Search results for "OAD"
showing 10 items of 3121 documents
Thiourea-Catalyzed Domino Michael–Mannich [3+2] Cycloadditions: A Strategy for the Asymmetric Synthesis of 3,3′-Pyrrolidinyl-dispirooxindoles
2017
The asymmetric synthesis of trifluoromethylated 3,3′-pyrrolidinyl-dispirooxindole derivatives with four contiguous stereogenic centers, including two vicinal spiro-stereocenters, is described. Employing a bifunctional thiourea catalyst, a domino Michael–Mannich [3+2] cycloaddition occurs readily between isatin ketimines and isatin-derived enoates with good yields and very high stereoselectivities, providing a direct entry to the title compounds of potential medical value.
Lidar sounding of volcanic plumes
2013
ABSTRACT Accurate knowledge of gas composition in volcanic plumes has high scientific and societal value. On the one hand, it gives information on the geophysical processes taking place inside volcanos; on the other hand, it provides alert on possible eruptions. For this reasons, it has been suggested to monitor volcanic plumes by lidar. In particular, one of the aims of the FP7 ERC project BRIDGE is the measurement of CO 2 concentration in volcanic gases by differential absorption lidar. This is a very challenging task due to the harsh environment, the narrowness and weakness of the CO 2 absorption lines and the difficulty to procure a suitable laser source. This paper, after a review on r…
Developing an indicator-modelling approach to forecast changes in nitrogen critical load exceedance across Europe arising from agricultural reform
2011
International audience; Atmospheric nitrogen (N) deposition above the critical load causes eutrophication with adverse impacts on biodiversity. Average Accumulated critical load Exceedance (AAE) is a measure of the amount of critical load exceedance and the area of habitat which is affected, and has been adopted in Europe as a pressure indicator for biodiversity. In Europe, AAE is calculated by the Coordination Centre for Effects (CCE) of the United Nations Economic Commission for Europe based on modelled nitrogen deposition and country-level reporting of critical load thresholds and ecosystem area. Due to differences in country-level reporting, AAE values for semi-natural habitats may show…
A review of environmental impacts of winter road maintenance
2019
Abstract The need for winter road maintenance (WRM) is changing in cold regions due to climate change. How the different modes of WRM will contribute to future overall emissions from infrastructure is therefore of great interest to road owners with a view to a more sustainable, low-carbon future. In the quest for near-zero-emissions transport, all aspects of the transport sector need to be accounted for in the search for possible mitigation of emissions. This study used 35 peer-reviewed articles published between 2000 and 2018 to map available information on the environmental impacts and effect of WRM and reveal any research gaps. The articles were categorized according to their research th…
Vibration Tests and Structural Identification of the Bell Tower of Palermo Cathedral
2019
Background: The recent seismic events in Italy have underlined once more the need for seismic prevention for historic constructions of architectural interest and in general, the building heritage. During the above-mentioned earthquakes, different masonry monumental buildings have been lost due to the intrinsic vulnerability and ageing that reduced the structural member strength. This has made the community understand more that prevention is a necessary choice for the protection of monuments. Objective: The paper aims at demonstrating a strategy of investigation providing the possibility of health judgment, identifying a computational model for the assessment of structural capacity under se…
On numerical broadening of particle size spectra: a condensational growth study using PyMPDATA 1.0
2021
Abstract. The work discusses the diffusional growth in particulate systems such as atmospheric clouds. It focuses on the Eulerian modeling approach in which the evolution of the probability density function describing the particle size spectrum is carried out using a fixed-bin discretization. The numerical diffusion problem inherent to the employment of the fixed-bin discretization is scrutinized. The work focuses on the applications of MPDATA family of numerical schemes. Several MPDATA variants are explored including: infinite-gauge, non-oscillatory, third-order-terms and recursive antidiffusive correction (double pass donor cell, DPDC) options. Methodology for handling coordinate transfor…
Shallow system rejuvenation and magma discharge trends at Piton de la Fournaise volcano (La Réunion Island)
2017
International audience; Basaltic magma chambers are often characterized by emptying and refilling cycles that influence their evolution in space and time, and the associated eruptive activity. During April 2007, the largest historical eruption of Piton de la Fournaise (Île de La Réunion, France) drained the shallow plumbing system (>240×106 m3>240×106 m3) and resulted in collapse of the 1-km-wide summit crater. Following these major events, Piton de la Fournaise entered a seven-year long period of near-continuous deflation interrupted, in June 2014, by a new phase of significant inflation. By integrating multiple datasets (lava discharge rates, deformation, seismicity, gas flux, gas composi…
Assessing optimal water quality monitoring network in road construction using integrated information-theoretic techniques
2020
Author´s accepted manuscript. The environmental impacts of road construction on the aquatic environment necessitate the monitoring of receiving water quality. The main contribution of the paper is developing a feasible methodology for spatial optimization of the water quality monitoring network (WQMN) in surface water during road construction using the field data. First, using the Canadian Council of Ministers of the Environment (CCME) method, the water quality index (WQI) was computed in each potential monitoring station during construction. Then, the integrated form of the information-theoretic techniques consists of the transinformation entropy (TE), and the value of information (VOI) we…
Nitrogen broadening of SF6 transitions in the nu3 band
2001
Abstract Nitrogen induced pressure-broadened halfwidths of a number of ν3 transitions of SF6 are calculated using the complex Robert–Bonamy (CRB) formalism. The calculations are made at 200, 250, 296 and 350 K and the temperature dependence of the halfwidths are determined. The intermolecular potential is taken as a sum of the leading electrostatic and Lennard-Jones [6] , [7] , [8] , [9] , [10] , [11] , [12] atom–atom components. The dynamics of the collision process are correct to second order in time. The calculated halfwidths are used to simulate the ν3 spectrum, which is compared to a simulation made using the HITRAN96 halfwidths and measurements made at the Universite Pierre et Marie C…
Arqueoentomología y arqueobotánica de los espacios de almacenamiento a largo plazo: el granero de Risco Pintado, Temisas (Gran Canaria)
2019
This contribution aims at understanding the storage techniques used in the past by means of studying the entomological and plant remains present in the pre-hispanic granary of Risco Pintado, dated between the IX and XV centuries cal AD.This type of granary groups together a large number of silos excavated in the volcanic tuff, situated on steep escarpments, difficult to access and easy to defend.The exceptional environmental conditions of these infrastructures have allowed the desiccated remains of the stored plant products and the pests associated with such storage to be preserved within the silos.The domestic species documented include cereals (barley and wheat), legumes (broad beans and …