eruptions. In the last decades, near-infrared room-temperature diode lasers, though in an experimental phase, are finding applications in volcanic gas studies. Here, we report on the application of the GasFinder 2.0, a commercial tunable diode infrared laser-receiver unit, operating in the 1.3-1.7 μm wavelength range, to measuring CO2 concentrations in volcanic gas emissions. At first, our field tests were conducted in three different campaigns at Campi Flegrei volcano (near Pozzuoli, Southern Italy), and, subsequently, also in…